Concast连铸机自控系统简介

天津钢铁有限公司引进了瑞士Concast公司6机6流方、圆坯连铸机及相关技术，文章简要介绍了Concast连铸机的自动控制系统的特点和功能。     

小纸层析法快速测定^99mTc—HMPAO放射化学纯度

采用小纸层析系统１：１的氯仿／四氢呋喃展开剂分析＾９９ｍＴｃ－ＨＭＰＡＯ的放射化学纯度，并与两个薄层析系统和一个纸层析系统的方法作比较。配对ｔ检验结果表明两种方法测定的放射化学纯度无显著差异；放射化学纯度在７４．２％－９６．４％，小纸层析法与薄层／纸层析法紧密相关，回归公式ｙ＝１．００６ｘ－０．３２３。     

Fabrication of blue-light emission fused-silica substrates by using Si-ion implantation and high-temperature annealing

We fabricated fused-silica substrates which emit blue light by using Si-ion implantation and high-temperature annealing. Photoluminescence peak wavelengths are around 400 nm, and the peak intensities can be remarkable after annealing above 1150 °C.     

An energy dispersive micro X-ray diffractometer based on a combined system of polycapillary optics

An energy dispersive micro X-ray diffractometer based on a combined system of two polycapillary X-ray lenses is designed. The polycapillary X-ray lens in the excitation channel is either a polycapillary parallel X-ray lens (PPXRL) or a slightly focusing polycapillary X-ray lens (SFPXRL). The polycapillary X-ray lens in the detection channel is a PPXRL. At 6.4 keV and 2m>θm> = 141.5°, the total resolution of the diffractometer based on a SFPXRL in the excitation channel and a PPXRL in the detection channel in Δm>dm>/m>dm> is 4.8%.     

The distribution of anthocyanins in grape skin extracts of port wine cultivars as determined by high performance liquid chromatography

The distribution of anthocyanins in methanolic skin extracts of 16 grape cultivars used for port wine production and grown at five sites in the Douro Valley in Northern Portugal has been assessed by high performance liquid chromatography. Results are confined to the seven most readily separated and identified anthocyanins and are expressed as percentages of their total (88–99% of the total integrated area). Anthocyanins based on malvidin (Mv) predominated. Of these, Mv 3-glucoside was the major pigment (33–60%), being exceeded by Mv 3-p-coumarylglucoside (2–51%) in only two cultivars; Mv 3-acetylglucoside (1–15%) was consistently the lowest. Peonidin 3-glucoside (1–27%) was prominent in four cultivars, but delphinidin 3-glucoside (1–11%), petunidin 3-glucoside (2–11%) and cyanidin 3-glucoside (trace-6%) were of low proportions throughout. The ratio Mv 3-acetylglucoside/total Mv glucosides appeared characteristic of cultivar, independent of site, and a useful aid to identification of grape cultivars. The coloured pulp of some cultivars contained peonidin 3-glucoside as a major component, present in greater proportions than in the skin; the percentage of Mv 3-p-coumarylglucoside was lower in pulp than in skin. The identities of six of the seven anthocyanins were confirmed by fast atom bombardment mass spectrometry and the structures of the Mv derivatives were determined by nuclear magnetic resonance. The formation of formyl and acetyl anthocyanin artefacts is described.     

SVPWM三相电压型逆变器的仿真研究

以三相电压型逆变器为基础,根据空间矢量脉宽调制（SVPWM）基本原理详细分析研究了电压矢量作用时间和扇区分配问题,以α-β坐标为基础,建立了互差π/3的x-y-z时间坐标系,提出了不同扇区矢量作用时间长短根据期望极值判断的原则。介绍了MATLAB中M文件编程的仿真方法,建立了MATLAB程序嵌入式主要功能模块,逆变器采用数字PID控制,利用Simulink对系统进行了综合仿真分析及试验,给出了仿真及实验波形,为实现SVPWM逆变器的数字控制提供参考。     

消失模精密铸造工艺研究

借助熔模铸造制壳工艺制成消失模铸造用的超薄空腔型壳，以减少消失模铸造在浇注过程中因聚苯乙烯气化而产生的铸件增碳、增氢等缺陷。聚苯乙烯模失模工艺为随炉升温至600℃，保温60min,型壳焙烧工艺为800℃焙烧1h。     

全球铝轧制工业概览系列综述之二十二日本与韩国的铝箔工业

对日本与韩国的铝箔工业作了全面介绍，扼要地介绍了两国的铝箔生产能力、企业名称、装备、产量、进出口量等。除中国外，日本与韩国是亚洲最大的铝箔生产国与消费国。日本2001年的产量为134．251h，2000年的产量为153．820kt，2002年预计产量约130．00kt；日本生产铝箔的公司有7家，10个工厂，其中最大的东洋铝业公司，生产能力35kt／a；日本是铝箔净输出国，2001年出口轧制箔54．473kt，其中对中国的出口为15．369kt。韩国有7个铝箔公司，总生产能力120kt／a，最大的是洛特铝业公司，生产能力40kt／a；也是一个铝箔净出口国，2000年的净出口量38．022kt。     

Influence of expandable graphite on fire resistance and water resistance of flame-retardant coatings

Expandable graphite (EG) coating and ammonium polyphosphate-pentaerythritol-melamine (APP-PER-MEL) coating were prepared. Thermal degradation and char formation of the coatings were investigated by differential thermal analysis (DTA), thermogravimetry (TG), X-ray diffraction (XRD), scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). The results have shown that the anti-oxidation and fire-resistant properties of expandable graphite coating containing EG with size of 74 μm are better than those of APP-PER-MEL coating. The static immersion test was applied to study water resistance of the coatings, and the fire protection test and mechanical test were used to analyse heat insulation and mechanical properties of coatings before and after water immersion. The fire-resistant and mechanical properties of APP-PER-MEL coating were severely damaged by water immersion, whereas EG coating containing 8.5% EG with size of 74 μm could retain the good fire resistance even after 500 h water immersion.     

Diluent effects on carbonate mobility in bisphenol-A polycarbonate in the solid state

The effect of miscible low molecular weight additives on the mobility of the carbonate group in bisphenol-A polycarbonate (BPAPC) has been studied using n.m.r. and dielectric relaxation experiments in the solid state. Proton-enhanced dipolar-decoupled carbon-13 n.m.r. spectra of BPAPC, isotopically enriched at the carbonate position, are obtained without magic-angle sample spinning. The resolved chemical shift anisotropy allows study of nuclear spin relaxation for the carbonate groups in the polymer that have different orientations relative to the static magnetic field in the laboratory frame. The spin-lattice relaxation time in the rotating frame (m>Tm>_1m>?m>) is measured at a motional-probe frequency of 50 kHz for the undiluted polymer and for BPAPC-diluent blends containing either dibutylphthalate or dinitrobiphenyl. The m>Tm>_1m>?m> exhibits some dependence on orientation in all systems studied. In the blend containing dibutylphthalate (DBP), m>Tm>_1m>?m> is decreased by a factor of two for all orientations of the carbonate group. This implies that DBP substantially increases the spectral density of 50 kHz motions in the carbonate region of the polymer at ambient temperature. In contrast, dinitrobiphenyl does not significantly alter the Fourier component of thermal fluctuations at 50 kHz. Dielectric relaxation measurements at 10 kHz reveal that the primary (m>Tm>_g) and secondary (β) motional processes in BPAPC are affected by low molecular weight additives. An intermediate relaxation process appears in the temperature interval between the glass transition temperature (m>Tm>_g) and the sub-m>Tm>_g β-relaxation (m>Tm>_m>βm>) in the polymer-diluent blends. The n.m.r. spin-lattice relaxation rate in the rotating frame, m>Tm>^?1_1m>?m>, correlates well with the relative magnitude of the dielectric dissipation factor (tan m>δm>_m>εm>) between m>Tm>_g and m>Tm>_m>βm>.