Hollow Pd/MOF Nanosphere with Double Shells as Multifunctional Catalyst for Hydrogenation Reaction

A new type of hollow nanostructure featured double metal‐organic frameworks shells with metal nanoparticles (MNPs) is designed and fabricated by the methods of ship in a bottle and bottle around the ship. The nanostructure material, hereinafter denoted as Void@HKUST‐1/Pd@ZIF‐8, is confirmed by the analyses of photograph, transmission electron microscopy, scanning electron microscopy, powder X‐ray diffraction, inductively coupled plasma, and N₂ sorption. It possesses various multifunctionally structural characteristics such as hollow cavity which can improve mass transfer, the adjacent of the inner HKUST‐1 shell to the void which enables the matrix of the shell to host and well disperse MNPs, and an outer ZIF‐8 shell which acts as protective layer against the leaching of MNPs and a sieve to guarantee molecular‐size selectivity. This makes the material eligible candidates for the heterogeneous catalyst. As a proof of concept, the liquid‐phase hydrogenation of olefins with different molecular sizes as a model reaction is employed. It demonstrates the efficient catalytic activity and size‐selectivity of Void@HKUST‐1/Pd@ZIF‐8.     

Metal microparticle – Polymer composites as printable,bio/ecoresorbable conductive inks

Biologically and environmentally resorbable electronic devices support application possibilities that cannot be addressed with conventional technologies. This paper presents highly conductive, water-soluble composites that can be printed to form contacts, interconnects, antennas, and other important features that are essential to nearly all systems of this type. An optimized material formulation involves in situ polymerization to yield a polyanhydride containing a dispersion of molybdenum microparticles at appropriate concentrations. Comparisons of essential physical and electrical properties of these materials to those of composites formed with other polymers and other metal microparticles reveal the relevant considerations. Various functional demonstrations of screen-printed test structures and devices illustrate the suitability of these conductive inks for use in water-soluble electronic devices. A key advantage of the material introduced here compared to alternatives is its ability to maintain conductance over significant periods of time while immersed in relevant aqueous solutions. Studies involving live animal models establish the biocompatibility.     

Effects of Fe concentration on microstructure and corrosion of Mg-6Al-1Zn-xFe alloys for fracturing balls applications

Mg-6Al-1Zn-xFe (x = 0, 1, 3, 5 and 7 wt%) alloys were prepared by powder metallurgy and followed by hot extrusion. Majority of Fe element exists as insoluble particles in the alloys. The as-extruded alloys showed higher degradable rates but less stable mechanical properties than as-annealed alloys. Corrosion rate of all the alloys increased with increasing Fe concentration, reaching 2.4 mL cm⁻² h^-1. 0.2% yield strength of all the alloys was higher than 150 MPa. In short, Mg-6Al-1Zn-xFe alloys have an attractive combination of corrosion and mechanical properties, which holds a bright future for fracturing balls applications.     

Production of perovskite-like La1−xCaxMnO3+δ ferromagnetic thin films by electrochemical reduction

Ferromagnetic and perovskite-like thin films (<1m) of La1–xCaxMnO3+ have been routinely prepared by heat treatment of an amorphous La–Ca–Mn precursor. The precursor was electrodeposited cathodically in the absence of oxygen and water onto polished silver substrates from a nonaqueous solution of the components' nitrates. Analysis by X-ray diffraction and SQUID magnetometry shows these materials exhibit the appropriate structural and magnetic phases indicative of colossal magnetoresistance.     

全固态裸露式Ag／AgCl参比电极的研制及应用

该文报道了一种树脂接界全固态裸露式Ag／Agcl参比电极,勿需电镀氯化,制备工艺简单,性能稳定,是对电解型Ag／AgCl参比电极的一大改进。可代替饱和甘汞电极作为通用型参比电极,同时可减少汞对环境所造成的二次污染,在温度大于75℃时仍能保持良好性能,突破了甘汞电极的局限。     

An inexact hybrid projection-proximal point algorithm for solving generalized mixed variational inequalities

In this paper, we investigate an inexact hybrid projection-proximal method for solving a class of generalized mixed variational inequalities in Hilbert spaces. We construct a general inexact hybrid projection-proximal point algorithm, in which an inexact relaxed proximal point step is followed by a suitable orthogonal projection onto a hyperplane. Under some suitable conditions concerned with the pseudomonotone set-valued mapping T, the nonsmooth convex function f and the step size λ_k, we prove the convergence of the inexact hybrid projection-proximal point algorithm for solving generalized mixed variational inequalities in Hilbert spaces.     

Analysis of microwave brightness temperature of lunar surface and inversion of regolith layer thickness:Primary results of Chang-E 1 multi-channel radiometer observation

In China’s first lunar exploration project, Chang-E 1 (CE-1), a multi-channel microwave radiometer was aboard the satellite, with the purpose of measuring microwave brightness temperature from lunar surface and surveying the global distribution of lunar regolith layer thickness. In this paper, the primary 621 tracks of swath data measured by Chang-E 1 microwave radiometer from November 2007 to February 2008 are collected and analyzed. Using nearest neighbor interpolation based on the sun incidence angle in ...     

Group path covering and distance two labeling of graphs

For a positive integer d, an L(d,1)-labeling f of a graph G is an assignment of integers to the vertices of G such that |f(u)−f(v)|?d if uv∈E(G), and |f(u)−f(v)|?1 if u and u are at distance two. The span of an L(d,1)-labeling f of a graph is the absolute difference between the maximum and minimum integers used by f. The L(d,1)-labeling number of G, denoted by λd,1(G), is the minimum span over all L(d,1)-labelings of G. An L^′(d,1)-labeling of a graph G is an L(d,1)-labeling of G which assigns different labels to different vertices. Denote by the L^′(d,1)-labeling number of G. Georges et al. [Discrete Math. 135 (1994) 103-111] established relationship between the L(2,1)-labeling number of a graph G and the path covering number of Gc, the complement of G. In this paper we first generalize the concept of the path covering of a graph to the t-group path covering. Then we establish the relationship between the L^′(d,1)-labeling number of a graph G and the (d−1)-group path covering number of Gc. Using this result, we prove that and for bipartite graphs G can be computed in polynomial time.     

Necessary optimality conditions for fuzzy variational problems

The main aims of this study are to derive the fuzzy Euler-Lagrange conditions for both fuzzy unconstrained and constrained variational problems based on the concepts of differentiability and integrability of a fuzzy mapping that may be parameterized by the left and right-hand functions of its α-level sets.