High-Temperature Corrosion Resistance of Al–Re and Re Coatings

The oxidation behavior in air at 1473 K, and sulfidation behavior in a H2S–H2 gas mixture with a sulfur partial pressure of 10^–2 Pa at 973 K of Al–Re coated CMSX-4 were studied. Investigation on the sulfidation behavior of the Re-coated CMSX-4 was carried out in a H2S–H2 gas mixture with a sulfur partial pressure of 10^–2 Pa at 973 K. The experimental results show that a Re-rich alloy layer was formed between an -Al₂O₃ layer and the inner concentration zone of Ta and Ti for the CMSX-4 single crystal alloy with an Al–Re coating after oxidation. The Re-rich alloy layer containing Cr, W, Ni, Co, and Mo effectively inhibited the outward diffusion of alloying elements and the inward diffusion of Al. The Al/Re-coated CMSX-4 single crystal alloy had excellent sulfidation resistance; the Re-rich alloy layer, containing W, Ti, Ta, and Mo, which formed during the sulfidation process and located between the alumina scale and the CMSX-4 base alloy, plays a role in inhibiting the outward diffusion of alloying elements. The sulfidation resistance of CMSX-4 single-crystal alloy is greatly improved by a Re coating on the CMSX-4 alloy surface; this is attributed to a Re–Cr–W alloy layer that retarded the outward diffusion of cations and the oxide layer containing Ta, Ti, and Al, which inhibited the inward penetration of sulfur.     

SEBF/SLF系列重防腐涂料的特性和分析

本文介绍2种SEBF熔融结合环氧粉末涂料和2种SLF双组份液体涂料,辽宁的物理和化学性能及部分测试和评价方法.     

在纳米压入仪上进行悬臂梁法测量弹性模量的影响因素分析

对在纳米压入仪上进行悬臂梁法测量弹性模量的主要影响因素进行了综合分析,主要包括加载系统悬置弹簧刚度、压头压入、梁沿截面宽度方向挠曲、梁支座附加挠曲等影响。在考虑这些因素的基础上,得到了悬臂梁的有效挠度,利用有效挠度与载荷之间的关系,评价悬臂梁材料的弹性模量。对单晶硅(100)悬臂梁试样进行了实验,得到其弹性模量为155GPa±9.5%GPa,与参考文献值符合较好。表明在纳米压入仪上进行悬臂梁法测量,只有综合这些影响因素后,才能获得有效、准确的弹性模量测量结果。     

The application of thermal sprayed coatings for pig iron ingot molds

Molds made of gray cast iron for casting pig iron ingots are subjected to severe temperature fluctuations. The main life- limiting factor for mold damage is the formation of surface cracks arising from thermal fa-tigue. Various flame and plasma sprayed coatings were investigated to extend the life of these molds. Coating materials studied include plasma sprayed ceramic coatings with bond coats as well as flame sprayed oxidation- resistant alloy powders. The results of cyclic furnace tests from room temperature to 1100 °C in air, simulating the thermal cycle in casting, indicated that failure occurred along the interface between the bond coat and the gray iron substrate because of iron oxidation, and not at the interface between the ceramic top coat-ing and the bond coating for a superalloy substrate. The field test results indicated that plasma sprayed alumina coatings with 200 μm top coating thickness are the most promising materials for pig iron casting.     

High-temperature oxidation of aluminum electroplated Fe-Mn alloys

Austenitic Mn-Al alloys (20–32 W/O Mn, 7–10 Al, 2–3 Si, 1C) were found to have satisfactory oxidation resistance up to 950°C under isothermal conditions in air. Surface enrichment of aluminum is a necessary condition for obtaining an almost pure alumina scale for uses at higher temperatures. Four different Mn-steels were Al-coated by the Capuano electroplating process. In all the steels there was an increase in the hot-oxidation resistance. The best results were obtained with steels containing both Al and Si, and this for temperatures up to 1100°C. No spalling was noticed during rapid cooling of the test pieces. Silicon was found to act as a diffusion barrier to outward iron diffusion. It appears that there is formation of a pure, thin film of alumina from the matrix which interacts with the aluminum diffusing from the superimposed, coating for the formation of good bonds.     

舰船防腐涂料与涂装

根据舰船各部位的具体使用要求,确定了常用舰船配套体系和涂装方案,阐述了舰船涂料的主要发展趋势是向着高性能、易施工、经济、节能和环保的方向发展。     

高辐射耐热涂层的研制

阐述了一种具有高辐射和耐高温性能的涂层，它可用于铁路的红外轴温探测系统，以提高该系统红外线(红外热量)的辅出度。介绍了涂层的制备工艺及其指标数据的测定原理及方法，分析了影响涂层耐热性及热辐射性能的众多因素。     

环保型木器涂料

介绍水性和紫外光固化两类环保型木器涂料及其研究进展。水性木器涂料主要为丙烯酸酯与聚氨酯两大类，其研究进展集中表现为乳液改性，包括自交联、共混共聚、微乳液等；紫外光固化木器涂料包括其光固化树脂、活性稀释剂和光引发剂的功能及进展；指出研究新型乳液以提高水性木器涂料涂膜的表面性能，开发新型原材料以降低紫外光固化木器涂料的成本、扩大适应范围将成为今后环保型木器涂料的研究重点。     

Low-Thermal-Conductivity Rare-Earth Zirconates for Potential Thermal-Barrier-Coating Applications

Rare-earth zirconates have been identified as a class of low-thermal-conductivity ceramics for possible use in thermal barrier coatings (TBCs) for gas-turbine engine applications. To document and compare the thermal conductivities of important rare-earth zirconates, we have measured the thermal conductivities of the following hot-pressed ceramics: (i) Gd₂Zr₂O₇ (pyrochlore phase), (ii) Gd₂Zr₂O₇ (fluorite phase), (iii) Gd_2.58Zr_1.57O₇ (fluorite phase), (iv) Nd₂Zr₂O₇ (pyrochlore phase), and (v) Sm₂Zr₂O₇ (pyrochlore phase). We have also measured the thermal conductivity of pressureless-sintered 7 wt% yttria-stabilized zirconia (7YSZ)—the commonly used composition in current TBCs. All rare-earth zirconates investigated here showed nearly identical thermal conductivities, all of which were ∼30% lower than the thermal conductivity of 7YSZ in the temperature range 25°–700°C. This finding is discussed qualitatively with reference to thermal-conductivity theory.     

改性丙烯酸-环氧树脂纳米乳液的制备及应用

介绍了水性丙烯酸-环氧树脂纳米乳液的制备及其在油罐防腐工程中的应用。讨论了亲水侧链聚乙二醇相对分子质量大小对涂膜性能的影响以及乳化剂各组分的用量对乳液粒径的影响。