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71.
A feasibility analysis methodology adopted from reactive distillation is applied to membrane reactors. A model is formulated to depict the reactive liquid phase composition on the retentate side of a continuous type membrane reactor. The effects of both the chemical reaction kinetics and the membrane mass transfer kinetics on the feasible products are elucidated by means of retentate phase diagrams and bifurcation analysis. The proposed method can be applied to various membrane processes, independent of the specific structure of the membrane. Two quaternary reaction systems are considered to illustrate the methodology. In the first hypothetical system, it is shown how selective membranes can influence the sequence of effective volatilities which in turn affects the feasible products of the system. In the second example of practical importance, i.e. the heterogeneously catalysed synthesis of propyl acetate coupled with permeation through a porous polycarbonate membrane, the dusty gas model is applied to describe the component fluxes through the membrane. For the latter reaction system, the existence of reactive arheotrope is demonstrated. Arheotropes represent mass transfer controlled feasible products of membrane separation process. 相似文献
72.
�Ĵ������Ȼ�����������б�����Դ̽�� 总被引:11,自引:0,他引:11
本文应用天然气中甲烷、乙烷的碳同位素,甲烷的氢同位素,汞含量及天然气成分等指标,探讨了四川盆地天然气成因分类;并结合地质情况对气源层进行了探讨。 相似文献
73.
J Schlipf 《Bulletin of Materials Science》1989,12(3-4):185-193
A model for propagating deformation bands is developed, based on a mechanical equation of state and on evolution equations
for the structure parameters. It is shown that, contrary to normal deformation, it is necessary to discriminate between global
parameters which depend solely on time elapsed and local parameters which are functions of the strain history. Correspondingly,
two sets of equations are presented, one describing the development of the global parameters in the course of time, the other
giving the evolution of the local state parameters in the course of deformation, i.e. as a function of strain. Measurable
quantities derived from the first set are the load serrations and the band velocity, while the second set yields the flow
stress and the strain profile of the propagating band. 相似文献
74.
75.
A numerical solution of the inverse problem of the gravitational field at a single point is obtained using six field elements
for a point, a spherical cap, a differential spherical sector and a vertical segment. In the system of six equations obtained,
the unknowns are the mass of the body, the depth of its center, and the second, third, and fourth degree moments. The accuracy
of the solution of this system is ten times higher than when using three field elements.
__________
Translated from Izmeritel’naya Tekhnika, No. 5, pp. 3–8, May, 2007. 相似文献
76.
The paper is devoted to the effect of compressibility of the avalanche snow impacting an obstacle. Compression shocks generated by obstacle cause high pressure peaks at first instants of impact. That is why the account of compressibility is essential for the understanding of measurements and the design of structures. The main problem in calculation compression shocks in avalanches is to formulate an equation of state for moving snow in impact. Two different types of equations of state are proposed depending on the type of the avalanche (low-density and high-density flows). The approach is not totally new. It was earlier proposed mainly in Russian literature. Here a brief review of the previous work is given with discussion of some gaps in it. The theory is reformulated and further developed to account thermodynamical equations. The simplest case of a normal compression shock in an avalanche flow is studied. Examples of estimations of pressure and density behind a shock are given. It is important to emphasize that the Mach number plays an important role in the theory of compressible flows so it should be taken into account (together with the Froude number) in calculation and modelling an avalanche impact pressure. 相似文献
77.
A comparative study of numerical solutions to non-linear discrete crack modelling of concrete beams involving sharp snap-back 总被引:1,自引:0,他引:1
Numerical problems are often encountered in modelling crack propagation in concrete beams using non-linear finite element (FE) analysis, especially when sharp snap-back behaviour in load-displacement relations occurs. This paper firstly identifies 16 arc-length control based numerical strategies based on extensive literature review. They are then used to carefully model the structural behaviour of a four-point single notched shear beam using discrete crack modelling approach in which cracks are represented by interface elements with bilinear softening constitutive laws. Based on extensive FE analyses, detailed comparisons of the merits and demerits of these numerical algorithms are then made. The results indicate that the effectiveness and efficiency of different algorithms may vary considerably from one to another, with the local arc-length based procedures in conjunction with tangential stiffness strategy and reversible unloading model being the most robust. 相似文献
78.
Lawrence K. Forbes Graeme C. Hocking Simon Wotherspoon 《Journal of Engineering Mathematics》2004,48(1):69-91
Rainwater can collect in a lens-shaped region within the rock of a tropical island, and may be separated from the underlying salt water by a sharp interface. This paper presents a nonlinear theory for determining the shape of this interface. The island is assumed to be saturated with rain, and provision is made for the outflow of rain-water through the sides of the island. The effect of a bore well on the shape of the interface is investigated, and the problem is solved using a spectral method. An integral-equation method is also presented for the case when the island has infinite width. 相似文献
79.
Dongchang Sun Liyong Tong 《International journal for numerical methods in engineering》2004,60(11):1911-1932
A novel finite element model is presented for static and dynamic analysis of composite plates integrated with a laminated piezoelectric layer, a host laminated composite plate and an adhesive layer between them. A new adhesive element is developed which includes both peel and shear effects in the adhesive layer based on first‐order shear deformation plate theory. The thin adhesive layer between the piezoelectric layer and the host plate is modelled by assuming that it carries constant shear and peel strains throughout its thickness. In addition, a weighted static shape control scheme for finding the optimal voltage distribution for static shape control is given. By selecting different weighting matrices, a variety of items such as displacements, slopes, curvatures, strains and even generalized forces, can be included in finding the optimal actuating voltage for static shape control. The present model is validated by comparing with those results available in the literature. The numerical results show that the weighted linear least method can give a satisfactory voltage distribution to best match the desired shape. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
80.
Visual evaluation experiments of color discrimination threshold and suprathreshold color‐difference comparison were carried out using CRT colors based on the psychophysical methods of interleaved staircase and constant stimuli, respectively. A large set of experimental data was generated ranged from threshold to large suprathreshold color difference at the five CIE color centers. The visual data were analyzed in detail for every observer at each visual scale to show the effect of color‐difference magnitude on the observer precision. The chromaticity ellipses from this study were compared with four previous published data, of CRT colors by Cui and Luo, and of surface colors by RIT‐DuPont, Cheung and Rigg, and Guan and Luo, to report the reproducibility of this kind of experiment using CRT colors and the variations between CRT and surface data, respectively. The present threshold data were also compared against the different suprathreshold data to show the effect of color‐difference scales. The visual results were further used to test the three advance color‐difference formulae, CMC, CIE94, and CIEDE2000, together with the basic CIELAB equation. In their original forms or with optimized KL values, the CIEDE2000 outperformed others, followed by CMC, and with the CIELAB and CIE94 the poorest for predicting the combined dataset of all color centers in the present study. © 2005 Wiley Periodicals, Inc. Col Res Appl, 30, 198–208, 2005; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/col.20106 相似文献