ZnO薄膜的制备和结构性能分析

ZnO作为一种宽带隙半导体材料,近几年来已经成为国际上紫外半导体光电子材料和器件领域的研究热点.激光分子束外延(L-MBE)系统是获得器件级ZnO外延薄膜的先进技术之一.高质量精密ZnO陶瓷靶材对于该工艺的实施是十分关键的,本文中采用高纯原料,在洁净条件下制备了大面积、薄片型、尺寸可控的符合理想化学配比的高纯ZnO陶瓷靶材.采用所制备的靶材,利用L-MBE技术在(0001)蓝宝石基片上进行了ZnO薄膜的外延生长,在280 ℃～300 ℃低温条件下所生长的薄膜样品具有(0001)取向的纤锌矿晶体结构,薄膜光学性能良好,论文中对ZnO薄膜的低温L-MBE生长机理进行了探讨.     

蒸发式冷凝器结构特点及工程应用

本文对蒸发式冷凝器的结构、工作原理及安装、使用过程中应注意的问题作一下介绍.并结合工程实例,对蒸发式冷凝器和水冷式冷凝器作综合比较.     

离子束溅射淀积光学薄膜的膜厚均匀性实验

介绍了离子束溅射技术改善薄膜均匀性的两种方法。研究了修正板技术,根据工程需要将修正板技术应用于行星转动条件下的光学薄膜的均匀性修正。分别研究了靶摆动和不摆动的情况下,淀积薄膜的均匀性修正。实验结果表明,修正后的均匀性结果优于 1%,能满足实际应用的要求;靶摆动修正的均匀性结果优于修正板技术。     

微波固化环氧树脂(E44/DDM)的热性能及膨胀性能

利用微波辐照固化环氧E44／二苯甲烷二胺(DDM)体系，考察了固化温度、固化时间以及微波功率之间的关系，分析了固化过程。利用FT-IR、DSC、热膨胀仪分别表征了体系的固化度、玻璃化转变温度(Tg)、热分解温度以及热膨胀系数(α)。结果表明，与热固化过程相比，微波能显著提高E44／DDM的固化速度，缩短凝胶化时间。且微波固化物具有较高的热分解温度和较低的线膨胀系数α。     

低温反相悬浮合成AA/AM共聚型吸水树脂

采用氧化还原引发体系，反相悬浮法低温合成AA／AM共聚型吸水树脂。研究了不同引发体系、单体组成、交联剂和引发剂浓度、温度、单体中和度对共聚物吸液能力的影响。与单一引发剂相比，采用复合引发体系，反应温度降低，聚合时间缩短，产物吸水速度和吸液能力高于聚丙烯酸钠，保水性略低于后者。共聚物最大吸液能力为：Q去离子水=970mL／g，Q生理盐水=129mL／g，Q人工尿=130mL／g。     

Ni-Cr-Al合金在1000℃空气中的氧化

研究了两种不同Cr含量的常规熔炼Ni-Cr-Al合金在1000℃空气中的氧化行为.合金氧化动力学遵循抛物线规律,Ni-20Cr-2.5Al合金在1000℃的氧化增重略小于Ni-15Cr-2.5Al合金,二者的氧化增重都明显小于Ni-20Cr合金.Ni-20Cr-2.5Al合金1000℃氧化后形成了外层的Cr2O3及内层极薄的Al2O3型氧化膜,在Ni-Cr合金中加入Al,由于Cr、Al的相互作用,降低了形成Cr2O3和Al2O3外氧化膜所需的Cr或Al的临界含量,促进了保护性Al2O3或Cr2O3膜的生成.     

Development of a system for measurement of permeability of aroma compounds through multilayer polymer films by coupling dynamic vapour sorption with purge‐and‐trap/fast gas chromatography

A system for measurement of permeability of aroma compounds through laminated polymer films was constructed by combining dynamic vapour sorption (DVS) with purge‐and‐trap/fast gas chromatography (P&T–fGC). Data validation was achieved by measuring the permeability of limonene across an HDPE film (film C) and comparing the permeation data with the literature values. The general applicability of this system, as well as its potential for simultaneous measurement of permeability of multiple aroma compounds, was demonstrated by measuring the permeability of limonene and ethyl butyrate as single permeants or as co‐permeants under different environmental conditions (at 25°C, 30°C or 35°C and 0% or 75% RH) through three different multilayer polymer films (film A, HDPE/EVOH/HDPE/HDPE; film B, HDPE/nylon/HDPE/HDPE; film C, HDPE/HDPE). The results showed that the aroma barrier performance of plastic films was determined by the polymer composition and was affected by various factors, such as temperature and the presence of other co‐permeants. Simplicity, speed and accuracy were some of the attractive features of this system, which indicates its potential as a useful tool that could be applied in the food industry for screening or selection of appropriate packaging materials for specific applications. Copyright © 2004 John Wiley & Sons, Ltd.     

Preparation of β-Fesi2 thin film by metal organic chemical vapor deposition using iron-carbonyl and mono-silane

β-FeSi₂ films were deposited at 750 °C by a supplying Fe(CO)₅ and SiH₄ simultaneously during metal organic chemical vapor deposition (CVD). Films could be deposited using this precursors system, even though film deposition was not ascertained by the single supply of Fe(CO)₅. Fe(CO)₅ was probably decomposed in gas phases before it reached to substrate surface. It was suggested that a kind of intermediate reactant which was more stable than Fe(CO)₅ created by the simultaneous supply of Fe(CO)₅ and SiH₄ makes Fe-Si films. Epitaxial β-FeSi₂ films were obtained on Si(111) substrates, and neither carbide nor oxide phases were detected on XRD patterns.     

Surface analysis of β-FeSi2 layer epitaxially grown on Si(100)

The epitaxial growth process of β-FeSi₂ on Si(100) surface under ultrahigh vacuum condition has been studied by low energy electron diffraction (LEED) and low energy ion scattering spectroscopy (LEIS). The LEED pattern of Si (100)-2×1 changes into amorphous structure with Fe deposition of about 10 Å at room temperature. With annealing at 540 °C, the LEED pattern shows 2×2 structure corresponding to the formation of the epitaxial β-FeSi₂ (100) template layer. The α-scan in Li⁺-LEIS and X-ray diffraction (XRD) study strongly suggest that the topmost surface of the 2×2 structure is terminated by Si atoms. By XRD, it is shown that the β-FeSi₂ develops with characteristic orientation even if iron reactant is deposited onto the template surface.     

Formation and properties of AgInSe2 thin films by co-evaporation

The electrical and optical properties of silver indium selenide thin films prepared by co-evaporation have been studied. X-ray diffraction indicates that the as prepared films were polycrystalline in nature. The lattice parameters were calculated to be a=0.6137 and b=1.1816 nm. Composition was determined from energy dispersive analysis of X-ray. Silver indium selenide thin films were also prepared by bulk evaporation of powdered sample for comparative study. They have an optical band gap (E_g) of 1.25 eV and it is a direct allowed transition. Refractive index (n) and extinction coefficient (k) were calculated from absorption and reflection spectra. Steady-state photoconductivity was measured from 300 to 400 K. Carrier lifetime was calculated from transient photoconductivity measurements at room temperature at different intensities of illumination.