CARS光谱测温及仪器狭缝函数对测量的影响

设计了一种利用光参量振荡器(OPO)来代替染料激光器的宽带相干反斯托克斯喇曼散射(CARS)光谱测温实验装置。为了提高CARS测量温度的精度,测量和分析了检测系统中狭缝函数对测量结果的影响,确定了狭缝函数的具体形式。将测量结果与热电偶读数比较,发现在温度范围300K～1200K内,温度测量的不确定度小于2%。     

NUMERICAL SIMULATION OF STRESS-INDUCED SECONDARY FLOWS WITH HYBRID FINITE ANALYTIC METHOD

1 .　ＩＮＴＲＯＤＵＣＴＩＯＮＴｈｅｔｕｒｂｕｌｅｎｔｓｔｒｕｃｔｕｒｅｓｉｎｎｏｎ ｃｉｒｃｕｌａｒｄｕｃｔｓａｎｄｏｐｅｎｃｈａｎｎｅｌｓａｒｅｃｈａｒａｃｔｅｒｉｚｅｄｂｙｌｏｎｇｉｔｕｄｉ ｎａｌｖｏｒｔｉｃｅｓ .Ｔｈｅｓｅｖｏｒｔｉｃｅｓａｒｅｔｈ     

Models for the formation of poly(butylene terephthalate): effect of water on the kinetics of the titanium tetrabutylate-catalysed reactions: 3

In an effort to investigate the mechanism of catalysis of titanium tetrabutoxide on the polycondensation of poly(butylene terephthalate), alcoholysis and hydrolysis reactions were studied with the aid of model molecules. The retarding effect of water has also been taken into account. Appropriate kinetic equations are derived and discussed and the results compared with experimental data obtained at different molar ratios of reactants.     

锗酸铋（Bi4Ge3O12）单晶热物理性质的研究

本文用不同的测试技术和方法测定了锗酸铋(BGO)单晶的比热(300～800K)热膨胀系数(100～1100K)和导温系数(140～700K),进而导出了 BGO 单晶不同温度下的导热系数、定容比热、德拜温度和格虑内森数。本文还对 BGO 单晶热物理性质的变化规律作了理论解释。     

钢结构稳定设计——理论与实践

本文提出了实际工程结构的非线性理论设计和分析方法(NIDA),并以澳门回归纪念馆的设计为例,展示了本方法的优越性.在设计过程中,设计者无需假设K系数和有效长度,在结构分析完成后便可迅速完成设计,因此本文提出的方法既经济又便利.尽管对于钢框架在往复荷载及动力荷载作用下的弹塑性大位移分析已经非常成熟,但本文的方法开创了结构的非线性分析及设计的新纪元,能够对现行的设计方法理论起到巨大的推动作用.     

Si衬底上横向外延GaN材料的微结构和光学性质的研究

用氢化物气相外延 (HVPE)方法在Si(III)衬底上成功横向外延生长出晶体质量较好的GaN薄膜材料。透射电子显微镜 (TEM )的研究结果表明 ,横向外延区域GaN的位错密度明显减小。由于SiO2 掩膜腐蚀角的不同 (分别为 90°和 6 6°) ,导致了横向外延GaN材料一些独特的微观形貌。微区拉曼光谱由数百条拉曼散射曲线组成 ,每一条曲线有三个振动模 ,分别对应Si振动模式 (5 2 0cm- 1) ,E2 模式 (5 6 6cm- 1)和E1(LO)模式(732cm- 1)。在垂直条纹方向 ,峰位和峰宽没有明显的变化 ,而峰强约 5 μm会发生周期性变化     

迫零对Turbo码的性能影响

从距离谱的角度对迫零在Turbo码中的作用进行了理论分析。通过仿真，研究了迫零对Turbo码性能的影响。仿真结果表明，Turbo码编码器迫零处理有助于改善Turbo码的性能。     

数字放大器—3G无线基站的助推器

为了构筑第三代无线网络,人们需要对现有基础设施进行彻底改造,包括网络的发射基站。配置在无线基站中的新型数字控制功率放大器能够改善频谱利用率和功率效率,从而提高系统容量。PMC-Sierra公司的数字控制功率放大器采用了数字校正信号处理器(DCSP)以及自适应控制处理器和补偿估值器(ACPCE),该放大器可改善无线基础设施的可靠性,同时降低系统成本、规模及复杂性。     

The Effect of Polymer Optoelectronic Properties on the Performance of Multilayer Hybrid Polymer/TiO2 Solar Cells

We report a study of the effects of polymer optoelectronic properties on the performance of photovoltaic devices consisting of nanocrystalline TiO₂ and a conjugated polymer. Three different poly(2‐methoxy‐5‐(2′‐ethylhexoxy)‐1,4‐phenylenevinylene) (MEH‐PPV)‐based polymers and a fluorene–bithiophene copolymer are compared. We use photoluminescence quenching, time‐of‐flight mobility measurements, and optical spectroscopy to characterize the exciton‐transport, charge‐transport, and light‐harvesting properties, respectively, of the polymers, and correlate these material properties with photovoltaic‐device performance. We find that photocurrent is primarily limited by the photogeneration rate and by the quality of the interfaces, rather than by hole transport in the polymer. We have also studied the photovoltaic performance of these TiO₂/polymer devices as a function of the fabrication route and device design. Including a dip‐coating step before spin‐coating the polymer leads to excellent polymer penetration into highly structured TiO₂ networks, as was confirmed through transient optical measurements of the photoinduced charge‐transfer yield and recombination kinetics. Device performance is further improved for all material combinations studied, by introducing a layer of poly(ethylene dioxythiophene) (PEDOT) doped with poly(styrene sulfonic acid) (PSS) under the top contact. Optimized devices incorporating the additional dip‐coated and PEDOT:PSS layers produced a short‐circuit current density of about 1 mA cm^–2, a fill factor of 0.50, and an open‐circuit voltage of 0.86 V under simulated AM 1.5 illumination (100 mW cm^–2, 1 sun). The corresponding power conversion efficiency under 1 sun was ≥ 0.4 %.     

Head-to-head polymers: 33. Bromination of cis-1,4-polybutadiene to head-to-head poly(vinyl bromide)

Cis-1,4-polybutadiene (PB) in a 0.5% solution of a solvent mixture of dichloromethane and 1,2-dibromoethane or tetrahydrofuran was quantitatively brominated with elemental bromine at 0°C under careful exclusion of oxygen to head-to-head poly(vinyl bromide). Partially brominated PB has a structure of random or block sequences of butadiene units in the polymer depending on the bromination solvent but shows no stereospecificity in the CHBrCHBr-dyads. Partially brominated PB with block structure showed a microphase-separated morphology over a wide range of composition. Microphase separation is less pronounced for the more random structure of butadiene units. I.r and ¹³C n.m.r. spectroscopy of the partially brominated PB was used to follow the progress of the bromination.