三氯化铁分光光度法测定药物中亚甲基二膦酸

通过三氯化铁与亚甲基二膦酸形成络合物,采用分光光度法,建立了注射用亚锡亚甲基二膦酸盐冻干药盒中亚甲基二膦酸含量的测定方法。结果表明,亚甲基二膦酸质量浓度在0.02~0.08 g/L范围内与吸光度A呈良好线性关系,线性回归方程y=14.61x+0.029 7,线性相关系数r=0.999 1。加标回收率为98.8%~102.0%,相对标准偏差为0.97%(n=6)。该方法可用于快速准确地测定注射用亚锡亚甲基二膦酸盐冻干药盒中亚甲基二膦酸的含量。     

糠醛渣基磁性多孔炭的制备及其吸附性能研究

以糠醛渣为原料,通过氯化镍浸渍和氯化锌活化制备了糠醛渣衍生的磁性多孔炭。结果表明,制备的多孔炭不仅具有磁性,还含有丰富的官能团和多孔结构;当浸渍后原料与氯化锌的质量比为1∶2时,比表面积达1051 m²/g,45 ℃下对亚甲基蓝的吸附量可达732.5 mg/g,且吸附过程符合准二级动力学方程和Langmuir等温吸附模型。     

棒束通道内定位格架搅混特性PIV可视化研究

定位格架作为燃料组件中重要的组成部件之一,不仅在结构上固定燃料棒,而且在燃料组件内热工水力性能同样显著,特别是对工质的搅混性能直接关系到反应堆的经济性和安全性,因此有必要对燃料组件内定位格架搅混特性进行研究。本文通过粒子图像测速（PIV）技术开展了棒束通道内定位格架上下游流场的可视化研究,对比了有无格架棒束通道内流场的分布特征,定量分析了定位格架对棒束通道流场搅混的贡献。对不同流速下定位格架下游横纵速度的沿程变化特性进行研究,发现了不同流速作用下定位格架对横向、轴向速度的促进和抑制规律。另外,通过速度均方根对下游的湍流特性进行了评估。实验结果可为数值计算提供全场的数据验证,并可为定位格架设计和优化提供基础。     

TiO2/膨胀石墨复合材料的制备及其对亚甲基兰的光催化降解

采用快速升温法制备出以膨胀石墨为载体的TiO2/膨胀石墨光催化剂,用SEM及XRD对其表面形貌及结构进行表征,研究了该负载型光催化剂在紫外光照射下的催化能力,探讨了在催化剂中TiO2的负载量、亚甲基兰溶液的初始浓度及其pH值对光催化剂的降解能力的影响.结果发现,负载量为10%的光催化剂对40mg/L的亚甲基兰溶液5h的光降解率达到58.8%.     

Authentication of the anti-tumor herb Baihuasheshecao with bioactive marker compounds and molecular sequences

Baihuasheshecao (Hedyotis diffusa), a Chinese herb for cancer treatment, is frequently adulterated by a related species Hedyotis corymbosa. DNA sequencing of the complete internal transcribed spacer region was applied to differentiate H. diffusa from H. corymbosa and other closely related species. The molecular data showed that four out of seven herb samples of Baihuasheshecao were adulterants. Chemical analyses by TLC and HPLC were used to authenticate H. diffusa and H. corymbosa. Two marker compounds were identified exclusively in H. diffusa: 6-O-(E)-p-coumaroyl scandoside methyl ester (compound 1) and 10(S)-hydroxypheophytin a (compound 2). Both compounds showed moderate anti-proliferation effect on PC3 human androgen-independent prostate cancer cells, while compound 2 also showed strong anti-proliferation effect on LNCaP human androgen-sensitive prostate cancer cells. Accordingly, these bioactive marker compounds could be applied to verify the authenticity and assess the quality of Baihuasheshecao.     

A Flower-like In2O3 Catalyst Derived via Metal–Organic Frameworks for Photocatalytic Applications

The most pressing concerns in environmental remediation are the design and development of catalysts with benign, low-cost, and efficient photocatalytic activity. The present study effectively generated a flower-like indium oxide (In₂O₃-MF) catalyst employing a convenient MOF-based solvothermal self-assembly technique. The In₂O₃-MF photocatalyst exhibits a flower-like structure, according to morphology and structural analysis. The enhanced photocatalytic activity of the In₂O₃-MF catalyst for 4-nitrophenol (4-NP) and methylene blue (MB) is likely due to its unique 3D structure, which includes a large surface area (486.95 m² g⁻¹), a wide spectrum response, and the prevention of electron–hole recombination compared to In₂O₃-MR (indium oxide-micro rod) and In₂O₃-MD (indium oxide-micro disc). In the presence of NaBH₄ and visible light, the catalytic performances of the In₂O₃-MF, In₂O₃-MR, and In₂O₃-MD catalysts for the reduction of 4-NP and MB degradation were investigated. Using In₂O₃-MF as a catalyst, we were able to achieve a 99.32 percent reduction of 4-NP in 20 min and 99.2 percent degradation of MB in 3 min. Interestingly, the conversion rates of catalytic 4-NP and MB were still larger than 95 and 96 percent after five consecutive cycles of catalytic tests, suggesting that the In₂O₃-MF catalyst has outstanding catalytic performance and a high reutilization rate.     

纳米二氧化钛薄膜协同接触辉光放电技术降解亚甲基蓝

通过溶胶-凝胶法制得纳米TiO_2薄膜,研究了日光条件下亚甲基蓝在薄膜上的光催化降解以及在TiO_2协同接触辉光放电条件下的降解,结果表明:镀膜5次所得薄膜具有高的催化性能;TiO_2协同接触辉光放电可以高效地降解亚甲基蓝分子;所制得的薄膜随使用次数的增加而活性变化不大。     

联结基团含羟基的季铵盐Gemini表面活性剂的合成及胶团化行为研究

合成了一种联结基团为含羟基亚甲基链的季铵盐Gemini表面活性剂,即C12-3(OH)-C12.2Cl,用红外光谱、核磁共振及元素分析对它们的结构进行了鉴定,并对影响反应的因素进行了讨论,得出了合成C12-3(OH)-C12.2Cl的最佳条件为十二叔胺:十二叔胺盐酸盐:环氧氯丙烷摩尔比为2.0∶1.0∶1.0,以正丙醇为溶剂,在回流温度下反应3 h,产率可达94.5%以上;采用表面张力法、瞬态荧光法研究了C12-3(OH)-C12.2Cl在水溶液中的胶团化行为,发现C12-3(OH)-C12.2Cl的胶团生成能力远比其单体强,cmc值降低一个数量级,胶团聚集数随表面活性剂浓度增大而增大。     

亚甲蓝分光光度法测定工业废水中阴离子洗涤剂的改进方法

以简化操作步骤,改进实验方法为目的。采用机械搅拌萃取的方法,节省了劳动力和工作时间,重要的是由于机械萃取更加彻底,不仅可以减少试验中每个样品中阴离子洗涤剂的加入量,也可大幅度提高实验的操作精度。另外,整个萃取过程可在通风橱内完成,避免了传统手工震摇方法,因三氯甲烷挥发而给实验操作人员造成的毒害。因此是对之前所有亚甲蓝分光光度法测定阴离子洗涤剂方法的一个提升和改进。     

三维整体经编夹芯结构预制件的制备工艺

在传统经编间隔织物研究的基础上进行玻纤经编间隔织物的研究,包括玻纤原料的选用、织物组织结构设计、上机试验编织的研究等。结果表明：优化设计经编间隔织物结构,选用细度较小、捻度较小的玻璃纤维纱并在编织过程中对玻纤采取适当的润滑处理,可大大减小玻纤因脆性大,起静电,易钩毛引起的断纱。同时,上机织造时选择利于编织的成圈机件配置,优化织针形状,合理调节上机过程中牵拉与送经参数的配置关系,选用较大的牵拉角度,可以较好的改善玻纤的编织性能,提高三维整体经编预制件的成型质量,为实际生产提供参考价值。