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41.
Laboratory investigation of reinforcement corrosion initiation and chloride threshold content for self-compacting concrete 总被引:2,自引:0,他引:2
Time-to-corrosion (Ti) of reinforcement in concrete and chloride threshold content (Cth) are important service life determinants for reinforced concrete structures in chloride-laden environments. In this study, the two determinants of a series of self-compacting concretes (SCC) and regular concretes were experimentally investigated. A new sampling approach for Cth determination (milling powder from corrosion active site at the rebar/concrete interface) was adopted to accurately express chloride content resulting in corrosion occurrence. It is found that the Ti and Cth follow the 3-parameter Weibull distribution. The results indicate that the corrosion initiation of rebar in concrete slabs depends upon both cement alkalinity and superplasticizer. Rebar, embedded in high alkalinity cement SCC, exhibits better corrosion resistance as indicated by the longer Ti, higher Cth and larger Weibull modulus, m. A larger Weibull modulus indicates that anti-corrosion performance of rebar in slabs is more stable and less scattered. The effects of specific superplasticizer on rebar corrosion resistance are discussed from the viewpoint of air void amount and size distribution at the rebar/concrete interface. 相似文献
42.
AM/AMPS/DMDAAC/AMC16S共聚物的合成与性能 总被引:4,自引:0,他引:4
采用氧化还原引发体系合成了丙烯酰胺(AM)/2丙烯酰胺基-2-甲基丙磺酸(AMPS)/二甲基二烯丙然氯化铵(DMDAAC)/2-丙烯酰胺基十六烷磺酸(AMC16S)四元共聚物,借助红外光谱和差热分析研究了聚合物的结构和热稳定性,初步评价了共聚物的溶液性能,结果表明,AM/AMPS/DMDAAC/AMC16S共聚物具有较好的热稳定性和耐温抗盐能力。 相似文献
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持续荷载下混凝土的氯离子扩散性能研究 总被引:1,自引:0,他引:1
基于实际海洋环境暴露条件,研究了力学荷载作用下混凝土中的氯离子扩散性能.以Fick第二定律理论为基础,用误差函数对混凝土中随深度变化的氯离子含量分布进行了曲线拟合,从而得到氯离子表现扩散系数,并以此表征氯离子在混凝土中的传输性.分析了氯离子的扩散系数与原材料、配合比、暴露环境以及力学荷载间的关系.结果表明,力学荷载对海洋环境下混凝土中的氯离子传输性能有显著影响,在利用氯离子扩散模型预测暴露海洋环境下混凝土结构的使用寿命时,需要考虑荷载因素的影响. 相似文献
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研究了硫铵结晶系统中氯离子的来源以及对硫铵结晶系统的影响,并制定了控制氯离子含量的对策。硫铵结晶系统由于氯离子进出严重不平衡,导致母液中的氯离子含量高,造成设备腐蚀,影响产品质量和系统安全,因而必须控制氯离子的含量。 相似文献
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The electrochemical corrosion behavior of 300M ultra high strength steel in chloride containing environment was investigated by potentiodynamic polarization technique, electrochemical impedance spectroscopy (EIS) and scanning electron microscopy (SEM). The results show that uniform corrosion occurs on 300M steel during the electrochemical measurements because no anodic passivation phenomenon is observed on polarization curves within the measurement range. The tests also show that 300M steel is highly susceptible to chloride containing solution, which is characterized by corrosion current density increasing with the addition of chlorides, and corrosion potential shifting towards positive direction and corrosion resistance decreasing, positively suggesting that chloride ions speed up the corrosion rate of 300M steel. Meanwhile corrosion products on the 300M steel surface formed during the salt spray test are too loose and porous to effectively slow down the corrosion rate. Additionally, a schematic structure of uniform corrosion mechanism can explain that 300M steel has better property of stress corrosion cracking (SCC) resistance than stainless steels. 相似文献
50.
The mechanism of damage occurring in NaCl contaminated materials has not been clarified yet. Apart from crystallization pressure, other hypotheses have been proposed to explain the cause of decay. Irreversible dilation has been observed in a few cases but has never been studied in a more systematic way. The aim of the research is to contribute to the modeling of this phenomenon.In the present paper the effect of NaCl on the hydric and hygric behavior of a lime-cement mortar is extensively studied. The results indicate that NaCl influences the hydric and hygric dilation behavior of the material. The material contaminated with NaCl shrinks during dissolution and dilates during crystallization of the salt. This dilation is irreversible and sufficient to damage the material after few dissolution/crystallization cycles. This behavior is not restricted to NaCl, but is observed in the presence of other salts as well (NaNO3 and KCl). Outcomes of electron microscopy studies suggest that salts causing irreversible dilation tend to crystallize as layers on the pore wall. 相似文献