铒离子注入晶体硅的射程分布和离散研究

用400 keV能量的铒离子垂直注入晶体硅(Si)样品中。利用卢瑟福背散射技术研究了能量为400 keV、剂量为5×1015ions/cm2的铒离子注入Si晶体的平均投影射程、射程离散和深度分布。测出的实验值和TRIM 98得到的理论模拟值进行了比较,发现实验值跟TRIM 98模拟计算的理论值符合较好。     

RP/RE技术与比例式设计

RP/RE制造技术与设计美学的有机结合,形成了具有竞争力和规模化的设计业,提高了企业创新设计和产品市场开发的能力.运用RP/RE技术得到实体模型,再以设计美学原则对其进行分析、数据处理、美化形态,促进产品开发、研制和销售.工业产品的形态比例关系,受诸多因素的制约.分析了传统的比例设计方法的缺陷与不足,介绍比例式设计的原理、方法及其具体应用.表明比例式设计具有数理性强,计算方便、简捷,容易掌握的特点.而且能根据功能要求、技术参数和使用对象等因素,迅速找出产品的最佳比例值,有效地解决功能和形式之间的协调关系.     

用金属卟啉络合物引发合成高分子量聚醚

介绍了用四苯基卟啉铝络合物催化体系合成高分子量聚醚的方法。该聚合过程显示出一种持续特性。产物具有均一的链长和极窄的分子量分布，且数均分子量Ｍｎ可通过改变单体与引发剂的摩尔比来控制。     

凝胶色谱法表征我国几种有代表性超滤膜的截留率——分子量曲线

本文考察了凝胶色谱法的操作压力和进料流速的影响。对国内具有代表性的几种平板超滤膜(聚砜、聚砜酰胺、醋酸纤维素、聚丙烯腈、聚氯乙烯)以及聚砜中空纤维超滤膜的截留率——分子量曲线进行了测定。并给出它们的切割分子量数据。     

Change in the molecular weight distribution of poly(ethylene oxide) caused by the complexation with poly(acrylic acid)

The complexation between poly(ethylene oxide) (PEO) and poly(acrylic acid) (PAA) was made by using double the molar quantity of either polymer component at pH 2 where the resulting complex completely precipitates. After the removal of the precipitate, PEO or PAA remaining in the supernatant was subjected to gel permeation chromatography to investigate the change in the molecular weight distribution (MWD) caused by the complexation. No remarkable difference is observed in the MWD curves for PEO[1] (M_w=1.37 × 10⁴) before and after the complexation with PAA[1] (M_w=1.10 × 10³) and PAA[2] (M_w=4.16 × 10⁵). However, the MWD curves of PEO[2] (M_w=1.26 × 10⁵) and PAA[2] become shortened and shift to the low molecular weight side after the complexation with PAA[1] or [2] and PEO[2], respectively. This tendency is enhanced by increasing the complexation temperature. From these results, it is indicated that the complexation between PEO and PAA deals with an equilibrium reaction, and the equilibrium constant is dependent on the chain length of both polymer components and also on the complexation temperature.     

国内外聚乙烯醇工业的进展及市场展望

简述了国内外聚乙烯醇工业情况，介绍了聚乙烯醇及其衍生物的应用领域，展望了聚乙烯醇的发展形势和市场状况。     

Molecular modeling of antibody-antigen complexes between the Brucella abortus O-chain polysaccharide and a specific monoclonal antibody

A molecular model of the binding site of an anti-carbohydrateantibody (YsT9.1) has been developed using computer-assistedmodeling techniques and molecular dynamics calculations. Sequencehomologies among YsT9.1 and the Fv regions of McPC603, J539and human Bence-Jones protein REI, all of which have solvedcrystal structures, provided the basis for the modeling. Thegroove-type combining site model had a topography which wascomplementary to low energy confonners of the polysaccharide,a Brucella O-antigen, and the site could be almost completelyfilled by a pentasaccharide epitope in either of two dockingmodes. Putative interactions between this epitope and the antibodyare consistent with the known structural requirements for bindingand lead to the design of oligosaccharide inhibitors that probethe veracity of the modeled docked complex. Ultimately boththe Fv model and the docked complex will be compared with independentcrystal structures of YsT9.1 Fab with and without pentasaccharideinhibitor, currently at the stage of refinement.     

分子筛自控系统原理

介绍分子筛的主要用途,阐述分子筛自动控制原理及故障形成原理.     

The reduction/oxidation behaviour of MnAPO-5 as studied by ESR spectroscopy

It is shown by ESR spectroscopy that Mn²⁺ ions in MnAPO-5 are oxidized to Mn³⁺ during calcination atT475 K. Mn²⁺ occupies variously distorted tetrahedral positions within the framework and in extra-lattice sites. Octahedrally coordinated Mn²⁺ presumably located in the channels becomes detectable after adsorption of water. The ESR spectra of reduced MnAPO-5 show line-narrowing due to spin exchange interactions. The material behaves reversible in redox cycles at temperatures near 500 K.