甲基丙烯酸缩水甘油酯的合成

在季铵盐催化作用下 ,甲基丙烯酸与环氧氯丙烷反应生成甲基丙烯酸缩水甘油酯。实验结果表明 ,二步法可获得较高的产率     

Surface modification of tetrafluoroethylene–perfluoroalkyl vinylether copolymer (PFA) by plasmas for copper metallization

Tetrafluoroethylene–perfluoroalkyl vinylether copolymer (PFA) sheet surfaces were modified with argon, helium, oxygen, and hydrogen plasmas. How the four plasmas modified the PFA sheet surfaces was investigated. All plasmas modified the PFA surfaces and at the same time initiated degradation of the PFA polymer chains. The balance between modification and degradation was strongly influenced by the magnitude of the discharge current in the plasmas. Efficiency of the plasmas in modification was hydrogen plasma > oxygen plasma > argon plasma > helium plasma. The modification involved defluorination of CF₂ carbons into CHF and CH₂ carbons and oxidation into O? CH₂, O? CHF, and O? CF₂ groups. The surface‐modification technique (a combination of hydrogen plasma treatment and silane coupling treatment) proposed in this study was applied for copper metallization of the PFA surface. The utility of the technique was confirmed. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 1087–1097, 2002     

STEAM OXIDATION OF CARBON FORMED BY THERMAL DEGRADATION OF PMMA IN ALUMINA

In the processing of multilayer ceramic multichip modules (MCM's), a ceramic substrate, such as alumina, along with a polymer, such as poly(methyl methacrylate) (PMMA), solvents, plasticizers, flocculants, is thermally degraded before sintering. The thermal degradation of PMMA from the green body of oxide ceramics leaves behind some amount of residual carbon in the ceramic. Carbon concentration above 100 ppm has a deleterious effect on the physical properties such as fkxural strength, density, breakdown voltage and dcnsification behavior of the ceramic. This paper discusses the kinetics of oxidation of carbon formed by the thermal degradation of poly(methyt methacrylate) in alumina. Pellets of 5 urn and I urn size alumina were made at 6000 psig in a single step change. Kinetic runs were made in the temperature range of 673 to 993 K with steam as the oxidant at a flow rate of 9.96E-03 g/cm² sec. The organics (polymethyl methacrylate, methyl ethyl ketone, methanol) concentration was varied from 5 to 20 by weight%. The oxidation products were analyzed using a Varian 3700 gas chromatograph coupled with CDS 111 integrator, and by volumetric analysis. Carbon analysis was carried out at the IBM Fishkill center using a Leco analyzer. Kinetic rates and activation energies are evaluated.     

Synthesis of polyethylene oxide end‐capped with perfluoroalkyl groups/polystyrene prototype brushes

Polystyrene (PS)/poly(ethylene oxide) (PEO) prototype brushes were prepared by alternating free‐radical copolymerization of methacryloyl‐terminated PS and α‐vinylbenzyl‐ω‐hydroxy or α‐vinylbenzyl‐ω‐perfluoroalkyl (R_f) PEO macromonomers with the addition of Lewis acid (SnCl₄). It was found from their dilute‐solution properties that PS/PEO end‐capped with R_f (PBR_f), and PS/PEO having OH groups at terminal ends (PBOH) prototype brushes formed a single molecule in benzene and aggregates in chloroform, respectively. However, the brush PBOH formed a single molecule in N,N‐dimethylformamide. Such aggregation behaviors seemed to be caused by the interaction between hydroxy groups of PEO chain ends. The brush PBOH was also converted into PBR_f‐type brush by chemical modification, using corresponding acid chloride. The substitution of R_f groups was ～70% due to slipping of terminal hydroxy groups into PEO internal domains. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 772–778, 2006     

甲基丙烯酸甲酯（MMA）生产中水解和酯化反应特性的研究

用间歇式搅拌反应器，对丙酮氰醇（ＨＣＮ）法甲基丙烯酸甲酯生产中水解和酯化反应的特性进行了研究。研究表明：（１）甲基丙烯酰胺硫酸盐的水解反应有较高的平衡转化率，其动力学方程为ｋ１＝６．５２×１０＾６ｅｘｐ（－６９．８／ＲＴ）；（２）甲基丙烯酸与甲醇间酯化反应的平衡转化率较低，故生产中必须加以提高。测得的液相和汽－液相酯化反应的活化能分别为４９．４ｋＪ／ｍｏｌ和５４．４ｋＪ／ｍｏｌ。     

High resolution solid state 13C n.m.r. of butadiene grafted polypropylene

¹H dipolar decoupled ¹³C n.m.r. experiments with the aid of the magic angle spinning technique have been used to determine the graft content and the isomer content of the polybutadiene grafts in a graft copolymer with isotactic polypropylene.     

高聚物湿度传感器的研究

本文介绍采用辐射引发聚合的方法制备高聚物/晶振型湿度传感器。通过对高聚物膜的感湿性能测试与评价,确定聚合物膜中各单体组分含量,并优化辐射聚合工艺。该高聚物/晶振型湿度传感器的技术特点是:湿度测量范围宽10％～100％RH;湿滞回差小,测量误差小于±2％RH。尤其适于在易燃易爆环境下应用。     

氯化聚丙烯改性胶粘剂的合成及粘附性能研究

以甲苯为溶剂，过氧化二苯甲酰(BP0)为引发剂，通过自由基聚合，采用甲基丙烯酸羟乙酯(HEMA)和苯乙烯(St)接枝改性氯化聚丙烯(CPP)。研究了不同苯乙烯用量、不同反应温度、不同反应时间、不同引发剂用量对改性氯化聚丙烯胶粘剂粘附性能的影响，得出较佳的工艺条件为反应温度90℃，反应时问2h，原料配比m(CPP)：m(HEMA)：m(St)：m(BPO)=50：0．5：0．6：0．15。     

SIS-g-AN热降解性能的研究

采用热重分析法和差示热重分析法研究丙烯腈(AN)接枝热塑性弹性体SIS(SIS g AN)的热降解性能。结果得出,SIS g AN的平衡起始降解温度、平衡最大降解速率温度和平衡终止降解温度分别为659. 17, 713. 94 和740.05 K;热降解反应活化能为195.2 kJ·mol-1;热降解机理是Deceleration中的D3 降解机理;不同质量损失率下的热寿命与温度呈线性关系。