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排序方式: 共有5900条查询结果,搜索用时 46 毫秒
81.
D. Miceli F. Arena A. Parmaliana M. S. Scurrell V. Sokolovskii 《Catalysis Letters》1993,18(3):283-288
Precipitated silica catalysts loaded with either MoO3 (0.2–4.0 wt%) or V2O5 (0.2–5.3 wt%) have been studied in the selective partial oxidation of methane to formaldehyde with molecular oxygen at 520 °C. The functionality of the SiO2 surface towards the formation of HCHO is significantly promoted by V2O5, while it is depressed by the MoO3. 相似文献
82.
甲烷磺酸电镀Sn-Pb合金添加剂研究 总被引:4,自引:1,他引:4
介绍了国内外磺酸型Sn-Pb合金电镀添加剂近十年的研究历程现况并根据各组分的化学结构及其在电镀中所体现出的性质将添加剂分为Sn^2 离子稳定剂、光亮剂及分散剂三类。最后列出了新研制的甲烷磺酸Sn-Pb合金电镀添加剂的主要性能及具体工艺配方。 相似文献
83.
The influence of the addition of 1–10 vol.% of hydrogen or carbon dioxide to the feed during the partial oxidation of methane was studied over a NiO/γ-Al2O3 catalyst. The addition of H2 decreases the conversion and syngas selectivity. This decrease of performance seems to be related to a higher reduction of the catalyst due to the H2 co-feeding. The addition of CO2 also appears unfavorable to the production of hydrogen but increases the CO yield. A combination of the dry reforming and the reverse water gas shift reactions is suggested to explain the observed modifications in the product yields. 相似文献
84.
85.
Isotopic transient techniques were applied to study oxidative coupling of methane over lanthanum oxide and strontium promoted La2O3 catalysts. Results of the18O2/16O2 isotopic exchange experiments indicate that Sr promotion increases oxygen uptake from the lattice of the catalyst. Oxygen self diffusion coefficients, which were determined for the series of lanthana catalysts, reach a maximum for the 1% Sr/La2O3. Steps of18O2 in the presence of a steady flow of methane over Sr/La2O3 catalysts, indicate that surface and bulk oxygen appear in the reaction products before gas-phase18O2. Steps of CO2 over catalysts in which lattice oxygen has been exchanged with18O2, show that gas/solid exchange involves over 50% of the lattice oxygen. Under reaction conditions, methane pulses with no gas-phase oxygen yield negligible amounts of products which indicates that methane interacts with lattice oxygen only in the presence of the gas-phase oxygen. 相似文献
86.
The effect of preparation method on MnO
x
–CeO2 mixed oxide catalysts for methane combustion at low temperature was investigated by means of BET, XRD, XPS, H2-TPR techniques and methane oxidation reaction. The catalysts were prepared by the conventional coprecipitation, plasma and
modified coprecipitation methods, respectively. It was found that the catalyst prepared by modified coprecipitation was the
most active, over which methane conversion reached 90% at a temperature as low as 390 °C. The XRD results showed the preparation
methods had no effect on the solid solution structure of MnO
x
–CeO2 catalysts. More Mn4+ and richer lattice oxygen were found on the surface of the modified coprecipitation prepared catalyst with the help of XPS
analysis, and its reduction and BET surface area were remarkably promoted. These factors could be responsible for its higher
activity for methane combustion at low temperature. 相似文献
87.
Ten selected samples with varying types and amounts of organic matter from two Miocene lacustrine basins in northwestern Turkey were analyzed by programmed-temperature open-system pyrolysis to determine methane generation potential and reaction kinetics. Open-system pyrolysis was performed at heating rates 0.1, 0.7 and 5.0 K/min, where generated gases were measured using an on-line gas chromatograph. Frequency factors and activation energy distributions of reaction kinetics for methane generation from the investigated lacustrine coals and sedimentary rocks indicated that type of kerogen controls the sequential order of methane generation. Methane from Type-III kerogen is generated at lower temperatures, which will be followed by methane from Type-II and Type-I kerogen. Methane generation potentials in the range 14-35 mg CH4/g TOC correlates also with type of organic matter. For Type-III kerogen up to 28% of the total hydrocarbon generation potential belongs to methane. The respective value is only 2% for a Type-I kerogen. 相似文献
88.
着重介绍红外探测系统的总体设计思想、微弱信号的检测技术及检测系统的软、硬件设计,对如何应用单片机ATMEGA16芯片作微控制器,来完成数据的采集、处理判断、数据的显示和传输等一系列功能作了重点的阐述和分析.针对目前大多数设备不具备数据传输这一特性,重点对RS485总线方式作了阐述,并采用了RBF神经网络的方法对温度进行了补偿,提高了测量精度,达到了理想的效果. 相似文献
89.
磁西勘查区主采煤层煤层气赋存特征 总被引:3,自引:2,他引:1
据勘探研究磁西勘查区主采煤层既是煤层气源岩,又是其储集层,煤层有机显微组分以镜质组为主,煤的变质程度为中~高变质的烟煤~无烟煤,生气量较高,为高瓦斯矿区。本区以正断层为主,断层使煤层与泥质岩层接触,具有一定的封闭性。煤层埋深较大,主采2号煤层直接顶板为泥岩、粉砂岩,岩性致密,透气性较差,有利于煤层气资源的保存,从而使煤层气含量升高。 相似文献
90.
在分析白额地区2#煤储层空间发育特征、储层物性特征、含气量分布特征及区域构造背景的基础上,对煤层气成藏控制因素进行分析。结果表明:构造演化史直接控制着煤储层埋藏史及生烃史,是煤层气成藏主控因素;地下水水动力特征和围岩封闭特征决定了煤层气藏的保存条件,是煤层气成藏的关键;综合以上特征,可以得出2#煤煤层气藏为单斜-水动力封堵型煤层气藏。 相似文献