基于混沌蚁群算法的应急救援车辆调度优化

针对应急救援车辆调度优化问题的特征和需求,以可变双向距离、道路风险和成本最小为主要目标,建立了应急救援车辆调度优化问题的多目标优化模型.为避免过早陷入局部最优,提出了基于混沌扰动的改进蚁群系统优化算法.该算法可对信息素进行全局更新混沌扰动,有效地提高了算法的适应性、求解效率和求解质量.仿真实验表明该算法是可行的,能较好地满足应急救援车辆调度的优化需求.     

PPTA／尼龙1010分子复合材料流变行为的研究

本文采用共沉淀法制备了聚对苯二甲酰对苯二胺(PPTA)/尼龙1010分子复合材料。测定了PPTA/尼龙1010分子复合材料的流变行为,发现PPTA使尼龙1010的表观熔体粘度变大,且PPTA/尼龙1010分子复合材料的表观熔体粘度对温度的敏感性不象尼龙1010那样突出。     

基于K-L散度的恶意代码模型聚类检测方法

在云计算应用环境下,由于服务系统越来越复杂,网络安全漏洞和被攻击情况急剧增加,传统的恶意代码检测技术和防护模式已无法适应云存储环境的需求。为此,通过引入高斯混合模型,建立恶意代码的分层检测机制,使用信息增益和文档频率等方法分析和提取样本数据特征值,结合K-L散度特性,提出基于K-L散度的恶意代码模型聚类检测方法。采用KDDCUP99数据集,使用Weka开源软件完成数据预处理和聚类分析。实验结果表明,在结合信息增益和文档频率进行特征分析的前提下,与贝叶斯算法相比,该方法在虚拟环境中恶意代码的平均检测时间降低16.6%,恶意代码的平均检测率提高1.05%。     

电子横移伺服LQR最优控制器设计

为了提高系统的稳态精度和动态性能,将LQR最优控制算法应用于高速经编机电子横移伺服控制系统.建立了伺服系统状态空间模型,引入了一类具有指数衰减度的二次型函数作为系统性能指标.仿真结果表明,所提出的电子横移伺服LQR最优控制算法易于工程实现,保证了系统的稳定性,具有良好的频响特性,改善了系统的动态特性,实现了无静差高精度控制.     

Hydrogenation of natural rubber latex in the presence of OsHCl(CO)(O2)(PCy3)2

Hydrogenation is an important method of chemical modification, which improves the physical, chemical, and thermal properties of diene elastomers. Natural rubber latex (NRL) can be quantitatively hydrogenated to provide a strictly alternating ethylene–propylene copolymer using a homogeneous osmium catalyst OsHCl(CO)(O₂)(PCy₃)₂. A detailed kinetic investigation was carried out by monitoring the amount of hydrogen consumption during the reaction using a gas‐uptake apparatus. The kinetic results of NRL hydrogenation indicated that this system had a second‐order dependence of the hydrogenation rate on hydrogen pressure and then decreased toward a zero‐order dependence for hydrogen pressures above 13.8 bar. The hydrogenation was also observed to be first‐order with respect to catalyst concentration and inverse first‐order on rubber concentration due to impurities present in the rubber latex. Additions of a controlled amount of acid demonstrated a beneficial effect on the hydrogenation rate of NRL. The temperature dependence of the hydrogenation rate was investigated and an apparent activation energy (over the range of 120–160°C) was calculated as 57.6 kJ/mol. Mechanistic aspects of this catalytic process are discussed on the basis of kinetic results. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 640–655, 2006     

Kinetic and molecular weight control for methyl methacrylate semibatch polymerization. II. Open control

The gel effect will bring a violent increase of conversion for methyl methacrylate (MMA) polymerization in a short time. It will be very dangerous for the reactor, as it causes an increase of molecular weight and broadens the molecular weight distribution. To unify the kinetics, molecular weight, and its distribution, on the basis of the mathematical models for semibatch polymerization of MMA, three controlled objectives that are the heat load distribution index, the change in molecular weight, and molecular weight distribution index are presented. Three materials (monomer, solvent, and chain transfer agent) and their flow rate and feeding mode are analyzed for the open control of kinetics, molecular weight, and its distribution. The optimum flow rate and mode are obtained. The heat load distribution index and molecular weight distribution index are even less than 2.0 and 2.2, respectively. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 4399–4405, 2006     

静电除尘器在磷石膏制硫酸联产水泥工程中的应用

本文阐述了磷石膏烘干脱水后,粉状半水石膏的收集、磷石膏煅烧窑气净化除尘均应选择静电除尘器的必要性。根据电除尘器处理介质(烘干尾气与水泥窑气)的特性及操作条件,介绍了设计选型要考虑结露、构件腐蚀、绝缘爬电等问题,并提出相应改进的措施。     

MgO-CaO-TiO2系材料的烧结性能及抗水化性能

以白云石、工业钛白粉、轻烧镁砂为原料配制了不同组成的MgO-CaO-TiO2材料,分别于1500℃、1550℃、1600℃、1650℃保温3 h煅烧后,研究了材料的烧结性能,并采用蒸压法(0.1 MPa下蒸压2 h)研究了烧后试样的抗水化性能.研究结果表明1550～1600℃煅烧后,试样均达到了良好的烧结,相对密度达到92%以上,原始配料中的CaO全部转化成了不易水化的CaO·TiO2,因而所有试样均表现出优良的抗水化性能.     

In situ composite of nano SiO2-P(VDF-HFP) porous polymer electrolytes for Li-ion batteries

Nano SiO₂-P(VDF-HFP) composite porous membranes were prepared as the matrix of porous polymer electrolytes through in situ composite method based on hydrolysis of tetraethoxysilane and phase inversion. SEM, TEM, DSC and AC impedance analysis were carried out. It is found that the in situ prepared nano silica was homogeneously dispersed in the polymeric matrix, enhanced conductivity and electrochemical stability of porous polymer electrolytes, and improved the stability of the electrolytes against lithium metal electrodes. The in situ composite method was found to be much better than the direct composite method in lowering the interfacial resistance between electrolyte and lithium metal electrode. Moreover, cycle test of lithium batteries using lithium metal as anode and sulfur composite material as cathode showed that the electrolyte based on in situ composite of silica presented stable charge-discharge behavior and little capacity loss of battery.     

Crystallization behavior of poly(N‐methyldodecano‐12‐lactam). IV. Nonisothermal crystallization

Nonisothermal crystallization of poly(N‐methyldodecano‐12‐lactam) (MPA) was investigated using DSC method at cooling rates of 2–40 K/min. With increasing cooling rate, crystallization exotherms decreased in magnitude and shifted toward lower temperatures. Subsequent heating runs (10 K/min) showed an exotherm just above T_g, which increased in magnitude with the rate of preceding cooling run, corresponding to the continuation of primary crystallization interrupted as the system crossed T_g on cooling. Kinetic evaluation by the Avrami method gave values of exponent n close to 2.0, suggesting two‐dimensional crystal growth combined with heterogeneous nucleation. The Tobin method, covering the intermediate range of relative crystallinities, provided n ? 2.20, suggesting possible partial involvement of homogeneous nucleation at later stages of nonisothermal crystallization. The crystallization rate parameter k^1/n showed a linear dependency on cooling rate for both methods, the Tobin values being slightly higher. The Ozawa approach failed to provide reasonable values of the kinetic exponent m of MPA. The Augis–Bennet method was used to determine the effective activation energy of the entire nonisothermal crystallization process of MPA. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 95: 564–572, 2005