工业埋地管道环氧煤沥青玻璃丝布防腐工程施工经验谈

从环氧煤沥青玻璃丝布施工方法及材料入手,分析了在防腐施工中应注意的问题,强调了过程控制的重要性。     

硬质合金刀片α-Al_2O_3涂层研究

采用一种全新的过渡层工艺,在过渡层上进行Al2O3化学气相沉积涂层,制备了单一α-Al2O3涂层,取代传统的κ-Al2O3涂层或κ-Al2O3和α-Al2O3混合涂层,应用于灰口铸铁高速切削加工,解决了传统的κ-Al2O3涂层或者是κ-Al2O3和α-Al2O3混合涂层高速切削中稳定应用的问题。     

38CrSi钢表面纳米结构层力学性能的研究

采用超音速微粒轰击技术在38CrSi合金钢表面制备了厚度约为25μm纳米晶层.利用X射线衍射、扫描电镜和透射电镜对表面结构进行分析.纳米结构层的最表面层的晶粒尺寸约为16nm,晶粒尺寸随着距表面距离的增加而增大.利用纳米压痕仪对表面纳米结构层的力学性能进行研究,结果表明,当表面晶粒尺寸降低到纳米量级时力学性能明显改善,最表面纳米结构层的硬度是基体的2倍左右,并服从Hall-Petch关系;表面纳米结构层的弹性恢复系数明显提高;利用该方法制备的纳米晶对弹性模量的影响较小;对表面纳米化样品进行低温退火处理可使纳米结构层的性能更加稳定.分析表明表面纳米结构层力学性能的改善主要是表面晶粒细化的结果.     

激光熔覆模压硬质合金粉末层的研究

利用液压机和简易模具直接将硬质合金粉末(25? 15%Co 60% WC)压制在碳钢基体上;采用大功率CO2激光器对预置层进行扫描,在一定工艺参数下得到了表面较为平整、无裂纹、与基体形成良好冶金结合的涂层;利用扫描电镜和显微硬度计对涂层进行成分、形貌和显微硬度分析.结果表明,在相对较软的涂层基体上分布着高硬度的条状碳化物及少量的鱼骨状共晶体.涂层的平均硬度达到56HRC.     

离心铸造轧辊外层熔炼配料的优化

离心铸造轧辊生产中为了减少外层气体含量，要求尽量少脱硫降硅、甚至不脱硫降硅，为此根据外层材料成分的不同要求，在配料过程中采用不同的原材料及不同的配比，最终达到工艺要求。并介绍为达到工艺要求对所需各种原材料的化学成分要求。     

Application of High Temperature Corrosion-Resistant Materials and Coatings Under Severe Corrosive Environment in Waste-to-Energy Boilers

Corrosion-resistant materials (CRMs) and coatings are key technologies to increase power generation efficiency and reduce maintenance in waste-to-energy (WTE) plants. Corrosion environment became severe as steam temperatures have increased. The steam condition of more than 400 °C/3.9 MPa became possible in WTE boilers by using highly durable corrosion-resistant coatings, such as thermal spray of Al/80Ni20Cr alloy, HVOF-sprayed NiCrSiB alloy, Alloy 625 weld overlay for waterwall tubes and also superheater tubes. Also, the use of 310S type stainless steels and high Cr-high Mo-Ni base and high Si-Cr-Ni-Fe alloys have progressed because of a better understanding of corrosion mechanisms. Furthermore, high durability coatings using cermet and ceramic materials were applied to high temperature superheaters. This paper describes the major developments and the application of CRMs and coating technologies in the last 30 years in WTE plants, the corrosion mechanisms of alloys, the deterioration mechanisms of spray coating layers, and future subjects for the development of corrosion-resistant materials and coatings.     

Flame-Sprayed Glaze Coatings: Effects of Operating Parameters and Feedstock Characteristics Onto Coating Structures

Many substrates do not sustain the conventional glazing process (i.e., vitreous glazing) due to the relatively high temperature required by this treatment (i.e., up to 1400 °C in some cases) to fuse glazes after their application on the surface to be covered. Flame spraying could appear as a solution to circumvent this limitation and to avoid thermal decomposition of substrates. This contribution describes some structural attributes of glaze coatings manufactured by flame spraying. It also discusses the influence of the feedstock powder morphology and some of its physical properties on coating characteristics. This article is an invited paper selected from presentations at the 2007 International Thermal Spray Conference and has been expanded from the original presentation. It is simultaneously published in Global Coating Solutions, Proceedings of the 2007 International Thermal Spray Conference, Beijing, China, May 14-16, 2007, Basil R. Marple, Margaret M. Hyland, Yuk-Chiu Lau, Chang-Jiu Li, Rogerio S. Lima, and Ghislain Montavon, Ed., ASM International, Materials Park, OH, 2007.     

热扩散对镁合金锌铝涂层界面组织和性能的影响

选用具有较低熔点的锌作过渡层,采用热喷涂工艺在AZ91D镁合金表面制备了锌铝涂层,并分析热扩散对锌铝涂层界面组织和性能的影响.研究表明:经热扩散处理后,涂层与基体界面处形成扩散熔合区,扩散熔合区由Mg-Zn-Al金属间化合物及其固溶体组成;由于扩散熔合区的形成,使涂层的显微硬度和耐磨性能均显著提高.     

液态钎料薄层中超声空化泡的成长与破裂

通过进行液态钎料Sn-9Zn的铺展试验,观察超声作用下钎料空化泡的成长破裂情况,得出液态钎料在超声作用下发生填缝行为并且形态以扇形进行扩散。通过Matlab语言,在超声空化理论的基础上,从温度、超声频率、空化泡初始半径以及空化泡崩溃时的最大温度和最大压力四个方面,对Sn-9Zn,Sn-0.7Cu和Zn-5Al三种液态钎料空化泡的成长和破裂进行模拟,得到了空化泡的运动情况。结果表明,温度越高,空化效应越弱;超声频率增大,空化效应减小;空化泡初始半径越小,空化泡的空化效应越明显;空化泡崩溃的最大温度同绝热指数成正比,而崩溃时的最大压力同绝热指数和反应体系的温度成反比。研究结果对超声波辅助钎焊中液态钎料空化效应的研究和应用提供了参考。     

镀Cu层调控AZ31B/TC4激光熔钎焊接特性

采用钛表面电镀铜作为中间层,开展镁(AZ31B)/钛(TC4)对接激光填丝熔钎焊,对镁/钛非互溶不反应焊接体系进行调控. 主要研究了激光功率对镁/钛接头焊接质量的影响规律,进一步分析了不同工艺参数条件下镁/钛界面组织及接头力学性能. 结果表明,铜镀层提高了熔融焊丝在母材表面的润湿铺展并卷入到焊缝组织中,随着激光功率的增加,镁/钛界面形成Ti₃Al反应层的能力提高,界面结合强度随之提高. 在较高激光功率1 700 W时,接头拉伸载荷最高达到3 085 N,为镁母材的76.2%,而接头在较高激光功率下的断裂模式也由完全界面断裂转变为部分界面断裂.