Kinetics of phenol oxidation in a trickle bed reactor over active carbon catalyst

The wet air oxidation of phenol over a commercial active carbon catalyst was studied in a trickle bed reactor (TBR) in the temperature and oxygen partial pressure ranges of 120–160 °C and 0.1–0.2 MPa, respectively. The performance of the active carbon was compared in terms of phenol and COD destruction. The weight change of active carbon due to reaction was also measured. Finally, oxic phenol adsorption isotherms were assessed in batch conditions at 25, 125 and 160 °C. In order to use the conversion data obtained from the TBR for a kinetic study, special care was taken to check the kinetic control in the TBR experiments. Several kinetic models including power law or Langmuir–Hinshelwood expressions were considered to describe the catalytic oxidation of phenol over active carbon. The simple power law model with first order dependence on both phenol and oxygen concentration predicted satisfactorily the experimental data not only over the entire range of operating conditions studied, but also outside its validity range. Copyright © 2005 Society of Chemical Industry     

石化行业污水回用途径的可行性分析

随着石化行业污水回用技术的成熟,污水回用途径成了制约污水回用的瓶颈。通过对各种回用水途径的可操作性比较,筛选出最佳途径,并通过现场试验,从技术、经济、可操作性方面论证,认为石化污水回用于工业循环冷却水场作为补充水确实可行。     

"十五"期间涟钢发展循环经济项目的主要内容及效果

介绍了涟钢在"十五"期间实施的循环经济项目:如燃气-蒸汽联合循环发电、小高炉TRT、焦化干熄焦、矿渣粉生产线、免烧承重砖等以及实施的效果.     

夏热冬冷地区高舒适度低能耗建筑新技术

文章通过对夏热冬冷地区建筑节能应考虑的因素及相关技术指标,及高舒适的低能耗技术构成等方面的论述,从理论和实践中加以分析了目前建筑节能面临的问题和误区,从技术角度分析入手,提出了相应的解决措施和方法,以达到舒适和节能的要求为目的.同时还从另一个方面提醒购房者在购房时要增强节能意识,警惕假节能.     

气固流化床中非线性特性的多尺度分析

Deterministic chaos theory offers useful quantitative tools to characterize the non-linear dynamic behavior of a fluidized bed and the developed complexity theory presents a new approach to evaluate finite sequences. In this paper,the non-linear,hydrodynamic behavior of the pressure flutuation signals in a reactor was discussed by chaos parameters and complexity measures.Coherent results were achieved by our multi-scale analysis,which further exposed the behavior in a gas-solid two-phase system.     

低压组合床重整工艺工业试验

介绍了国产500kt／a低压组合床催化重整装置首次在中国石化股份有限公司长岭分公司的工业试验情况。近两年的运转及标定结果表明试验是成功的，该技术达到了国外连续重整技术第一代与第二代之间的水平，并且投资小，适于小型固定床重整装置的改造。     

塔河油田深井穿盐膏层钻井液技术

深井盐膏层钻井施工风险极大,常会引起卡钻和套管损坏,影响安全钻井。通过对塔河油田深井盐膏层矿物组分、理化特征等进行综合分析,阐明井壁失稳的主要原因,为选择钻井液体系提供理论基础;对适应于该段的钻井液体系和现场维护处理技术进行了探索,提出了欠饱和盐水钻井液技术方案,并在T913井、TK827井、TK1106井进行了现场应用。结果表明,井下复杂大幅度降低,钻井周期大幅度缩短,经济效益较好。     

Enhancing sulphur self-retention by building-in CaO in straw–bitumen pellets

Combined straw–bitumen pellets have been proposed as an alternative fuel. An interesting finding is the potentiality of straw ash constituents to retain sulphur as bitumen that has relatively high sulphur content. The aim of the present work is to enhance sulphur self-retention to directly meet the environmental regulations by building-in CaO in the pellet instead of feeding sorbent separately. CaO powder has been mixed with the pellet constituents during production processes.     

无溢流管多层流化床换热器的热态模型研究

本文对无溢流管多层流化床换热器进行了热态模型实验研究，得出了气－固两相间的界膜换热系数曲线，所得结论可供参考。     

基于多模型半参数非线性回归模型的外弹道节省参数估计

双星定位系统的应用是外弹道估计中的一种发展趋势。文章给出基于双星、光雷的联合测量模型,建立基于半参数回归的外弹道节省参数估计模型;给出基于半参数回归的外弹道节省参数估计算法及计算步骤,并从理论上分析了基于半参数回归的外弹道节省参数估计算法能有效地消除非线性因素对参数估计性能的影响,其估计精度优于经典的节省参数建模方法,并通过仿真得到：该算法确实有效。