锂离子电池健康状态估计方法

为研究动力锂离子电池的健康状态( state of health,SOH),根据SOH和荷电状态( state of charge,SOC)的定义以及电池的二阶电阻电容( resistance-capacitance,RC)等效电路模型,建立了基于恒流充电阶段电池电压曲线的SOH估计模型。通过分析电池循环寿命测试数据,利用恒流充电阶段电池电压曲线对SOH进行估计,并与试验数据进行了对比,在SOH值衰减至80%之前,SOH估计的相对误差均在±2%范围内,能较好地吻合试验结果。结果表明：所提出的估计方法具有可行性和精确性。     

Al_2O_3包覆对富锂锰基正极材料Li_(1.2)Mn_(0.54)Co_(0.13)Ni_(0.13)O_2的电化学性能影响

采用水热法合成富锂三元正极材料,探究了最佳包覆比例下Al_2O_3包覆对材料的电化学性能影响.采用扫描电镜(SEM)和X射线衍射仪(XRD)表征了富锂三元正极材料的表面形貌和结构,通过循环伏安(CV)、交流阻抗(EIS)技术分析了材料电化学性的影响因素.结果表明,通过异丙醇铝水解制得了氧化铝包覆层,提高了材料的比容量,稳定了材料的结构.     

锂交换法制备六氟磷酸锂及表征

六氟磷酸和吡啶反应生成吡啶六氟磷酸,吡啶六氟磷酸和氢氧化锂通过锂交换反应生成吡啶六氟磷酸锂,在四氢呋喃溶剂中,吡啶六氟磷酸锂与浓硫酸反应生成六氟磷酸锂。实验研究了溶剂、反应温度、反应时间、配料比等对锂交换反应的影响,得到适宜的工艺条件:65℃反应4 h,原料配比n(C5H5NHPF6)∶n(LiOH)=1.0∶1.0,此条件下吡啶六氟磷酸锂收率94.5%;经核磁共振、红外光谱检测,吡啶六氟磷酸锂和LiPF6是目的产物。     

氯化锂对纤维素/离子液体浓溶液纺丝的影响

以离子液体1-烯丙基-3-甲基咪唑氯盐（[AMIM]Cl）为溶剂、氯化锂（LiCl）为添加剂,通过测定纤维素溶液的流变性能来考察LiCl对纤维素/[AMIM]Cl溶液纺丝性能的影响,发现纤维素/[AMIM]Cl/LiCl呈现切力变稀行为,当LiCl添加量为[AMIM]Cl质量的3%时,切力变稀行为最明显.使用双螺杆挤出机通过干湿法纺丝制备出了高浓度的纤维素纤维,通过XRD、偏光显微镜、SEM及单纤强力仪等表征了纤维的结构与性能,结果表明随着LiCl含量的增加,所得纤维的结晶度和双折射率增加,结构致密,纤维强度增加,当LiCl含量达3%时,纤维强度可达3.13 cN/dtex.     

Synthesis and characterization of triclinic structural LiVPO4F as possible 4.2 V cathode materials for lithium ion batteries

A potential 4.2 V cathode material LiVPO4F for lithium batteries was prepared by two-step reaction method based on a carbon-thermal reduction （CTR） process. Firstly, V2O5, NH4H2PO4 and acetylene black are reacted under an Ar atmosphere to yield VPO4. The transition-metal reduction is facilitated by the CTR based on C→CO transition. These CTR conditions favor stabilization of the vanadium as V^3＋ as well as leaving residual carbon, which is useful in the subsequent electrode processing. Secondly, VPO4 reacts with ElF to yield LiVPO4F product. The property of the LiVPO4F was investigated by X-ray diffractometry （XRD）, scanning electron microscopy （SEM） and electrochemical measurement. XRD studies show that LiVPO4F synthesized has triclinic structure（space group p I ）, isostructural with the naturally occurring mineral tavorite, EiFePO4-OH. SEM image exhibits that the particle size is about 2μm together with homogenous distribution. Electrochemical test shows that the initial discharge capacity of LiVPO4F powder is 119 mA·h/g at the rate of 0.2C with an average discharge voltage of 4.2V （vs Ei/Li^＋）, and the capacity retains 89 mA·h/g after 30 cycles.     

多超声振子作用下气泡动力学数值模拟

超声对强化吸收制冷循环中发生器内溴化锂水溶液沸腾传热有重要意义,目前开展的相关研究较少,尤其多超声振子气泡动力学方面的理论尚未报道。为探究振子数量对溶液空化特性的影响,构建多振子气泡动力学模型,以纯水为例验证了模型准确性,探讨了不同影响因素对溶液空化特性的影响。模拟结果表明：总声强为1 W/cm²,振子数量由1增加至5时,空化气泡最大半径增加了44.12%,振子数量达到24～25个时,气泡最大半径增加率仅为1%;发生压力对空化效应的影响随着振子数量的增多而增大,单振子在吸收制冷系统的真空发生器更易产生稳态空化,而多振子更易在真空发生器内产生瞬态空化;多振子频率均匀度越小,空化强度越大,声强均匀度对空化强度的影响可忽略。     

高电压磷酸钴锂正极材料性能调控研究

高性能、高安全储能电池的迫切需求加速了橄榄石型高电压正极材料的研究步伐。为了改善高电压磷酸钴锂(LiCoPO₄)的综合电化学性能,采用溶剂热法研究了溶剂比、过渡元素(Fe、Mn)单掺杂和双掺杂(掺杂元素总量占10%)对正极材料形貌、尺寸、反位缺陷和电化学性能的影响。结果表明,当溶剂比为2.3时,未掺杂LiCoPO₄在0.1C下表现出163.1 mAh·g^-1的最高理论比容量;双掺杂LiCo_0.9Mn_0.05Fe_0.05PO₄正极材料具有突出的循环性能,在0.5C电流密度下,循环100圈后的容量保持率为78.9%,循环稳定性得到明显改善。     

LiNO3对高温高浓度LiBr溶液中碳钢的缓蚀机理

采用电化学法和化学浸泡法研究了高温65%LiBr+0. 07mol/L LiOH溶液中，LiNO3对碳钢腐蚀的影响.结果表明，随LiNO3浓度增加碳钢腐蚀 速率降低，复合添加150 mg/L Na2MoO4后，碳钢在100mg/L LiNO3时腐蚀速率出现最 小值.通过计算NO-3和MoO2-4还原平衡电极电位，发现NO-3优先还原形成 内层以Fe的氧化物为主的膜是由于NO-3具有较高的还原电极电位.LiNO3小于10 0 mg/L时，复合添加的MoO2-4在外层得以还原形成缺氧型MoO2，建立起稳定的双 层膜结构.当LiNO3浓度大于100 mg/L后，NO-3对膜层中MoO3优先侵蚀，加速Br- “楔入” 钝化膜历程，从而破坏了双层膜结构.     

Ageing characteristics and microstructure of Al-4Mg-1.5Cu alloys containing silver and lithium

1　INTRODUCTIONTheroleoftraceelementsonageingofAlalloyshasbeenextensivelystudiedandhasbeenrecentlyre viewedbyPolmear ,RingerandPrabhuetal[14 ] .Itwasfoundthatthesmalladditionofsilvercanstimu lateenhancedagehardeningincertainAl Cu Mgal loys,andthiseffectisevidentforawiderangeofcompositionsselectedinthe (α +θ) ,(α +S)and (α+S +T ) phasefieldsoftheternary phasedia gram[57] .TheadditionofAgtoAl Cu MgalloyswithhighCutoMgratiosstimulatestheformationofanhexagonal shaped precipitate pha…     

Synthesis and characterization of LiNi0.45Co0.10Mn0.45O2 cathode for lithium ion batteries

1INTRODUCTIONAdvanced rechargeable lithium ion batteriesare attractive for use in consumer electronic andelectric vehicle(EV)application because of a fa-vorable combination of voltage,energy density,cycling performance,and have been developed rap-idly worldwide during the past decade[1,2].LiCoO2has been widely used as a cathode material in com-mercial lithiumion battery because it is reasonableeasy to synthesize and shows a stable discharge ca-pacity[3].But due to its high cost and toxic…