聚苯醚磺酸锂／共聚醚复合物的离子导电性研究

合成了３种不同磺化度的聚苯醚磺酸锂（ＳＰＰＯＬｉ）与Ｐ（ＭＥＯ１６－ＡＭ）／ＳＰＰＯＬｉ复合物。研究了复合物的离子导电性与磺化度，组成比及增塑剂含量的关系。含４０％（ｍａｓｓ）增塑剂的复合物具有单离子导电特征，锂离子迁移数高达０．９７，室温电导率达２×１０－５Ｓ／ｃｍ。     

参数三次B样条曲线的一种整体光顺方法

本文在能量法的基础上，提出了一种新的目标函数，给出了参数三次Ｂ样条曲线的一种新的整体光顺方法。利用这种方法得到的曲线不仅具有较小的应变能，而且曲率变化比较均匀，具有很好的光顺效果。该方法能推广到对曲面的光顺。     

Reaction between the tetragonal tungsten bronze niobate K2Sr4Nb10O30 and the perovskite Pb(Mg1/3Nb2/3)O3

The search for dielectric materials with a high dielectric constant and ′_r = ƒ(T) curves with a flat profile fitting the X7R specification is still ongoing. Promising results were obtained by mixing compounds with closely related structures, such as the tetragonal tungsten bronze (TTB) niobate K₂Sr₄Nb₁₀O₃₀ and the perovskite Pb(Mg_1/3Nb_2/3)O₃ (PMN). The present study, based on three methods of synthesis, explores the origin of the spreading out of the dielectric curves ′_r = ƒ(T). For the composition 10x K_0.2Sr_0.4NbO₃ (KSN) + (1 − x)Pb(Mg_1/3Nb_2/3)O₃ (PMN) with x = 0.3–0.6, the three synthesis methods provided similar characteristics and for the highest perovskite ratio (x = 0.3), the ′_r = ƒ(T) curve exhibits a flat profile. When lithium is used as a sintering agent, ′_r = ƒ(T) curves present a linear dependency with the temperature. These materials are also characterized by a structural and a microstructural inhomogeneity. Two phases TTB and perovskite type, different from KSN and PMN, are present after calcination and sintering, but not evenly distributed. The PbO loss during sintering also contributes to the evolution of the properties of the material.     

快速评定砂浆配方对钢筋腐蚀的影响

用电化学方法测定砂浆试件中钢筋的极化电阻，并测定了砂浆的孔隙率，结果发现:砂浆的孔隙率、孔径分布与钢筋极化电阻大小有良好的对应关系。电化学方法能可靠、快速测定砂浆配合比、添加剂对钢筋腐蚀速度的影响。     

Prediction of the energy dissipation rate in ductile crack propagation

In this paper, energy dissipation rate D vs. Δa curves in ductile fracture are predicted using a ‘conversion’ between loads, load‐point displacements and crack lengths predicted by NLEFM and those found in real ELPL propagation. The NLEFM/ELPL link was recently discovered for the DCB testpiece, and we believe it applies to other cracked geometries. The predictions for D agree with experimental results. The model permits a crack tip toughness R(Δa) which rises from J_c and saturates out when (if) steady state propagation is reached after a transient stage in which all tunnelling, crack tip necking and shear lip formation is established. J_R is always greater than the crack tip R(Δa) and continues to rise even after R(Δa) levels off. The analysis is capable of predicting the usual D vs. Δa curves in the literature which have high initial values and fall monotonically to a plateau at large Δa. It also predicts that D curves for CCT testpieces should be higher than those for SENB/CT, as found in practice. The possibility that D curves at some intermediate Δa may dip to a minimum below the levelled‐off value at large Δa is predicted and confirmed by experiment. Recently reported D curves that have smaller initial D than the D‐values after extensive propagation can also be predicted. The testpiece geometry and crack tip R(Δa) conditions required to produce these different‐shaped D vs. Δa curves are established and confirmed by comparison with experiment. The energy dissipation rate D vs. Δa is not a transferable property as it depends on geometry. The material characteristic R(Δa) may be the ‘transferable property’ for scaling problems in ELPL fracture. How it can be deduced from D vs. Δa curves (and by implication, J_R vs. Δa curves) is established.     

Correlation between quasi-static and dynamic crack resistance curves

The correlation between the crack resistance measured from dynamic and quasi-static J-R tests has been investigated based on test data from instrumented Charpy impact tests and quasi-static single edge notched bend (SENB) J-R tests.The method originally proposed by Aurich et al. [Analyse und Weiterentwicklung Bruchmechanischer versagenskonzepte--Lokales Risswachstum, Ermittlung des Risswiderstandsverhaltens aus der Kerbslagarbeit. BAM Forschungsbericht 192, Berlin 1993, ISBN 3-89429-329-2], to develop a correlation coefficient between the net fracture resistance of Charpy V-notch (ISO) and quasi-static compact tension tests, was extended to establish correlations between so-called ductile-brittle transition fracture resistance curves obtained from instrumented Charpy V-notched (ISO) and fatigue precracked impact tests and quasi-static SENB J-R fracture resistance tests.The correlation between the dynamic and quasi-static crack resistance with regard to practical application to fracture assessments appears to be reasonably consistent, bearing in mind the inherent scatter in crack resistance data in general. The findings of the present research project from testing of ship grade NVE 36 and pressure vessel steel to ASTM A516 Gr. 70 as well as two weldments in the NVE 36 steel, are in excellent agreement with the results of the research conducted by Aurich et al. [Analyse und Weiterentwicklung Bruchmechanischer versagenskonzepte--Lokales Risswachstum, Ermittlung des Risswiderstandsverhaltens aus der Kerbslagarbeit. BAM Forschungsbericht 192, Berlin 1993, ISBN 3-89429-329-2] for structural and pressure vessel steels to the German DIN standard steels including St 52-3, StE 355 and StE 460.     

含氮杂环季铵盐缓蚀剂在CO2-3%NaCl溶液体系中的电化学行为

为控制CO2腐蚀，合成了含氮杂环季铵盐缓蚀剂9912-1，通过电化学实验，研究了该缓蚀剂在CO2-3％NaCl-H2O体系中对碳钢于25℃和90℃下的缓蚀行为。实验结果与挂片失重法测试的结果基本一致。低温下缓蚀效果优于高温下的缓蚀效果。而且该缓蚀剂与硫脲有很好的协同效应。Tafel曲线表明，该缓蚀过程是以控制阴极腐蚀为主，并对其缓蚀机理进行了初步探讨。     

Ti／RuO2＋SnO2＋Sb2O3｜Pb3O4阳极的性能研究

本文对Ｔｉ│ＲｕＯ２＋ＳｎＯ２＋Ｓｂ２Ｏ３│Ｐｂ３Ｏ４阳极进行了ＳＥＭ、ＥＤＳ、ＸＲＤ研究，考察了在ＩＭＨ２ＳＯ４中电极寿命，测定了该电极的电化学动力学参数ａ、ｂ、ｉ０，并用双位垒模型讨论了其电化学性能，结果表明该电极具有优良的电化学性能和较长的使用寿命。     

CO2激光器线偏振光输出腔内起偏器的研究

混合InGaAs光电二极管阵列ETX128FPA是16384元InGaAs焦平面阵列,供1.0～1.7μm波段内的近红外成象使用。这种128×128元的二维光电二极管阵列是使用钢冲击结合技术把InGaAs材料结合到高级的CMOS倍增管上而制成的。     

X波段双极化有源相控阵天线的设计

机载或星载X波段有源相控阵雷达系统具有很高的分辨率，由于雷达系统使用了大量双极化子阵组成的有源相控阵天线（俯仰面和方位面均需扫描），频率的升高使得子阵馈线网络的可用面积受到了很大的限制。本文着重论述了有源相控阵天线中的双极化阵设计，提出了一系列解决方法，进而叙述了整个天线阵的设计。