PVC树脂聚合用有机过氧化物引发剂

介绍了目前国内外引发剂的使用及开发方向,并对引发剂的选择及其对树脂质量的影响进行了讨论。     

常压渣油热反应过程中胶体的稳定性

利用质量分数电导率方法研究了中东和克拉玛依常压渣油在热反应过程中胶体的稳定性。结果表明，随着反应时间的增长，在热反应生焦诱导期内，渣油的胶体稳定性迅速下降；开始生焦后，胶体稳定性缓慢下降。从中东常压渣油的SARA四组分的数均相对分子质量、碳氢元素组成、平均芳碳率等方面探讨了中东常压渣油在热反应过程中胶体稳定性下降的原因。结果表明，在热反应中，由于裂解和缩聚反应的共同作用，使渣油的沥青质和饱和分含量上升，芳香分含量下降，胶质含量变化不大；随着热反应的进行，四组分的数均相对分子质量均呈下降趋势，导致了渣油胶体稳定性的下降并发生生焦反应。     

The Difference in Turbulent Diffusion between the Active and Passive Scalars in a Thermally Stably Stratified Medium

The difference in the turbulent diffusion between the active (heat) and passive (mass) scalars in a thermally stably stratified medium is investigated. The axisymmetric problem is treated on the formation of a turbulent circulation flow above a heated disk and on the turbulent diffusion of a passive scalar (impurity) from a continuous surface source in a stably stratified medium. The results indicate that the thermal stratification causes appreciable differences in the coefficients of turbulent transfer between the active (heat) and passive (mass) scalars. This means that the assumption of the identity of the coefficient of turbulent diffusion of heat and mass, employed in conventional models of turbulence, produces significant errors in estimating the heat and mass transfer in a thermally stably stratified medium.     

A Mixed-Approach Analysis of Deformations in Pipe Bends. Part 3. Calculation of Bend Axis Displacements by the Method of Initial Parameters

A problem of deformation of a curved shell loaded by internal pressure, axial force, and temperature difference is discussed. Physical equations are derived whereby the displacements and angles of rotation of the line of centers of mass of cross sections of a shell are related to loading parameters. A general constitutive set of equations for a curved element during its deformation is given. Using a method of initial parameters, an analytical solution is obtained for the differential equations for displacements and angles of rotation of the center line allowing for the action of distributed forces and moments.     

垂直管吸收器内泡式吸收过程的数值研究

建立垂直管吸收器管内泡式吸收过程中传热传质的数学物理模型，对其泡式吸收过程进行数值研究，获得泡式吸收方式的一些传热传质特性，为吸收器的优化设计提供一定理论指导。     

岩土体斜(边)坡滑坡发生的机理

根据滑坡发生的初始条件、滑坡成因及方式表象,对常见的蠕变倾覆滑坡、卸荷滑坡、震动液化平推滑坡、潜蚀塌陷滑坡、溶蚀下陷滑坡、孔隙水压浮动滑坡和人工切蚀或冲(浪)蚀—加载滑坡等机理进行了分析.     

Ozonation of CI Reactive Black 5 using rotating packed bed and stirred tank reactor

This study investigates the ozonation of CI Reactive Black 5 (RB5) by using the rotating packed bed (RPB) and completely stirred tank reactor (CSTR) as ozone contactors. The RPB, which provides high gravitational force by adjusting the rotational speed, was employed as a novel ozone contactor. The same ozone dosage was separately introduced into either the RPB or the CSTR for the investigation, while the experimental solution was continuously circulated within the apparatus consisting of the RPB and CSTR. The decolorization and mineralization efficiencies of RB5 in the course of ozonation are compared for these two methods. Moreover, the dissolved and off‐gas ozone concentrations were simultaneously monitored for the further analysis. As a result, the ozone mass transfer rate per unit volume of the RPB was significantly higher because of its higher mass transfer coefficient and gas–liquid concentration driving force. Furthermore, ozonation kinetics was found to be independent of the gravitational magnitude of an ozone gas–liquid contactor. Therefore, the results suggest employing RPBs as ozone‐contacting devices with the advantage of volume reduction. The experimental results, which can be used for further modeling of the ozonation process in the RPB, also show the requirement of correct design for the RPB. Consequently, the present study is useful for the understanding of practical application of RPBs. Copyright © 2004 Society of Chemical Industry     

台缙高速公路苍岭隧道水文地质勘察与涌水量预测

以台缙高速公路苍岭隧道为例，通过水文地质综合勘探方法，查明隧道不同裂隙发育程度岩体的渗透系数K值。然后利用地下水动力学法、地下水径流模数法对隧道开挖涌水量进行了预测。通过施工检验发现，涌水段位置和涌水量总体较接近，说明预测工作对隧道的施工开挖和排水设计具有指导意义。     

苯烃化和四聚丙烯共用一套装置的设计与使用

介绍兰州炼油化工总厂苯烃化和四聚丙烯工艺交替使用同一套装置的设计。由于两种工艺所用催化剂相同，反应机理和原料类同，所以可共用原料系统、反应系统和一些设施，节省用地４５２４ｍ２。依靠技术进步，节能降耗，每年获经济效益６６０万元