Study of the morphology and mechanical properties of polypropylene composites with silica or rice‐husk

The mechanical, morphological behavior and water absorption characteristics of polypropylene (PP) and silica, or PP and rice‐husk, composites have been studied. The silica used in this study as filler was a commercial type produced from soluble glass or rice husks. The compatibilizing effect of PP grafted with monomethyl itaconate (PP‐g‐MMI) and/or with vinyltriethoxysilane (PP‐g‐VTES) as polar monomers on the mechanical properties and water absorption was also investigated. In general, a high loading of the studied fillers in the polymer matrix increases the stiffness and the water absorption capacity. This effect is more noticeable in the tensile modulus of the PP/silica composite with PP‐g‐VTES as compatibilizer. However, the increase of the rice‐husk charge as a natural filler in the PP matrix decreases the stiffness, and in the presence of PP‐g‐MMI as compatibilizer in PP/rice‐husk, the tensile modulus and water absorption of the composite were improved. The better adhesion and phase continuity in the PP/silica and PP/rice‐husk composites with different compatibilizers was confirmed by the morphological study. Copyright © 2004 Society of Chemical Industry     

大塑性变形制备纳米结构金属

细化晶粒是改善材料性能的有效手段，传统的压力加工技术(如轧制、挤压、拉拔和锻造等)可以细化晶粒(微米量级)。纳米结构金属由于具有很小的晶粒尺寸(20-500nm)和独特的缺陷结构，从而表现出优异的物理—力学性能。大塑性变形(SPD)具有将铸态粗晶金属的晶粒细化到纳米量级的巨大潜力，近年来已引起人们的极大关注。介绍了4种大塑性变形制备纳米结构金属的方法、原理、变形特点及应用，分析了纳米结构金属的强度和超塑性变形特征，以及当前研究中存在的主要问题，并对大塑性变形技术的应用前景进行了展望。     

橡塑共混热塑性弹性体的形态结构与性能

综述了影响共混热塑性弹性体的形态结构与性能的主要因素。     

低合金高强度钢的微观组织和疲劳裂纹扩展行为

用透射电镜观察了３０ＣｒＭｎＳｉＮｉ２Ａ钢等温的微观组织，疲劳裂纹扩展行为、裂纹尖端塑性区和位错结构，结果表明，等温状态组织由马氏体和贝氏体组成。在一个奥氏体晶粒内一般存在四个板条领域、裂纹尖端的塑性区内存在主位错带，疲劳断裂的基本组织单元为板条晶或板条束。裂纹遇到板条束界时方向发生较大偏斜。     

Liquid viscosities and densities of HFC-134a+glycol mixtures

Liquid viscosity and density of six binary mixtures of HFC-134a with glycols [ethylene glycol, diethylene glycol, triethylene glycol, polyethylene glycol (400), and polypropylene glycol (2000)] have been measured in the temperature range from 273 to 333 K. The viscosity was measured by a rolling-ball viscometer calibrated with standard liquids of viscosities and densities (JS5, JS10, JS20, and JS50). The density was measured with a glass pycnometer. The uncertainties of the measurements were estimated to be less than 3.4 % for viscosity and 0.04 % for density, respectively. An equation is given to represent the obtained viscosity values as a function of weight fraction and temperature.     

红外加热胶接技术

提出了红外加热胶接的思想，并对红外加热胶接技术作了简单阐述。介绍了一种红外加热胶接矿用阻燃、防腐、橡塑风筒布的装置。     

Melt index prediction by weighted least squares support vector machines

Melt index is considered an important quality variable determining product specifications. Reliable prediction of melt index (MI) is crucial in quality control of practical propylene polymerization processes. In this paper a least squares support vector machines (LS‐SVM) soft‐sensor model of propylene polymerization process is developed to infer the MI of polypropylene from other process variables. Considering the use of a SSE cost function without regularization might lead to less robust estimates; the weighted least squares support vector machines (weighted LS‐SVM) approach of propylene polymerization process is further proposed to obtain a robust estimation of melt index. The performance of standard SVM model is taken as a basis of comparison. A detailed comparison research among the standard SVM, LS‐SVM, and weighted LS‐SVM models is carried out. The research results confirm the effectiveness of the presented methods. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 285–289, 2006     

聚丙烯催化剂的研发进展

综述了用于丙烯聚合的Ziegler-Natta催化剂在给电子体技术及催化剂制备工艺等方面,茂金属催化剂在制备丙烯均聚物、丙烯共聚物及特殊聚丙烯等方面,非茂单活性中心催化剂在丙烯活性聚合、丙烯与极性单体共聚及水介质聚合等方面的研发进展;讨论了聚丙烯催化剂的前景。     

助催化剂对TiCl_4/MgCl_2催化丙烯高温聚合的影响

研究了助催化剂种类(三甲基铝、三异丁基铝、三正己基铝、三乙基铝和甲基铝氧烷)及其含量对无内、外给电子体的TiCl4/MgCl2催化剂催化丙烯高温(100℃)聚合性能的影响,并用结晶分级分析、示差扫描量热和凝胶渗透色谱等方法分析了所得聚丙烯的结晶熔融行为和微观结构。实验结果表明,聚合温度从70℃升至100℃时,TiCl4/MgCl2催化剂的定向能力基本不变;100℃聚合时,以烷基化能力较弱的三异丁基铝为助催化剂时TiCl4/MgCl2催化剂的活性最高,而采用烷基化能力最强的三甲基铝为助催化剂时TiCl4/MgCl2催化剂的活性最低;100℃聚合时,助催化剂的种类对TiCl4/MgCl2催化剂的定向能力影响很小。     

非织造产业中塑胶网带的用途

介绍了塑胶网带的用途和网带的种类 (玻璃纤维网带、金属网带和塑胶网带 )及其优缺点 ,并对网带的透风率、网带清理及网带收缩等问题进行了讨论