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41.
Interpenetrating polymer networks (IPNs) based on different ratios of a modified bismaleimide resin (BMI/DBA) and cyanate ester (b10) have been synthesized via prepolymerization followed by thermal curing. A systematic thermal degradation study of these new BMI/DBA‐CE IPN resin systems was conducted by thermogravimetric analysis at different heating rates both in N2 (thermal stability) and in air (thermal‐oxidative stability). The cured BMI/DBA‐CE IPN resin systems show excellent thermal stability, which could be demonstrated by 5% weight loss temperature (T5%) ranging between 409 and 423 °C, maximum decomposition rate temperature (Tmax) ranging between 423 and 451 °C, and the char yields at 800 °C ranging from 37% to 41% in nitrogen at a heating rate of 10 °C min?1. The apparent activation energy associated with the main degradation stage of the cured BMI/DBA‐CE IPN resin systems was determined using the Kissinger method. The obtained results provide useful information in drawing correlation between thermal properties and structure. © 2003 Society of Chemical Industry 相似文献
42.
YI Xiao-su 《材料研究与应用》2005,(3):102-116
In framework of the National Key Basic Research Program (973 Program) we focus our attention on R&D of (1) continuous enhancement of composites performance both for new generation and existing materials, (2) cost-effective manufacturing technologies, particularly resin transfer molding (RTM) in conjunction with textile technology, and (3) crashworthy composite structures in design, and manufacturing and simulation methodology for aircrafts composites. Many successful examples stories such as ex-situ concept have been demonstrated that the performance potential of composites could be enhanced and maximized by basically understandirg the complicated multi-scale and multi-dimensional structural characteristics in relation to properties. Based on the concept, graphite composites system with generally high impact damage resistance and balanced processing conditions has being developed consisting of base resins, modifiers and binders/tackifiers. 相似文献
43.
环氧改性双马来酰亚胺树脂聚集态结构的研究 总被引:4,自引:0,他引:4
利用透射电子显微镜(TEM)追踪环氧改性双马来酰亚胺树脂在固化过程中聚集态结构的变化,发现环氧与双马来酰亚胺形成了互穿网络结构(IPN)。但由于环氧和马来酰亚胺的固化活性不同,环氧先发生固化,引起两种单体间的溶解度下降而发生相分离,形成了富环氧区域和富双马来酰亚胺区域。互穿与相分离是两个相反的结构发展方向,它们决定着树脂的结构和机械性能。树脂的互穿程度直接受初始固化温度的控制。 相似文献
44.
45.
A novel high‐performance resin system with low injection temperature for resin transfer moulding, M4506, was developed, which was made of 4,4′‐bismaleimidodiphenylmethane, o,o′‐diallyl bisphenol A, o,o′‐diallyl bisphenol A ether, and 1,1′‐bis(4‐cyanatophenyl)ethane. The processing characteristics, thermal and mechanical properties of the system were studied, and the effect of differing stoichiometries of each component on the processing and performance parameters was discussed. Investigations show that the processing properties of the M4506 system are greatly dependent on the stoichiometries of each component in the formulations, while all the three formulations developed in this paper have good processing characteristics, their suitable injection temperature are between 40 and 50 °C, depending on their respective formulation. The three formulations exhibited outstanding heat resistance (Tg = 294–300 °C) and thermal stability, good toughness and high strength, evidence that the M4506 system is a potential candidate as a high‐performance RTM matrix for advance composites as well as high‐performance paints with no solvents. Copyright © 2004 Society of Chemical Industry 相似文献
46.
含硅双马来酰亚胺的合成及表征 总被引:7,自引:2,他引:5
采用新的合成路线制得了N-(4-羟基苯基)马来酰亚胺,并以此为起始反应物合成了3种新型含硅双马来酰亚胺。所合成的含硅双马来酰亚胺的分子结构采用红外光谱及^1H-NMR进行了表征。 相似文献
47.
高性能复合材料基体双马来酰亚胺树脂的研究状况及发展趋势 总被引:5,自引:0,他引:5
本文详细介绍了20多年来国内外双马来酰亚胺树脂的研究状况,并重点分析了增韧技术及其化学原理,最后对双马来酰亚胺的应用和发展趋势作了探讨。 相似文献
48.
研制了具有良好溶液性质的双马来酰亚胺树脂体系的新方法。该树脂由4,4′-二氨基二苯甲烷双马来酰亚胺,4,4′-二氨基二苯甲烷,改性物B三元共混物预聚而成。研究结果表明,预聚体在丙酮中具有良好的溶解性,预聚体固化后具有较高的耐热稳定性,可以作为高性能复合材料的候选基体树脂。 相似文献
49.
50.
新型双马来酰亚胺改性环氧树脂体系性能研究 总被引:1,自引:0,他引:1
用含二氮杂萘联苯结构的双马来酰亚胺(DHPZ-BM I)与4,4'-二氨基二苯砜(DDS)为复合固化剂固化环氧树脂(E-51)。采用示差扫描量热仪(DSC)研究了该体系的固化反应动力学,求得固化反应表观活化能Ea=63.28 kJ/mol,碰撞因子A=1.55×106s-1,反应级数n=0.89,该体系与链延长型双马来酰亚胺PPEK-BM I(DP=15)/DDS/E-51体系的固化反应动力学数据几乎相同,证明二者的固化反应过程相同。采用热失重分析仪(TGA)分析研究了上述2种固化体系的热分解动力学,前者的热分解活化能达215.04 kJ/mol,为后者的1.5倍以上,说明DHPZ-BM I/DDS/E-51是1种热稳定性能良好的耐高温环氧树脂体系。 相似文献