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991.
We review our recent work on spatial inhomogeneity of the electronic states in the strongly correlated molecular conductors κ-(BEDT-TTF)2X. Spatial mapping of infrared spectra (SMIS) is used for imaging the distribution of the local electronic states. In molecular materials, the infrared response of the specific molecular vibration mode with a strong electron–molecular vibration coupling can reflect the electronic states via the change in the vibration frequency. By spatially mapping the frequency shift of the molecular vibration mode, an electronic phase separation has been visualized near the first-order Mott transition in the bandwidth-controlled organic conductor κ-(BEDT-TTF)2Cu[N(CN)2]Br. In addition to reviewing SMIS of the phase separation, we briefly mention the electronic and optical properties of κ-(BEDT-TTF)2X. 相似文献
992.
耐高温有机胶粘剂的现状与发展 总被引:2,自引:0,他引:2
综述了耐高温有机胶粘剂的发展现状,对一些重要的不同类型耐高温有机胶粘剂的性能和应用进行了讨论。并指出了耐高温有机胶粘剂的研究发展方向。 相似文献
993.
This paper reports the synthesis of Co2SnO4@C core-shell nanostructures through a simple glucose hydrothermal and subsequent carbonization approach. The as-synthesized Co2SnO4@C core-shell nanostructures have been applied as anode materials for lithium-ion batteries, which exhibit improved cyclic performance compared to pure Co2SnO4 nanocrystals. The carbon matrix has good volume buffering effect and high electronic conductivity, which may be responsible for the improved cyclic performance. 相似文献
994.
995.
A new voltage-programmed driving scheme named the mixed parallel addressing scheme is presented for AMOLED displays, in which one compensation interval can be divided into the first compensation frame and the consequent N-1 post-compensation frames without periods of initialization and threshold voltage detection. The proposed driving scheme has the advantages of both high speed and low driving power due to the mixture of the pipeline technology and the threshold voltage one-time detection technology. Corresponding to the proposed driving scheme, we also propose a new voltage-programmed compensation pixel circuit, which consists of five TFTs and two capacitors(5T2C). In-Zn-O thin-film transistors(IZO TFTs) are used to build the proposed 5T2C pixel circuit. It is shown that the non-uniformity of the proposed pixel circuit is considerably reduced compared with that of the conventional 2T1C pixel circuit. The number of frames(N) preserved in the proposed driving scheme are measured and can be up to 35 with the variation of the OLED current remaining in an acceptable range. Moreover, the proposed voltage-programmed driving scheme can be more valuable for an AMOLED display with high resolution, and may also be applied to other compensation pixel circuits. 相似文献
996.
An experimental investigation on the influence of phenol on the solubility of CO2 in aqueous solutions of NaOH
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Michael Jödecke Jianzhong Xia Álvaro Pérez‐Salado Kamps Gerd Maurer 《American Institute of Chemical Engineers》2015,61(9):2832-2840
Experimental results are presented for the solubility of CO2 in an aqueous solution of phenol and NaOH (molalties in water: phenol: 0.5; NaOH: 1.0) at (314, 354, and 395) K and pressures up to 10 MPa. The experimental work extends recent investigations on the influence of phenol as well as of (phenol + NaCl) on the solubility of CO2 in water. In contrast to those previous investigations, the strong electrolyte reacts with carbon dioxide and also with phenol. The experimental results are compared with predictions from a thermodynamic model. That model combines a model for the “chemical” solubility of CO2 in aqueous solutions of NaOH with a model for the “physical” solubility of CO2 in aqueous solutions of phenol. An extension is introduced to account for the chemical reaction between the weak acid phenol and the strong base sodium hydroxide. The prediction results nicely agree with the new experimental data. © 2015 American Institute of Chemical Engineers AIChE J, 61: 2832–2840, 2015 相似文献
997.
Sarah E. Feicht George D. Degen Aditya S. Khair 《American Institute of Chemical Engineers》2015,61(4):1447-1454
The aim of this paper is to analyze moving front dynamics of ions and holes in a planar, mixed ionic‐electronic conducting polymer film. As cations invade the film, holes evacuate; thus, an ionic current is converted to an electronic signal. Recent experiments show that the location of the advancing ion front increases as the square‐root of time, a scaling typically associated with diffusive transport, which is surprising given the large driving voltages utilized. Ionic and electronic transport is modeled via the drift‐diffusion equations. A similarity transformation reduces the governing partial differential equations to ordinary differential equations that are solved numerically. The similarity transformation elucidates the origin of the square‐root‐of‐time front scaling. The similarity solution is then compared to the numerical solution of the full drift‐diffusion equations, finding excellent agreement. When compared with experimental data, our model captures the front location; however, qualitative differences between the ion profiles are observed. © 2015 American Institute of Chemical Engineers AIChE J, 61: 1447–1454, 2015 相似文献
998.
999.
High‐throughput and comprehensive prediction of H2 adsorption in metal‐organic frameworks under various conditions
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Yu Liu Shuangliang Zhao Honglai Liu Ying Hu 《American Institute of Chemical Engineers》2015,61(9):2951-2957
High‐throughput prediction of H2 adsorption in metal‐organic framework (MOF) materials has been extended from a few specific conditions to the whole T, p space. The prediction is based on a classical density functional theory and has been implemented over 712 MOFs in 441 different conditions covering a wide range. Some testing materials show excellent behavior at low temperatures and obvious improvement at high temperatures compared to conventional MOFs. The structures of the best MOFs at high and low temperatures are totally different. Linear and nonlinear correlations between the two Langmuir parameters have been found at high and low temperatures, respectively. According to the analysis of the excess uptake, we found that the saturated pressure increases along with temperature in the low temperature region but decreases in the high temperature region. © 2015 American Institute of Chemical Engineers AIChE J, 61: 2951–2957, 2015 相似文献
1000.