CaO-SiO2系玻璃的析晶动力学研究

利用溶胶-凝胶法制得CaO-SiO2系基础玻璃,通过差热分析曲线分析质量比为CaO-SiO2玻璃的析晶能力。经分析,其析晶活化能E=457.1kJ·mol-1,而晶化生长指数是随升温速率的不同而不同,速率越大,晶化生长指数越小。     

电子陶瓷和器件的低温共烧技术

较系统地介绍了电子器件用低温共烧陶瓷(low temperature cofired ceramics,LTCCs)材料,探讨了其工艺中的若干问题。电子器件用低温共烧陶瓷材料包括:玻璃/陶瓷复合材料、结晶化玻璃、晶化玻璃/陶瓷复合材料以及液相烧结陶瓷,其中典型的和最为常用的LTCCs为玻璃/陶瓷(特别是氧化铝)复合材料。正在研究的一些陶瓷介质材料中,Bi基介质材料引起了人们的关注。玻璃/陶瓷复合材料的制备工艺中,应当着重关注和加深了解玻璃的流动性和结晶性、玻璃的起泡、玻璃和陶瓷颗粒间的反应、共烧材料的匹配等问题,从优选材料配方和优化工艺着手,从而获得优质可靠的材质和器件。     

ZrO2对CaO-SiO2系玻璃析晶的影响

通过DSC曲线研究了不同含量的ZrO2对CaO-SiO2系玻璃析晶的影响,根据JMA方程计算动力学参数(如析晶活化能E、频率因子ν、晶化指数n)。从计算结果可以看出,随着ZrO2含量的增加,析晶活化能E减少,而频率因子ν和晶化指数n增加。当ZrO2含量为7%时,E值最小:235.58kJ/mol;n值最大:4.70。说明ZrO2在CaO-SiO2玻璃体系是有效的晶核剂。     

影响结晶化玻璃板材质量因素的分析

研究了烧结法生产结晶化玻璃装饰板材中的气孔、翘板及炸裂产生的原因以及解决的方法。     

一种测量透明平行平板折射率的新方法

通过测量激光细光束经平行平板玻璃所产生的位移,可确定平行平板的的折射率。本文阐述了该方法的测量原理,给出了测量公式,并详细分析了测量误差。计算机模拟计算结果表明,当平板厚度为50mm时,如果入射角测量标准偏差为1”,平板厚度和光线位移量测量标准偏差均为0.001mm,则折射率测量的标准偏差可达6×10~(-5),此时入射角约55°。     

Experiences with Mathematical Modeling of Electro- Boost in Glass Furnaces

The goal of the latest strategy in glass companies is to decrease the cost of production while maintaining or increasing the glass quality. One of the perspective ways is to install the electric boosting into the existing furnace or to build the new furnace including the electric boosting. This strategy may be surprising as electric energy is generally more expensive than gas or oil （considering the cost per unit energy） but because of efficiency of use （ direct glass - melt heating by Joulean heat） it is inevitably cost effective. The use of the CFD modeling capability for electro - boost designing is presented in this contribution. The Glass Service Glass Furnace Model （ GS - GFM ） is used for investigating the optimal electrode arrangement and phasing, and moreover, for increasing the glass quality during the electro - boost applying.     

直埋玻璃钢聚氨酯保温管及其保温层厚度设计

介绍了直埋玻璃钢聚氨酯保温管的结构形式及优良性能．为了降低玻璃钢聚氨酯保温管的初期投资,探讨了直埋玻璃钢聚氨酯热力管保温层的2种设计方法,并采用工程实例进行计算．结果表明,按双层保温计算法设计保温层更为经济合理．以上结论为直埋玻璃铜聚氨酯保温管保温层设计提供了理论依据．     

泡沫玻璃窑炉温度控制系统的设计与应用

针对泡沫玻璃生产线窑炉温度控制的工艺要求,设计并应用了P L C温度控制系统、P I D控制算法。现场应用表明,该系统运行稳定可靠,设计先进,界面友好,控制精度高,具有较高的实用价值,从而保证了产品的质量,降低了能耗,提高了企业竞争力。     

Cooling rate effects on the microstructure and phase formation in Zr51Cu20.7Ni12Al16.3 bulk metallic glass

A detailed transmission electron microscope (TEM) study has been conducted to investigate the microstructures of the Zr₅₁Cu_20.7Ni₁₂Al_16.3 metallic glass formed at different cooling rates. It has been found that the most competitive crystalline phase to the amorphous structure is an oxygen-stabilized FCC NiZr₂-type phase, which in turn acts as the leading phase to trigger the formation of other crystalline phases in the slow-cooled alloy.     

Fabrication of Er3+/Pr3+ Co-doped soda-lime glass thin films using RF magnetron sputtering method and optical property characterization

Er^3+/Pr³⁺ co-doped soda-lime glass thin films have been fabricated using RF magnetron sputtering method and their structural and optical properties have been studied. Deposition rate, crystallinity, and composition of glass thin films were investigated by scanning electron microscopy, transmission electron microscopy, and electron probe micro area analysis. Refractive index, birefringence and binding characteristics have been investigated using a prism coupler and X-ray photoelectron spectroscopy. Er³⁺/Pr³⁺ co-doped soda lime glass thin films were prepared by changing substrate temperature (room temp. ∼550^∘C), RF power (90 W–130 W), and Ar/O₂ gas flow ratio at processing pressure of 4 mTorr. Glass thin films could be obtained at the optimized processing condition at 350^∘C, RF power of 130 W, and gas flow of Ar:O₂ = 40:0 with maximum deposition rate of 1.6 μm/h. Refractive index and birefringence increased from 1.5614 to 1.5838 and from 0.000154 to 0.000552, respectively, as the content of Pr³⁺ increased. Binding energy of Pr3d also increased as the content of Pr³⁺ increased.