超细粉碎技术现状及发展趋势

综述了国内外超细粉碎技术及设备的现状、进展,指出了其发展趋势,从工作原理、结构特点等方面详细介绍了超细粉碎典型设备,同时又指出了近年来国内外在此领域中的新进展,基于现存问题指出了今后超细粉碎研究的方向。     

络合沉淀法制备BaTiO_3超细粉末

在分析ＢａＴｉＯ_３前驱体形成机理的基础上，提出了以草酸作为络合剂，用络合沉淀法制备超细ＢａＴｉＯ_３新工艺。用化学分析法测定产物Ｂａ／Ｔｉ比，用ＸＲＤ、ＴＥＭ、ＢＩ－９０激光散射粒度仪对产物的晶型、粒度及形貌进行表征。结果表明：采用该法合成的前驱体，微观组分确定，粒径小，粒度分布窄，近似球形，煅烧后为高纯超细ＢａＴｉＯ_３粉末。     

浅色补强填充剂LEE白滑粉在合成橡胶中的应用

介绍了新型浅色补强填充剂ＬＥＥ白滑粉的组成、物化性质、加工特性、硫化胶性能及应用前景。     

Mechanical degradation of coating systems in high temperature cyclic oxidation

Cyclic oxidation tests were performed on a large variety of commercially available overlay coatings. The results of cyclic oxidation tests confirmed that the composition of the coating as well as the processing method of the coating can affect the life of the system. Coating life was determined by the time to coating penetration and initiation of substrate attack. As this work was part of a effort to evaluate the relative protectiveness of available coating systems for Industrial Gas Turbine applications at relatively high temperature, an extensive testing programme was undertaken. The different coatings were tested to visual failure. The results presented in this paper concentrate on the surface instability of the coating. Apart from usual oxidation of the coating an additional degradation mechanism was observed. A mechanical effect caused by the instability of the coating as a result of the difference in the thermal coefficient of expansion and mechanical properties between the substrate and coating. This effect, the so-called “rumpling” effect, resulted in a significant reduction in time to penetration and was in some systems the life controlling factor.     

高性能各向异性Sm2Fe17Nx磁粉的制备

本文研究了高性能各向异性Ｓｍ２Ｆｅ１７Ｎｘ磁粉的制备工艺路线与工艺参数。优化了制备与工艺参数。已制备出磁性能达到：Ｂｒ＝１．３９Ｔ，Ｈｃｉ＝８５０ＫＡ／ｍ和（ＢＨ）ｍ＝２３６ＫＪ／ｍ＾３的各向异性Ｓｍ２Ｆｅ１７Ｎ２．８８磁粉，该磁粉的各向异性场ＨＡ达到２０Ｔ。     

Preparation and Properties of Sintering Additives Coated Si3N4 from Heterogeneous Nucleation Processing

The sintering additives such as Al2O3 and /or Y2O3 were coated on the surfaces of Si3N4 particles via heterogeneous nucleation processing using a buffered pH solution as the precipitation reagent .They nucleated and grew only on the surfaces of Si3N4 and did not form sol particles in solution by TEM observation .The isoelectric point(IEP) of coated Si3N4 was different from that of as-received Si3N4.The IEP of Al(OH)3-coated Si3N4 occurred at pH8.4, which is close to that of alumina .When Al(OH)3-coated Si3N4 particles were coated with Y(OH)3,the IEP of coated Si3N4 powder shifted from pH8.4 to pH9.2 ,similar to that of yttria.In addition ,the rheological data showed that Al2O3 and /or Y2O3 coated Si3N4 suspension is nearly Newtonian and that added Si3N4 suspension shows a shear rate thinning behavior.     

用废旧橡胶生产精细胶粉的空气涡轮制冷低温粉碎法

利用先进的空气涡轮制冷系统，在低温条件下，将废旧橡胶进行冷冻，粉碎，制成60目以上细度的精细胶粉，此法简称ATCG法，它的冷冻能耗成本仅为国际上通用的液氮法的十分之一，整个工艺过程不产生二次污染，为精细胶粉的制取开辟了一条新途径。     

高温润滑涂层设计的系统考虑

航天、航空、核能等尖端技术迫切要求使用耐高温润滑涂层，以保护金属构件的表面，增加发动机、推进器的工作效率和输出功率，８０年代国际摩擦学界根据工业和国防的需要将高温润滑涂层和耐磨材料定为摩擦学学科发展的重要研究方向之一。本文对高温润滑涂层设计中遇到的典型环境、涉及到的关键问题、未来发展的途径等问题作了阐述。     

HAP陶瓷合成的研究

本文对生物陶瓷材料－羟基磷灰石的合成进行了研究。试验将激光合成与湿法合成对比分析，着重探讨了在激光辐照下生物陶瓷的形貌，粒度，化学组成和结构等的变化规律，对激光涂敷生物陶瓷涂层有一定的指导意义。     

Li2O在保护渣中的作用

采用在不同玻璃性的两种基渣中加入Ｌｉ２Ｏ为研究Ｌｉ２Ｏ对保护渣粘度，熔化温度及玻璃性能的影响，并对Ｌｉ２Ｏ改善保护渣玻璃性的机理进行了探讨，提出了寻找高速连铸保护渣中Ｌｉ２Ｏ的代用物的一种方法。