塑料包装应用及技术进展

塑料在包装领域有着广泛的应用，其中聚酯（PET）性能优良，应用领域不断扩大。介绍了塑料包装不断通现的新技术，以及塑料包装环保问题的几点思路。     

High resolution XPS characterization of chemical functionalised MWCNTs and SWCNTs

High resolution XPS analysis of chemical functionalised multi-wall carbon nanotubes (MWCNTs) and single wall carbon nanotubes (SWCNT) was done with ESCA300 (overall instrument resolution of 0.35 eV). Information to the degree of functionalisation was ascertained by argon ion bombardment of the samples followed by XPS analysis to detect the functional groups, the percentage atomic concentration of various elements present and whether or not the detected functional groups imposed a chemical shift on the CNT atoms. The results show that true chemical functionalisation was achieved and by argon ion bombardment these functional groups can be altered relative to the C 1s carbon atoms of the CNT. The choice of chemicals used for functionalisation, the techniques employed and the types of nanotubes treated are important factors in chemical characterisation. The carbon atom on the nanotube ring to which the functional group (atom) is bonded, the chirality of the CNT, the electronegativity of the functional group, the bond type and whether the CNT is single-wall or multi-wall, or cut (short) could play a role in determining the chemical shift on the CNTs atoms. These investigations are relevant to chemical functionalisation of carbon nanotubes for various applications for example DNA sensors and other biomedical sensors.     

110 dtex/36f抗菌POY纺丝工艺研究

讨论了干燥温度、纺丝温度、冷却成形条件等对纺丝的影响。指出预结晶温度为160℃,干燥温度为145℃时,干燥效果较好。螺杆各区温度比常规纺丝时低10℃,纺丝顺利。侧吹风速0.37m/s,风温25℃,风湿75%,丝条稳定;上油率达0.9%时,集束性较好。此抗菌纤维抑菌率达99.99%以上。     

基于单片机的PID温控系统在塑料挤出机中的应用

针对在塑料挤出过程中温度控制的重要性，介绍了一种新型的PID温度控制系统。该系统采用高性能单片机芯片，可以方便地对系统加热、冷却周期及PID的各个参数进行在线设定和修改，提高了塑料挤出机的温控精度。     

有机试剂结构与性质的研究：Ⅻ.有机试剂的pKa与改进的Hammett方程

有机试剂的ｐＫａ是其重要物化参数，是有机试剂酸碱性的度量，直接决定配合物的稳定性。应用改进的Ｈａｍｍｅｔｔ方程处理取代基常数与ｐＫａ的关系，得到满意的结果。     

高强度快干变性淀粉粘合剂的研究及在纸制品包装中的应用

本文介绍了高强度快干变性淀粉的制备原理和工艺,以及用该变性淀粉调配瓦楞纸板用粘合剂的方法和应用情况。讨论了变性淀粉粘合剂的初粘力,干燥速度等并与普通淀粉粘合剂作了比较。     

改性聚丙烯酰胺水溶液的疏水缔合性质

合成了一种疏水缔合水溶性聚丙烯酰胺共聚物，使用荧光光谱法并结合紫外及流变性实验，对制备的疏水缔合水溶性聚丙烯酰胺共聚物在水溶液中形成疏水微区、超分子聚集体及空间网络结构进行了研究，并用扫描电子显微镜证实了溶液中网络结构的存在．     

Electrochemical preparation of epinephrine/Nafion chemically modified electrodes and their electrocatalytic oxidation of ascorbic acid and dopamine

Two types of epinephrine and cyclized epinephrine quinone films have been prepared using cyclic voltammetry from the epinephrine in the strong acidic solutions and neutral aqueous solutions over different scanning potential ranges. The cyclic voltammogram of the epinephrine film is characterized by one redox couple at about +0.5 V (versus Ag|AgCl) and cyclized epinephrine quinone film exhibits one redox couples at about −0.15 V (versus Ag|AgCl) .In addition to cyclic voltammetry and an electrochemical quartz crystal microbalance (EQCM) were used to study the growth mechanism of the epinephrine and cyclized epinephrine quinone molecules. The electrocatalytic oxidation of catecholamines (dopamine and norepinephrine) and also ascorbic acid were investigated in acidic aqueous solutions using epinephrine films. The rotating ring-disk electrode technique was used to investigate the mechanism of electrochemical oxidation of dopamine and ascorbic acid.     

国外废旧塑料的再生利用

简述了废旧塑料的处理方法。着重介绍了世界工业发达国家,如美国、西欧、日本等国家近年来废旧塑料再生利用的情况及部分公司废旧塑料的再生回收技术。在世界性节能和节约资源的浪潮中,我国有关部门与行业应努力借鉴国外经验,开发废旧塑料的再生利用技术。     

新型AGR管材的性能及应用前景

新型供水管材-AGR管(亚克力共聚PVC管)，采用超微粒子丙烯酸树脂弹性体与PVC接枝共聚而成，在保持原有PVC刚性性能基础上，提高了低温冲击性能及卫生性能，可用于供水管、抗震管及其他饮料和化工流体的输送。