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991.
砂岩储集层微波加热产生微裂缝的机理及意义 总被引:10,自引:2,他引:8
微波加热无需介质传热,具有升温速度快、热惯性小、选择性加热、穿透力强、过程易于控制等优点,已被试验性地应用于石油开采中。但有关微波加热对储集层岩石微观结构影响的研究还很缺乏,限制了该项技术在油气开采领域的广泛应用。通过实验手段研究了微波加热前后砂岩岩样微观结构变化、微裂缝产生机理及特征。结果表明,砂岩在微波加热过程中容易产生微裂缝,且不同岩石的微波加热致裂机理不尽相同,主要包括:矿物失水收缩、颗粒粒间开裂和颗粒内部开裂,低渗透致密砂岩刚性颗粒的粒内开裂作用显著。微波加热产生的微裂缝具非定向特征,即使在应力的作用下有一部分裂缝会发生闭合,但仍有大量微裂缝可以起到增加渗透率的作用。井下微波加热的致裂作用有助于改善近井区域渗流能力,提高低渗透油气藏的开采效率。图4参15 相似文献
992.
通过XDCAM、P2HD在大洋D^3-edit、D^3-edit HD、苹果非编上的测试,分析各自的特点,总结出相应的工作流程,为下一步的设备选型和应用打下基础。 相似文献
993.
Gas-phase selective oxidation of toluene has been carried out on vanadium oxide systems (5–20 wt.% of V2O5, equivalent to 0.4–1.7 theoretical monolayers) supported on TiO2–sepiolite (with titania loading around the theoretical monolayer, 12 wt.%) and on sepiolite. A study has been made on both the influence of vanadia loading and of the support on the catalytic behaviour of the supported vanadium systems. The reducibility by H2 TPR was also studied as well as the acid and basic/redox sites from the results of conversion of the 2-propanol test reaction of the solids. Benzaldehyde, benzoic acid and several coupling products were the main ones detected, attaining over 50% selectivity towards the benzaldehyde and benzoic acid products at a total conversion around 10%. The activity and selectivity to the selective products exhibited by vanadium systems supported on mixed support were superior to those exhibited by the systems supported on sepiolite and increased notably in both series with the increase in vanadium loading. The best catalytic behaviour exhibited by the vanadium systems supported on mixed support, which also exhibited the highest density of sites capable of being reduced (as well as their reducibility) and of those responsible for propanone formation, could be attributed not only to the different balance of the vanadia species existing in the two supports (monomeric + oligomeric/polymeric), but also to such other factors as the nature of the support and, concretely, its chemical composition. 相似文献
994.
995.
R.A. Jacques J.G. Santos C. Dariva J. Vladimir Oliveira E.B. Caramo 《The Journal of Supercritical Fluids》2007,40(3):354-359
This work presents a study concerning the chemical characteristics and analytical separation process of the essential oil obtained from high-pressure carbon dioxide extraction of Ilex paraguariensis. The experiments were performed in a laboratory-scale unit in the temperature range of 20–40 °C, from 100 to 250 bar. A blend of the I. paraguariensis extracts was percolated through a preparative chromatographic column, containing silica gel, and successively eluted with 150 mL of each of the following solvents: hexane, toluene, dichloromethane, ethyl acetate, acetone and methanol. The raw extract and its fractions were analyzed by gas chromatography coupled to mass spectrometry detection (GC/MS). The fractionation procedure showed to be a good clean up technique due to the isolation of different classes of compounds in each fraction. Chromatographic analyses allowed the identification of caffeine, fatty acids and esters, phytol, squalene, Vitamin E, stigmasterol derivatives and saturated hydrocarbons. 相似文献
996.
R. D. Dupuis J. C. Bean J. M. Brown A. T. Macrander R. C. Miller L. C. Hopkins 《Journal of Electronic Materials》1987,16(1):69-77
We report the results of studies which have been made on heteroepitaxial layers of GaAs and AlGaAs grown by metalorganic chemical
vapor deposition on composite substrates that consist of four different types of heteroepitaxial layered structures of Ge
and Ge-Si grown by molecular beam epitaxy on (100)-oriented Si substrates. It is found that of the four structures studied,
the preferred composite substrate is a single layer of Ge ∼1 μm thick grown directly on a Si buffer layer. The double-crystal
X-ray rocking curves of 2 μm thick GaAs films grown on such substrates have FWHM values as small as 168 arc sec. Transmission
electron micrographs of these Ge/Si composite substrates has shown that the number of dislocations in the Ge heteroepitaxial
layer can be greatly reduced by an anneal at about 750° C for 30 min which is simultaneously carried out during the growth
of the GaAs layer. The quality of the GaAs layers grown on these composite substrates can be greatly improved by the use of
a five-period GaAs-GaAsP strained-layer superlattice (SLS). Using the results of these studies, low-threshold optically pumped
AlGaAs-GaAs DH laser structures have been grown by MOCVD on MBE Ge/Si composite substrates. 相似文献
997.
济钢350m^3高炉高富氧生产技术 总被引:1,自引:1,他引:0
分析了济钢350m^3高炉高富氧对产量,理论燃烧温度,炉况顺行状况,焦比和生产效益的影响,高富氧可提高产量,但升高焦比和高炉理论燃烧温度,一定程度上影响高炉顺行,存在富氧效益最大化的适宜富氧率.高炉生产应低富氧高喷煤,根据钢目前的情况,富氧率经2%-3%为宜. 相似文献
998.
In this paper we design a dynamic dictionary for
the priced information model initiated by Charikar et al. Assume that a set S consisting of n elements is given such that
each element has an associated price, a positive real number. The cost of performing an operation on elements of S is a function
of their prices. The cost of an algorithm is the sum of the costs of
all operations it performs. The objective is to design algorithms
which incur low cost. In this model we propose a dynamic dictionary, supporting
search, insert and delete, for keys drawn from a linearly ordered set.
As an application we show that the dictionary can be used in
computing the trapezoidal map of a set of line segments, a fundamental problem in
computational geometry. 相似文献
999.
为了控制熔融铝合金直接氧化法制备Al2O3/Al复合材料的氧化生长,采用ZnO,SiO2和MgO3种表面引发剂,研究它们对Al-Si-Zn合金氧化生长过程及Al2O3/Al复合材料组织形貌的影响.结果表明:与未使用引发剂时相比,使用SiO2,ZnO或MgO表面引发剂制备的粉末都能显著地缩短Al-Si-Zn合金的氧化生长孕育期,提高合金氧化生长速率,改善复合材料的胞状生长方式,提高复合材料的组织均匀度和致密度,为实际生产应用提供了依据.实验发现:ZnO表面引发剂的使用效果最为突出,其最佳添加量为12mg/cm2. 相似文献
1000.
A novel one-shell high temperature and high pressure semi-continuous reactor has been developed for the study of the Boudouard reaction at temperatures up to 820 °C and pressures up to 32.5 MPa. Semicontinuous gasification of charcoal using supercritical CO2 has been achieved at conversions up to 90.8% (w/w) at LSHV between 20 and 30 h−1 after 5–9 h. A gasification model is proposed and validated. Effective rates of gasification (1.32 ± 0.12) × 10−6 to (6.10 ± 2.03) × 10−5 s−1 were obtained. The results indicated that this method is technically feasible for the on-line production of high pressures streams of CO/CO2 in the lab for carrying out further chemistries, avoiding the use of CO high pressure bottles. 相似文献