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101.
Promotion of hydrogen permeation on metal-dispersed alumina membranes and its application to a membrane reactor for methane steam reforming 总被引:1,自引:0,他引:1
Maorong Chai Masato Machida Koichi Eguchi Hiromichi Arai 《Applied Catalysis A: General》1994,110(2):239-250
A mesoporous membrane for selective separation of hydrogen was prepared usingthe sol-gel method. Some metal salts such as RuCl3, Pd(NH3)4Cl2, RhCl3,, and H 2PtCl6, were added to the boehmite sol and coated on a porous alumina substrate before firing at 500°C. It was foundthat the permeability of hydrogen and the separation factor for a hydrogen-nitrogen gaseous mixture of these metaldispersed membranes exceeded the limitations of the Knudsen diffusion mechanism. Although the gas permeation through a neat alumina membrane is governed by the Knudsen diffusion, the metals dispersed in alumina membranes were effective in promoting hydrogen permeation. These metaldispersed alumina membranes were also used in a membrane reactor for methane steam reforming at low temperature. In the temperature range of 300 to 500°C, the membrane reactor attained a methane conversion twice as high as the equilibrium value of the packed bed catalytic reactor system as a result of the selective removal of hydrogen from the reaction system. 相似文献
102.
V. Sekkar K. Narayanaswamy K. J. Scariah P. R. Nair K. S. Sastri How Ghee Ang 《应用聚合物科学杂志》2006,101(5):2986-2994
Hydroxyl‐terminated polybutadiene (HTPB)‐based allophanate–urethane networks were prepared by reacting HTPB with di‐isocyanates, such as toluene–di‐isocyanate (TDI), isophorone–di‐isocyanate (IPDI), and 4,4′‐di(socyanatocyclohexyl)methane (H12MDI) at stoichiometric ratios (r‐values) ranging from 1.0 to 1.5. The networks were characterized for mechanical and swell properties. The network parameters, such as “X,” which is the fraction of urethane groups involved in the allophanate formation, and effective chain length (Lx) were calculated from experimental crosslink density values determined from swell data, using α‐model equations developed by Marsh. Excellent linear correlations were obtained between mechanical properties and the calculated network parameters. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 2986–2994, 2006 相似文献
103.
Keiichi Tomishige Shogo Kanazawa Motoki Sato Kenji Ikushima Kimio Kunimori 《Catalysis Letters》2002,84(1-2):69-74
Pt(0.3)/Ni(10)/Al2O3, prepared by a sequential impregnation method, exhibited a more excellent performance in methane reforming with CO2 and O2 in terms of the catalytic activity and the temperature profile of the catalyst bed than Pt(0.3) + Ni(10)/Al2O3 prepared by a coimpregnation method, Ni(10)/Al2O3, Pt(0.3)/Al2O3, and Pt(10)/Al2O3. It is thought that this is because the surface Pt atoms on Ni catalyst can contribute to the enhancement of the catalyst reducibility. 相似文献
104.
The direct conversion of methane to higher hydrocarbons over a silica-supported Ru catalyst has been investigated via an oxygen free, two-step route. The reaction consists of decomposition of methane over a 3% silica-supp orted Ru catalyst at temperatures
between 400 and 800 K to produce surface carbonaceous species followed by rehydrogenation of these species to higher hydrocarbons at
of 368 K. It was found that the Ru/SiO2 catalyst exhibits a trend similar to that for single-crystal Ru catalysts. However, the temperature at which a maximum in ethane selectivity occurs shifts toward a higher temperature. It was also found that the ethane yield can be optimized by changing the surface carbon coverage. Under optimum conditions a net ethane yield of about 13–15% has been realized. For this two-step reaction sequence, only a few reaction cycles could be operated without intermediate high temperature rehydrogenation and without significant loss in ethane yield. This is attributed to large amounts of inactive carbon that could not be hydrogenated at 368 K. Higher methane partial pressures were found to be desirable for this reaction. The activity of the catalyst could also be maintained at total pressures up to 10 atm. 相似文献
105.
以郑庄区块东大井区为主要研究对象,综合运用实验测试数据、煤田钻孔及煤层气井资料,并结合沉积、构造和地下水动力的原理和方法,深入分析了该区煤层含气量分布和主控地质因素。研究结果表明:研究区煤层含气量较高,总体呈自东向西逐渐增大的趋势,且主要受煤层埋藏深度、地质构造和水动力条件三个因素控制。即煤层埋深对含气量分布具有较好的控制作用,总体上含气量高值区大都位于北部深埋区域;地质构造对含气量的影响主要表现为次级构造叠加在煤层埋深影响的总体背景之上导致含气量展布复杂化;北部地区水动力条件对煤层气的运移和富集具有显著的控制作用,是影响煤层含气量展布的主要因素;而南部地区则由于埋深和断层等因素的影响,从而导致水动力条件与煤层含气量的相关性不太明显。 相似文献
106.
煤层气储层的裂隙发育程度与储层的地球物理测井响应特征相关,通过对沁水盆地郑庄区块80余口井测井资料的分析,总结了地质构造作用及裂隙发育对测井特征的影响,认为研究区识别煤层气储层裂隙的敏感参数依次为体积密度(DEN)、深侧向电阻率(RD)、声波时差(AC)、井径(CAL)、自然伽马(GR)、中子孔隙度(CNL)等,通过判断深、中、浅三个电阻率值的差异识别裂隙发育程度,建立了夹矸层RD≥3000 Ω·m、3000Ω·m>RD≥1000Ω·m、1000Ω·m>RD≥500Ω·m、RD<500Ω·m、及CNL> 45%等几种类型的测井响应参数,给出了相应的测井响应示例,为建立研究区的裂隙发育展布提供了参考. 相似文献
107.
108.
Intensification of low-grade methane enrichment in nitrogen mixture by CH4/CO2 displacement
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To solve the problem of CO2 uncompleted desorption in the process of CO2 displacement enhancing the adsorption separation of CH4/N2, a small amount of product gas CH4 was used as purge gas to improve the CO2 desorption. CH4/CO2 mixture gas obtained from desorption step was recycled as the displacement gas to enhance the enrichment of low-grade methane in nitrogen mixture. In this work, the research conducted the experiments for CH4/N2 separation using CH4/CO2 displacement intensification adsorption and the laboratory-made coconut shell activated carbon as sorbent. The mathematical models were built in gPROMS and the accuracy of models was verified by comparison of simulations and CH4/N2/CO2 breakthrough experiments. The performance of enrichment of low-grade methane with displacement intensification using different displacer was compared. The result showed that the process with CH4/CO2 displacement had higher purity product than CO2 displacement. The CH4/ CO2 mixed gas replacement enhanced vacuum pressure swing adsorption cycle experiment was carried out, which can jointly enrich 14% CH4/ N2 and 53% CH4/CO2 to 98.8%, and at the same time obtain a recovery rate of 77.8%. 相似文献
109.
110.
陈文礼 《单片机与嵌入式系统应用》2013,(10):54-56
介绍一种便携式多气体检测仪的设计方案,使用PIC18LF6620作为核心处理器,同时连续检测O2、CO、H2S、CH4四种气体的浓度。详细介绍了气体传感器工作原理及其信号处理电路。经过实际测试,该检测仪具有体积小、重量轻、灵敏度高、响应速度快、测量精确等优点。 相似文献