低温氩等离子体改善PTT织物吸湿性的研究

用氩低温等离子体对PTT织物进行表面改性,以提高PTT织物的吸湿性能。在不同等离子体处理工作参数(放电功率、放电时间、工作气压)下对PTT织物吸湿性变化进行了规律性和原理分析,并探讨等离子体对PTT织物的最佳处理工艺。实验结果表明:放电时间5min、放电功率200W、气体压强50Pa的处理条件使PTT织物得到最佳的吸湿性能;PTT织物的微观表面出现了明显的凹坑和裂纹,同时强力变化较小。     

Ferroelectric SrBi 2 Nb 2 O 9 Thin Films by Aqueous Chemical Solution Deposition

SrBi 2 Nb 2 O 9 (SBN) thin films on a Pt/Ti/SiO 2 /Si substrate were prepared by aqueous chemical solution deposition. The precursor solution was synthesized by means of an 'aqueous solution-gel method', starting with stable, inexpensive and easily available inorganic salts which are dissolved in an aqueous solution of chelating or coordinating ligands (acetates and citrates). Afterwards the synthesized precursor was spin-coated. However, problems arose as a consequence of insufficient 'wetting' of the substrate surface by the aqueous solution (poor film-substrate adhesion). Instead of improving surface adhesion by the addition of a surface-wetting reagent, a new strategy was developed: prior to spin-coating the platinum surface characteristics were modified using a UV/ozone technique. In this way the precursor solution was not chemically changed. Wetting/wettability was verified by means of contact angle measurements. A uniform, three-layer thin film with a total thickness of about 200 nm was obtained after thermal treatment, as could be verified using SEM and XRD.     

发热电缆低温辐射供暖技术的应用

结合具体工程实例,阐述了发热电缆低温辐射供暖技术的应用,从该供暖方案的选择、工作机理及施工要点等几方面进行了探讨,强调了该供暖方案的施工要点,并进行了综合效益分析,最后提出了该供暖技术存在的问题,以推广该技术的应用。     

低温下用J_R曲线确定金属材料延性断裂韧度J_(IC)的研究

以石油天然气设备及机器中常用的几种中、低强度钢为代表,通过弹塑性断裂力学J积分试验,研究了在低温环境下如何用J积分阻力曲线(J_R曲线)和裂纹尖端钝化线确定金属材料低温延性断裂韧度J_(IC)值,结果表明,该方法能得到J_(IC)随温度降低而降低的规律,适合于工程应用。     

低温混凝土抗冻临界强度影响因素的研究

目的针对低温条件下东北地区冬季施工特征，研究不同养护制度、水灰比、龄期对普通C30混凝土幼龄期抗压强度以及幼龄期抗冻临界强度的影响．方法采用一次冻结法，在-20℃的条件下养护7d。以混凝土在后期继续标准养护条件下强度增长的百分率(95％)作为评价标准．结果得出不同养护温度条件下混凝土的幼龄期抗压强度，以及标准养护条件下表干状态与表面浸润状态下混凝土的抗冻临界强度．结论水灰比在0.4～0．6的范围内，随着水灰比的增大，表干状态混凝土达到抗冻临界强度的时间由12h增加到26h，浸润状态混凝土达到抗冻临界强度的时间由36h增加到70h，而且在冬季施工低温环境中浸润状态混凝土所需的抗冻临界强度为8．5～9MPa，远大于表干状态混凝土的抗冻临界强度2、5～3MP。     

硼泥陶粒混凝土用于低温热水地板辐射供暖

目的 研究硼泥陶粒混凝土作为低温热水地板辐射供暖系统蓄热层的作法及其性能．方法 辽化湖畔花园小区住宅楼工程中，用硼泥陶粒混凝土代替豆石混凝土作低温热水地板辐射供暖系统蓄热层，取暖期内对试验工程进行温度监测实验．结果 试验工程混凝土试块强度平均值为27.5MPa，合格率为100％，厚度均在允许偏差内，合格率100％；外观鉴定混凝土表面无裂缝，并根据温度监测结果画出了取暖期内每天温度随时间变化的曲线图．结论 用硼泥陶粒混凝土作低温热水地板辐射供暖系统的蓄热层，与用豆石混凝土相比，减轻了建筑物自重、减缓了传热速度、增强了房间的热稳定性．     

冰蓄冷空调系统的经济性分析

本文在介绍冰蓄冷空调系统的两种经济分析评价方法的基础上,主要通过对某一大厦的冰蓄冷空调与常规空调设计的投资比较的经济性分析,论证了采用冰蓄冷空调系统具有良好的经济效益,同时也分析了影响冰蓄冷空调几种经济效益的主要因素.     

Thermal Instability and Microstructure of Strontium M-type Hexaferrite Nanoparticles Synthesized by Citrate Approach

The dried gel of SrFe12O19, prepared by citrate approach, was investigated by means of infrared spectroscopy （ IR ）, thermogravimetric analysis （ TG ）, differential scanning calorimetry （ DSC ）, X- ray diffraction（ XRD ） techniques, energy dispersive spectroscopy（ EDS ）, and transmission electron microscopy（ TEM ）. The thermal instability and the thermal decomposition of low-temperature strontium M-type hexaferrite crystallized at about 600℃ were confirmed for the first time by XRD method. The decomposition of the low-temperature strontium M-type hexaferrite took place at about 688.6℃ determined by DSC investigation. The low-temperature strontium M-type hexaferrite nanopartieles were decomposed into SrFeO2.5 with an orthorthombic cell and Fe2O3 with a tetragonal cell as well as possibl α-Fe2O3 . The agglomerated particles with sizes less than 200 nm obtained at 800℃ were plesiomorphous to strontium M-type hexaferrite. The thermally stable strontium M-type hexaferrite nanopartieles with sizes less than 100um cotdd take place at 900 ℃ . Up to 1000 ℃ , the phose transformotion to form strontium M-type hexaferrite was ended, the calcinations with the sizes more than 1μm were composed of α-Fe2O3 and strontium M-type hexaferrite. The method of distinguishing γ-Fe2O3 with a spinel structure from Fe2O3 with tetragonal cells by using powder XRD method was proposed. Fe2O3 with tetragonal cells to be crystallized before the crystallization of thermally stable strontium M-type hexaferrite was confirmed for the first time. The reason why α- Fe2O3 as an additional phase appears in the calcinations is the cationic vacancy of stroutium M-type hexaferrite , SrFe12-x□O19 （0≤x ≤0.5）.     

BCB对CSLLT陶瓷的烧结及介电性能的影响

在CaO-SrO-Li2O-Sm2O3-Nd2O3-TiO2(简称CSLLT)陶瓷中加入BaCu(B2O5)(简称BCB),研究了BCB对CSLLT陶瓷的烧结特性和介电性能的影响。结果表明:随BCB的添加,CSLLT陶瓷的烧结温度逐渐下降,并且具有高介电常数。其中,添加10?B后的CSLLT陶瓷其烧结温度从1 300℃显著下降到1 050℃,且在微波频率下具有如下介电性能:ε=77.3、Qf=4 735 GHz;τf=-48.1×10-6/℃(1 MHz)。     

B位取代对钛酸锌相结构及介电性能的影响

通过固相烧结法结合半化学法制备了ZnO-(1-x)TiO2-xSnO2(x=0.04~0.20)陶瓷,掺杂1.0%3V2O5(质量分数)-B2O3降低陶瓷的烧结温度,研究了B位取代对ZnTiO3相结构及介电性能的影响。结果表明,Sn的加入促进了六方相分解,形成了立方尖晶石结构的固溶相Zn2(Ti1-xSnx)O4;随烧结温度升高,Sn的固溶量增加,900℃时,最大固溶量为0.08 mol。900℃烧结试样,随x增加,其介电常数ε先增大后减小,而介电损耗tanδ恰好相反,先减小后增大,当x=0.12时,得到ε的最大值(ε=29)和tanδ的最小值(tanδ=9.86×10-5)。900℃烧结的具有优良介电性能的ZnO-(1-x)TiO2-xSnO2(x=0.04~0.20)陶瓷有很好的实际应用前景。