CpTi(dbm)Cl_2催化烯烃聚合及其聚合物性质

开发了一种新型非茂聚烯烃催化剂———CpTi(dbm)Cl2,考察了催化剂在均相及负载条件下对乙烯及乙烯-1-己烯共聚的催化行为。催化剂在均相条件下对乙烯聚合的催化活性较低,但用MgCl2和MgCl2/SiO2复合双载体对催化剂进行负载后,催化乙烯聚合具有非常好的催化活性。催化剂还具有良好的共聚能力及良好的氢调敏感性。     

Computations of Explosive Boiling in Microgravity

Dynamics of the explosive growth of a vapor bubble in microgravity is investigated by direct numerical simulation. A front tracking/finite difference technique is used to solve for the velocity and the temperature field in both phases and to account for inertia, viscosity, and surface deformation. The method is validated by comparison of the numerical results with the available analytical formulations such as the evaporation of a one-dimensional liquid/vapor interface, frequency of oscillations of capillary waves, and other numerical results. Evolution of a three-dimensional vapor nucleus during explosive boiling is followed and a fine scale structure similar to experimental results is observed. Two-dimensional simulations yield a similar qualitative instability growth.     

Measurement accuracy enhancements for wideband modulated signals

Time‐domain waveform measurements of wideband modulated signals, although attractive for communication systems modeling applications, have until now lacked the required accuracy for quantitative analysis. New developments described here enhance the accuracy of these measurements, enabling their application to communication system characterization and modeling. © 2003 Wiley Periodicals, Inc. Int J RF and Microwave CAE 13: 32–39, 2003.     

板式换热器在中小高炉炉体冷却中的应用探讨

中小高炉炉体软水冷却采用的空冷器冷却效果随季节变化而波动，夏天时最高进高炉水温达到70℃以上，影响了高炉的安全高产和使用寿命。板式换热器以波纹板为传热面，传热系数高、体积小、拆装清洗方便，换热强度高，换热效果好，根据中小高炉炉体冷却软水系统流量大、温差小等特点，宜选用316或316L不锈钢材质、结构矮胖型、开二备一、3台并联的板式换热器。济钢2^#355m^3高炉采用BR1．IXC(1．0／100)200．2型水-水板式换热器，软化水进高炉温度全年稳定在34～39℃。     

Analytical modeling and experimental study of tensile strength of asphalt concrete composite at low temperatures

In this study, analytical modeling of the tensile strength of hot-mix asphalt (HMA) mixtures at low temperatures was developed. To do this, HMA mixtures were treated as a two-phase composite material with aggregates (coarse and fine) dispersed in an asphalt mastic matrix. A two-phase composite model, which was similar to Papanicolaou and Bakos's [J. Reinforced Plast. Compos. 11 (1992) 104] model with a particle embedded in an infinite matrix, was proposed. Unlike Papanicolaou and Bakos's model, an axial stress was introduced to the fiber end to consider the load transferred from the asphalt mastic the aggregate. Efforts were also made to consider the effect of aggregate gradation, asphalt mastic degradation, and interfacial damage between the aggregates and asphalt mastic matrix on the tensile strength of the HMA mixtures. Experimental investigations were conducted to validate the developed theoretical relations. A reasonable agreement was found between the predicted tensile strength and the experimental results at low temperatures. Parameters affecting the tensile strength of asphalt mixtures were discussed based on the calculated results.     

低渗透油藏回注污水的深度处理中试研究

为达到将油田采出水回注低渗透油藏的水质要求，在辽河油田进行含油污水处理试验：先在油田来水进入沉降罐前加入除油剂，使水中油的含量从20g／L降至约0．15g／L．悬浮物含量从10g／L降至3g／L左右；再采用气液多相泵气浮技术净水，使水中油的含量降至约0．005g／L。悬浮物含量降至约0．03g／L；进行初级过滤后，采用硅藻土动态膜超滤工艺精密过滤，最终使水中油和悬浮物含量均小于0．002g／L，悬浮物粒径控制在1μm左右。硅藻土动态膜超滤工艺集中了填充床过滤技术易再生和超滤膜过滤技术高水质的优点，运行费用低，应用前景很好。图6参11     

地层测试对油层改造选井选层的重要性及改造措施有效性评价

经对胜利油田近三年来典型井例测试资料分析评价及其增产措施效果分析认为，有三类地层压裂增油效果很好：地层物性相对较好的常压系统且存在严重堵塞的储层；物性较好的常压地层；高压低渗透储层。有两类地层酸化效果很好：灰岩、白云岩裂缝、低产低渗透储层；物性较好且存在严重污染堵塞的储层。其它地层压裂、酸化一般是无效的。     

添加VC的TiB2基硬质材料研究

对添加VC的TiB2基硬质材料进行了研究。通过实验测定了硬度、横向断裂强度、高温强度以及耐磨性等性能，通过观察SEM照片研究了VC对TiB2基硬质材料组织结构的影响。综合各种指标，我们确定在TiB2-Fe—Mo硬质材料中VC的最佳添加量为0．5％。     

一种精密温度控制仪

采用精密温度补偿及在传统PID调节基础上运用模糊控制运算 ,实现以单片机为基础开发研制的精密温度控制仪 ,并输出时间开关量信号和 4～ 2 0mA标准电流信号 ,为闭环控制及温度值远传提供依据。     

煤粉着火难易模型的初步建立

利用沉降炉试验系统，针对不同煤质的煤种进行了着火燃烧试验，采用回归分析方法确定了煤粉着火难易模型，按照该模型计算得到的着火温度指数与实际试验中测量得到的结果相符合，证明了模型的精确性。