Oxidation of methane in a wide range of pressures and effect of inert gases

The analysis of methane oxidation in a wide range of pressures (0.05–10 atm) demonstrates that the efficiency of CH₃ radicals recombination is of great importance for high selectivity of C₂ hydrocarbons formation. The relative efficiency of different “colliders” assisting the stabilization of exited C₂H*₆ molecules increases in the series: solid surface> Ar> He. The increase of the overall reaction rate upon increasing pressure of the inert gases in the case of catalysts having a higher surface area and more developed pore structure is likely due to the contribution of the surface-induced chain reaction in the volume of pores.     

饮用水氯化中氯仿形成的动力学模式

以黄腐酸（ＦＡ）为卤仿前驱物质，分别测定不同投氯量、ＴＯＣ水平、温度以及ｐＨ值对ＣＨＣｌ３形成速率的影响，确定出ＣＨＣｌ３形成的动力学模式。该模式可用于预测投氯后的管网水中ＣＨＣｌ３的形成量，以便采取必要措施保证饮用水符合国家规定ＣＨＣｌ３〈６０μｇ／Ｌ的标准。     

Oxidation of methane to formaldehyde over Fe/SiO2 and Sn---W mixed oxides

In an attempt to develop new catalysts for the formation of formaldehyde from methane, the promotion effect of Fe on SiO₂ and that of Sn on WO₃ have been studied. The formation of formaldehyde on silica can be appreciably enhanced by the impregnation of Fe, as far as iron loadings are kept below 0.1 atom.% (Fe/Si × 100). In the case of Sn---W---Ox catalysts, both the addition of Sn to WO₃, and that of W on SnO₂ were effective to the selective formaldehyde formation. Absorption spectra (UV-Vis) and ESR measurements revealed that tetrahedrally coordinated Fe³⁺ in the silica network plays an important role in the formation of formaldehyde. A thin surface layer consisting of W and Sn oxides can account for the selective formaldehyde formation on the Sn---W---Ox catalysts.     

提高润滑油基础油氧化安定性的组合工艺

以生产润滑油基础油的老三套工艺为基础，开发了改善油品氧化安定性的组合工艺。该工艺的主要特点是包括一步络合脱氮过程。实验证明，该组合工艺既可以有效地提高基础油的氧化安定性，又能降低溶剂精制深度，提高基础油收率。     

油井细粉砂防砂工艺技术研究与应用

辽河油田的油井出细粉砂严重，通过防砂基础理论及试验研究，形成了地层深部防砂与携排砂采油技术。在出细粉砂油井及出砂区块进行试验、应用，年平均采取防砂措施300余井次，防砂成功率达90％以上。     

磷矿山环境污染的形成与防治

以湖北省黄麦岭、荆襄磷矿为研究对象，分析了造成磷矿山环境污染的污染源类型及特点，并从矿石特征、矿山生产环节、区域自然环境条件等方面，讨论了对矿山污染的制约和影响，以此，有针对性地提出防治矿山污染的对策和措施。     

Performance Characteristics of a Drying Heat Pump Using Superheated Steam

A complete mathematicalhumerical model is proposed, in order to simulate the performance characteristics of a novel concept of a drying heat pump based on the theory of minimum energy cyclcs. The drying heat pump involvcs vapour condensation in a Lava1 nozzle. removal of the liquid phase in a supersonic separator as well as compression of the working medium. which is superheared vapour.     

应用铟源的反应蒸发制备In2O3透明导电膜

本工作说明，在低压氧气氛中。应用铟源的反应蒸发很容易淀积高质量的Ｉｎ２Ｏ３透明导电膜．旦然没有使用锡杂质，但所得膜的性能可以和最好的掺锡的Ｉｎ２Ｏ３膜相比．膜电阻率达２～３×１０￣４Ω·ｃｍ，可见光透过率超过９０％，并且膜生长速率高达２１９／ｍｉｎ．文章对成膜过程作了分析，报道了膜的最佳淀积条件，对由于偏离最佳淀积参数而导致的异常膜的形成机制也进行了讨论．     

Void formation and growth in a class of compressible solids

A new class of compressible elastic solids, which includes the Blatz-Ko material as a special case, is proposed. A closed-form solution is constructed and studied for a bifurcation problem modeling void formation in this class of compressible elastic solids. The relation between the void-formation condition and the material parameters is obtained analytically. An energy comparison of the void-formation deformation and the homogeneous expansion deformation is carried out.     

华北盆地南缘大地电磁测深资料地质解释及大别山推覆体成因探讨

根据新近在大别山北麓获得的四条大地电磁测深剖面可以看出,该区地下介质的电性恃征具了明显的纵向上分层、横向上分块的特点。纵向上目上而下分为9个电性层.均有确定的地质属性。其中:第二和第九电性层为本区低阻标志层;第三和第六电性层为相对高阻层;第八电性层为高阻率电阻率高达1000Ω·m以上);第四、第五、第七电性层既有高阻、又有低阻分布.情况比较复杂。■向上的电性分块结构与本区的凸、凹相间的构造格局相对应。这四条大地测深剖面,均反映本区在5～15km深处有一个面积达15000km~2的连续低阻层(第九电性层).电阻率仅有1～3Ω·m。经分析,认为此低阻层可能是一个区域性的主滑脫面,是形成大別山推覆体由北向南的运动面.