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81.
Electrochemical corrosion measurements have been carried out with Pt-containing and Pt-free Al-diffusion coatings on IN 738 LC in a 90Na2SO4+ 10K2SO4 (mol%) melt at 1173 K. Pt improves the resistance to basic fluxing while there are no significant differences between both coating types in their resistance to acidic fluxing. The corrosion resistance of the Pt-containing coating is also higher in the passive potential region where protective scales rich in Al2O3 are formed. The reason for the different behavior of both coating types appears to be related to the high corrosion resistance of the Pt-rich surface layer of the coating and an increased Al2O3 content in the scale of the Pt-containing type. 相似文献
82.
SynthesisandCharacterizationofHeteropolyComplexesofIndiumwithMetal-centredUndecatungstateLigandsWuQingyin(吴庆银)(LiaoningUniver... 相似文献
83.
Yoshihiko Sadaoka Enrico Traversa Masatomi Sakamoto 《Journal of Alloys and Compounds》1996,240(1-2):51-59
Perovskite-type LaxLn1−x″CoO3 oxides are prepared by the thermal decomposition of LaxLn1−x″ [Co(CN)6] · nH2O hetero-nuclear complexes. Except for LaCoO3 (hexagonal), the structures observed for LaxSm1−xCoO3 are othorhombic. While the perovskite-type oxide HoCoO3 is not formed by decomposition at 1000°C of the corresponding hexacyano complex, the partial replacing of Ho with La is effective in forming the pervoskite-type oxide having an orthorhombic structure containing Ho even at 800°C. A monotonous correlation (quasi-linear relationship) was found between the b- and c-lattice constants of the orthorhombic structures of the perovskite-type oxides and the effective radii of Ln ions, defined as reff = xr1.a + (1 − x)r1.0″. The distortion parameter for the orthorhombie cell (3″a/b−1) increaseswith decrease in reff and is expected to be 0.270 for perovskite-type HoCoO3. The crystal structure of the LaxLn1−x″, CoO3 oxides is mainly controlled by the effective radii of Ln ions. 相似文献
84.
The influence of externally located platinum on the isothermal stability of -Al2O3 scales formed at high temperatures has been examined. It has been observed that a nickel-base alloy forms an external scale of -Al2O3 during oxidation at 1200°C, but this scale breaks down isothermally, enabling a faster-growing Cr2O3-rich scale to develop. However, in the presence of platinum metal alongside the specimen in the furnace hot zone, the breakdown of the -Al2O3 scale is postponed for a substantial period of time. It appears that platinum, as the volatile species PtO2, is incorporated into the growing -Al2O3 scale where it either influences the stress relief mechanism at temperature or reduces oxidation growth stress generation and thus significantly enhances the isothermal stability of the scale. 相似文献
85.
Harish Chintakunta Thanos Gentimis Rocio Gonzalez-Diaz Maria-Jose Jimenez Hamid Krim 《Pattern recognition》2015
In persistent homology, the persistence barcode encodes pairs of simplices meaning birth and death of homology classes. Persistence barcodes depend on the ordering of the simplices (called a filter) of the given simplicial complex. In this paper, we define the notion of “minimal” barcodes in terms of entropy. Starting from a given filtration of a simplicial complex K, an algorithm for computing a “proper” filter (a total ordering of the simplices preserving the partial ordering imposed by the filtration as well as achieving a persistence barcode with small entropy) is detailed, by way of computation, and subsequent modification, of maximum matchings on subgraphs of the Hasse diagram associated to K. Examples demonstrating the utility of computing such a proper ordering on the simplices are given. 相似文献
86.
Barton B Rhinow D Walter A Schröder R Benner G Majorovits E Matijevic M Niebel H Müller H Haider M Lacher M Schmitz S Holik P Kühlbrandt W 《Ultramicroscopy》2011,111(12):1696-1705
We report the implementation of an electrostatic Einzel lens (Boersch) phase plate in a prototype transmission electron microscope dedicated to aberration-corrected cryo-EM. The combination of phase plate, Cs corrector and Diffraction Magnification Unit (DMU) as a new electron-optical element ensures minimal information loss due to obstruction by the phase plate and enables in-focus phase contrast imaging of large macromolecular assemblies. As no defocussing is necessary and the spherical aberration is corrected, maximal, non-oscillating phase contrast transfer can be achieved up to the information limit of the instrument. A microchip produced by a scalable micro-fabrication process has 10 phase plates, which are positioned in a conjugate, magnified diffraction plane generated by the DMU. Phase plates remained fully functional for weeks or months. The large distance between phase plate and the cryo sample permits the use of an effective anti-contaminator, resulting in ice contamination rates of <0.6 nm/h at the specimen. Maximal in-focus phase contrast was obtained by applying voltages between 80 and 700 mV to the phase plate electrode. The phase plate allows for in-focus imaging of biological objects with a signal-to-noise of 5-10 at a resolution of 2-3 nm, as demonstrated for frozen-hydrated virus particles and purple membrane at liquid-nitrogen temperature. 相似文献
87.
Marco A. Loza-Mejía Rafael Castillo Alfonso Lira-Rocha 《Journal of molecular graphics & modelling》2009,27(8):55
Although 9-anilinoacridines are among the best studied antitumoral intercalators, there are few studies about the effect of isosteric substitution of a benzene moiety for a heterocycle ring in the acridine framework. According to these studies, this approach may lead to effective cytotoxic agents, but good cytotoxic activity depends on structural requirements in the aniline ring which differ from those in 9-anilinoacridines. The present paper deals with molecular modeling studies of some 9-anilino substituted tricyclic compounds and their intercalation complexes (in various DNA sequences) resulting from docking the compounds into various DNA sequences. As expected, the isosteric substitution in 9-anilinoacridines influences the LUMO energy values and orbital distribution, the dipole moment, electrostatic charges and the conformation of the anilino ring. Other important differences are observed during the docking studies, for example, changes in the spatial arrangement of the tricyclic nucleus and the anilino ring at the intercalation site. Semiempirical calculations of the intercalation complexes show that the isosteric replacement of a benzene ring in the acridine nucleus affects not only DNA affinity but also base pair selectivity. These findings explain, at least partially, the different structural requirements observed in several 9-anilino substituted tricyclic compounds for cytotoxic activity. Thus, the data presented here may guide the rational design of new agents with different DNA binding properties and/or a cytotoxic profile by isosteric substitution of known intercalators. 相似文献
88.
Metal-based anticancer agents are frequently used in the treatment of a wide variety of cancer types. The monitoring of these anticancer agents in biological samples is important to understand their pharmacokinetics, pharmacodynamics, and metabolism. In addition, determination of metals originating from anticancer agents is relevant to assess occupational exposure of health care personnel working with these drugs. The high sensitivity of inductively coupled plasma mass spectrometry (ICP-MS) has resulted in an increased popularity of this technique for the analysis of metal-based anticancer drugs. In addition to the quantitative analysis of the metal of interest in a sample, ICP-MS can be used as an ultrasensitive metal selective detector in combination with speciation techniques such as liquid chromatography. In the current review we provide a systematic survey of publications describing the analysis of platinum- and ruthenium-containing anticancer agents using ICP-MS, focused on the determination of total metal concentrations and on the speciation of metal compounds in biological fluids, DNA- and protein-adducts, and environmental samples. We conclude that ICP-MS is a powerful tool for the quantitative analysis of metal-based anticancer agents from multiple sample sources. 相似文献
89.
Kasem K. Kasem Franklin A. Schultz 《Journal of Inorganic and Organometallic Polymers》1994,4(4):377-390
Multiply charged electroactive anions [IrCl
6
2–
, Fe(CN)
6
3–
, and W(CN)
8
4–
] are electrostatically incorporated in polymeric films of tris(4-vinyl-4-methyl-2,2-bipyridine) ruthenium(II) [poly-Ru(vbpy)
3
2+
] from aqueous trifluoroacetate solution. Values of apparent diffusion coefficients (D
ct) and heterogenous electron transfer rates (k
et) are measured for these anions as a function of their relative concentration (
M/
Ru) in the film.D
ct andk
et decrease systematically as
M/
Ru increases in a manner that is independent of charge and chemical identity of the ion. This result suggests that a nonchemical process, presumably electrostatic cross-linking, limits diffusional motion and is responsible for the decrease inD
ct andk
et with increasing anion content. Protonated polyvinyl-pyridine films exhibit similar ranges and variations inD
ct andk
et, which suggest similar structures and mechanisms of charge transport for these films and poly-Ru(vbpy)
3
2+
. 相似文献
90.
Hydrogenation of aromatics under mild conditions on transition metal complexes in zeolites. A cooperative effect of molecular sieves 总被引:1,自引:0,他引:1
The hydrogenation of aromatics, i.e. benzene, toluene, -methylstyrene, anisole, and ethyl benzoate, can be carried out under a very low (1/12000) catalyst to substrate ratio, and mild reaction conditions (80°C, 6 atm of H2O), on Rh and Ni organometallic complexes anchored on USY zeolites. A strong cooperative effect between the faujasite surface and the transition metal surface complex is thought to be responsible for the simultaneous enhancement of concentrations of arene and H2 in the neighborhood of the catalytic centers, and for the observed electronic effects. 相似文献