新型三硅氧烷表面活性剂的合成与表征

合成了一种新型的三硅氧烷表面活性剂Me3SiOSiMeROSiMe3[R=(CH2)3NHCH2CH(OH)CH2(OCH2CH2)xOCH3,x=1,2]。通过低聚乙二醇单甲醚和环氧氯丙烷在相转移催化剂(P.T.C)的存在下合成出低聚乙二醇甲醚缩水甘油醚,产物再与氨丙基三硅氧烷进行开环反应,得到目标产物。通过气相色谱(GC)和氢核磁共振(1HNMR)确定了目标产物的纯度与结构。     

微波诱导稀土固体超强酸SO4^2-／TiO2／Ce^4＋催化合成乙酸正丁酯

本文探讨了标题合成方法中合成反应条件对酯收率的影响。其最佳反应条件为：n(醇)：n(酸)=2．5：1．0，固体超强酸用量为反应物总质量的2．0％，微波辐射功率528W，辐射时间20min，酯收率达89．5％。用IR等手段对产品进行了确证。     

Synthesis and Characterization of Segmented Block Copolymers Based on Hydroxyl‐Terminated Liquid Natural Rubber and α,ω‐Diisocyanato Telechelics

Summary: Segmented block copolymers, consisting of non‐polar soft segments from hydroxyl‐terminated liquid natural rubber (HTNR) and polar hard segments from α,ω‐diisocyanato telechelics obtained by “criss‐cross”‐cycloaddition, have been synthesized. The block copolymer formation took place under relatively mild reaction conditions at 80 °C in dichloroethane in the presence of dibutyltin dilaurate as a catalyst. The resulting block copolymers were characterized by spectroscopic techniques (¹H NMR, FTIR, UV‐vis spectroscopy) as well as GPC for molar mass determination. The block copolymers were compression molded in a hot stage press, and the resulting samples were characterized by DSC and stress‐strain measurement. The solubility and phase morphology of the materials have also been studied.

Segmented block copolymer from HTNR and α,ω‐diisocyanato telechelics     

合成正丁烷的一种改进方法

本文论述了一种从正丁醇合成正氯丁烷的改进方法，提高了产率，并用元素分析，红外光谱、沸点、比重和折光率对正氯丁烷作了鉴定。     

Correlation of reactivity and electrical resistivity of coke

A correlation between the reactivity and electrical resistivity of a series of cokes was determined using cokes prepared from blends of medium- and high-volatile coals. After correcting for the ash yield of the coke and the density of the resistivity specimen, a statistically significant relation between reactivity and resistivity was established. As the resistivity test requires much less time to perform than the reactivity test, it can be considered as an alternative approach to reactivity testing currently performed for quality control purposes.     

曲坦类药物的制备方法综述

曲坦类化合物是一类重要的治疗偏头痛的药物,现已开发出来的有舒马曲坦,纳拉曲坦、佐米曲坦、利扎曲坦、阿莫曲坦、依利曲坦和氟伐曲坦.本文对其合成方法进行了分类介绍.     

Growth of β-Alumina (Na2O · 11Al2O3) Single Crystals by the Flux Method

The crystal-growth process and growth conditions of β-alumina (Na₂O · Al₂O₃) were investigated using the Na₂B₄O₇-Na₃AlF₆ flux method. β-Alumina (electric fusion brick) was used as both nutrient and seed. Weight loss of the flux varied widely for various runs: ≅ 10 wt% of flux evaporated at 100 h, ≅ 17 wt% at 150 h, and 43 wt% at 600 h. When β-alumina crystal was grown, only 20 wt% Na₂B₄O₇ was added to the Na₃AlF₆ flux. The linear growth rates of the β-alumina single crystal grown by an Na₃AlF₆-20 wt% Na₂B₄O₇ flux method at 1040°C and Δ t = 18°C were ≅ 1.0 × 10⁻³ mm/h ( a face) and ≅0.3 × 10⁻³ mm/h ( c face). The β-alumina single crystals grown were bounded by only c [001] and a [100] and were colorless and transparent.     

NC74-1型氨合成催化剂的升温还原及应用

介绍了NC74-1氨合成催化剂在山东华鲁恒升化工股份有限公司大氮肥氨合成的装填、升温还原及使用情况。     

新型染料中间体手性胍的合成及表征

本文以(R)-苯基甘氨酸甲酯盐为原料合成了手性胍—化合物(6),并对合成反应条件进行了探索和优化。化合物(6)上与氮相连的活泼氢原子,可能对某些反应有不利影响,故用碘甲烷对其进行甲基取代,得到了新的手性胍—化合物(7),并做了表征。     

Low-temperature methanol synthesis in a circulating slurry bubble reactor

A circulating slurry bubble reactor was developed to synthesise methanol via methyl formate from the gas mixture of carbon monoxide and hydrogen at low temperature. The strategy for designing and scaling up the bubble reactor involved a preliminary understanding of fluid dynamics in a cold model, continuous operations under industrial conditions and a parallel experiment in an autoclave. Per-pass syngas conversion was investigated during 100-h operations. The axial profile of solid catalyst concentration was measured just before the shutdown and the composition of liquid product was analysed after the shutdown. These results show that the circulating slurry bubble column will become a potential reactor for the commercial process of low-temperature methanol synthesis after the catalyst system has been improved.