苯胺类缓蚀剂的量子化学研究

用量子化学半经验计算方法CNDO/2程序,研究了苯胺类缓蚀剂的电子性质与缓蚀性能的关系。结果表明质子化的胺基是苯胺衍生物与金属作用的活性部位。提出了该类分子作为酸性介质中金属缓蚀剂在铁表面形成吸附膜的作用机理。     

Sulfidation behavior of Fe-25Cr-20Ni-1.5Al2O3 in simulated coal combustion/gasification environments

The effect of minor addition of -Al₂O₃ dispersoids on the sulfidation behavior of Fe-25Cr-20Ni was investigated over a range of pO₂, 1.13×10^–20 to 1.18×10 ****^–22 atm. at constant pS₂=1.22×10^–8 atm. Fe-25Cr-20Ni and Fe-25Cr-20Ni 1.5 Al₂O₃ with and without preformed oxide scales were exposed to bioxidant gas mixtures H₂/H₂O/H₂S/Ar at 700° C. Both isothermal and cyclic exposures were included. Scales were characterized by a combination of several surface analytical tools. A remarkable improvement in sulfidation resistance is observed in Fe-25Cr-20Ni-1.5Al₂O₃ under the conditions investigated here. This is attributed to the ability of the alloy to form and maintain a predominantly Cr₂O₃ scale with reduced Fe-diffusion and content. Possible scientific reasons for such improvement are discussed. The base alloy, Fe-25Cr-20Ni, fails to develop and retain such a Cr₂O₃ scale and undergoes sulfidation within a few minutes of exposure. The scale breakdown process by sulfidation is explained qualitatively. Experimental evidence suggests that sulfur in the environment enhances Fe-diffusion and content in the scale.     

Ni对C－B_4C－SiC复合材料显微结构与性能的影响

本文研究了烧结助剂Ｎｉ对Ｃ－Ｂ_４Ｃ－ＳｉＣ复合材料显微结构与性能的影响．Ｘ射线衍射表明Ｎｉ在烧结温度下与ＳｉＣ，Ｂ_４Ｃ人发生反应在晶界生成Ｎｉ_（４．６）Ｓｉ_２Ｂ，并产生液相，有效地促进了Ｃ－Ｂ_４Ｃ－ＳｉＣ复合材料的烧结，抑制了晶粒的长大，使复合材料密度与强度大幅度地增加，电阻率下降；同时Ｎｉ_（４．６）Ｓｉ_２Ｂ在氧化时生成致密的２ＮｉＯ·Ｂ_２Ｏ_３，包裹了易氧化的Ｂ_４Ｃ和Ｃ，有效地防止了复合材料的氧化，从而大大提高了制品的抗氧化性能．     

用正电子湮没技术研究Zr对Ni_3Al缺陷态的影响

本文用正电子湮没技术（ＰＴＡ）研究了含不同ｚｒ量多晶Ｎｉ３Ａｌ的ｅ＋寿命谱。结果表明：在Ｎｉ３Ａｌ中加入Ｚｒ，一部分Ｚｒ原子进行原子替位，使晶格发生畸变，导致基体中正电子寿命（τ_１）增长；另一部分在晶界偏聚的Ｚｒ调整了晶界结构，使平均寿命（τ）下降。当Ｚｒ量为１．２ａｔ．－％时，缺陷态的寿命τ２显著增长，表明有自由体积较大的缺陷组态生成．     

MODELLING OF P/M FORMING PROCESSES BY FEM

ＭＯＤＥＬＬＩＮＧＯＦＰ／ＭＦＯＲＭＩＮＧＰＲＯＣＥＳＳＥＳＢＹＦＥＭ￥Ｗｅｉ，Ｙｕａｎｐｉｎｇ；Ｒｕａｎ，Ｘｕｅｙｕ（ＤｅｐａｒｔｍｅｎｔｏｆＰｌａｓｔｉｃｉｔｙＴｅｃｈｎｏｌｏｇｙ，ＳｈａｎｇｈａｉＪｉａｏＴｏｎｇＵｎｉｖｅｒｓｉｔｙ，Ｓｈａｎｇ...     

Effect of growth-interrupted method on quality of AlGaAs/GaAs multiple quantum wells prepared by MBE

AlGaAs/GaAs multi-quantum well （MQW） was prepared by molecular beam epitaxy（MBE） with growth-interrupted heterointerface （GIH） method and continuous growth （CG） method, respectively. The microstructures Of the MQWs were characterized by double-crystal X-ray rocking curve （DCRC） and atomic force microscopy （AFM）, and the photoluminescence （PL） properties of the MQWs were also studied. The MQWs grown with GIH method show that higher order satellite peaks of Pendelloesung fiinges are observed in DCRC, the roughness of surface is much reduced in AFM, and the full width at half maximum （FWHM） of exciton line is much narrower in PL. The results indicate that the GIH method reduces the monolayer growth step density at the heterointerface due to the migration of surface atomsfor a few minutes grower interruption, and substantially improves the quality of AlGaAs/GaAs MQWs.     

Study of modeling and simulation of full digital controlled PMIG／MAG welding system based on Matlab／Simulink

This paper presents an integrated simulation model for full digital controlled PMIG/MAG welding system with Matlab/Simulink, and it consists of power inverter, digital control system and dynamic arc-load model. An integrated simulation study was done for fuU digital PMIG/MAG welding, and a method of connecting dynamic arc-load model to the system with controlled current source was presented, in addition, the simulation results were utilized to study the issues of digital control PMIG/MAG welding in this paper. The experimental results validated the developed simulation model, and this simulation study can be applied in implementation of the full digital PMIG/MAG welding and analysis of system dynamic process.     

K/Na-RE复合变质对辊环用高速钢组织及力学性能的影响

在辊环用高速钢中添加不同含量的K／Na-RE复合变质剂，对试样分别进行HSVM及力学性能测试。结果表明，随着复合变质剂含量的增加，并进行适当的热处理，高速钢中铸态碳化物趋于断网，奥氏体晶粒急剧变小，由大的枝晶变为小的等轴晶，分布趋于均匀，且高速钢的强度和韧性明显提高。当复合变质剂的加入量为1．0％时，高速钢的组织及力学性能较好。     

Al2O3/Cu复合材料制备中的Cu2O-Al体系化学反应

对Cu2O与Al进行热力学分析后将其粉末压制成块,测试了不同温度下反应的热分析曲线,并对反应后的试样进行X射线衍射分析.结果表明Cu2O-Al体系化学反应包括3个阶段,即第1阶段体系温度T＜910 K,有少量Al2O3和Cu生成;第2阶段体系温度为910 K≤T＜1103 K,Cu2O-Al体系未发生化学反应;第3阶段体系温度为1103 K≤T≤1373 K,Cu2O-Al体系发生化学反应,其产物为Cu、Al2O3及CuAlO2.     

Microstructure and mechanical properties of laser solid formed 30Cr–Mn–Si–Ni–2A ultra-high-strength steel

ABSTRACT

Microstructure and mechanical properties of laser solid formed 30Cr–Mn–Si–Ni–2A steel are investigated. The deposits consist of epitaxial columnar grains, equiaxed grains or direction changed dendrites can be observed in the bulk specimens. The microstructure at the bottom of deposits is mainly composed of tempered martensite; the middle to top zone of the deposits are characterised by martensite and bainite. With the increasing of deposition height, the volume fraction of bainite increases, the size of martensite laths increases but its volume fraction decreases. The microhardness shows a decrease from the bottom zone to the middle–upper zone, and then a significant increase at the top of the deposits. Anisotropic and unevenly distributed tensile properties are observed for the deposits. Samples after heat treatment demonstrate tensile strength of 1720?MPa and elongation rate of 8.7%.