A new dynamic hydrogen reference electrode for applications in thin-film sensor systems

The realization and applicability of a new dynamic hydrogen reference electrode (DHRE) within an electrochemical microcell for sensor applications is reported. The electrodes are fabricated in thin-film technology and fixed within a flow-through device. An experimental setup for accurate electrochemical potential measurements is described. Smooth platinum, platinized platinum and pHEMA coated electrodes are investigated with regard to their initialization behavior, stability, reproducibility and interference with electrolytes. It is found that platinized platinum DHREs show excellent stability and reproducibility. For uncoated electrodes, the electrochemical potential is established within seconds. The potential is independent of the pH value within the range of pH 4–10. Interference with sulfate and phosphate is observed. Thus, the platinized platinum DHRE is well suited for bioanalytical sensor applications, where the pH value is buffered and the concentrations of the disturbing anions are constant or very low.     

Nanoparticle-based lift-off technique for ultra-thin nanoporous film preparation

Ultra-thin membrane with nanoscale through hole has great potential in biomedical applications, where precise controllability of porosity, pore size and film thickness is urgently required. The present work proposed a cost-effective way to prepare the ultra-thin nanoporous film with a promising controllability. Monodispersed nanoparticle, rather than photoresist, is used as the sacrificial material for this new lift-off process. By releasing the particles, holes can be achieved with predeter-mined characters. A 110 nm-thick nanoporous aluminum film with well-controlled pore＇s diameter was successfully fabricated to validate the technique. The technique has wider process window and better applicability than other nanofabrication methods.     

cdSe_xTe_(1-x)薄膜电极光溶解性能的研究

用循环伏安法对半导体Cdse_xTe_(1-x)薄膜电池的光溶解性能进行了研究。在1mol/L KCl溶液中测量光溶解产物的阴极还原特性,考察了在多硫化钠,多硫化钾及铁氰化钾溶液中的光腐蚀行为。用此方法还研究了薄膜电极表面的光刻蚀过程和pH的影响,并用X射线光电子能谱分析光刻进行不同时间后,电极表面发生的变化。     

金属表面环氧漆漆膜拉伸剪切强度的测定

借鉴国标胶粘剂拉伸剪切强度测定方法测定了阳极、阴极环氧电泳漆与环氧涂料在底材为铝合金及钢材上漆膜的拉伸剪切强度，在铝件及钢铁件表面上阳极电泳漆漆膜的拉伸剪切强度为11．60MPa及17．91MPa，阴极电泳漆漆膜分别为17．60MPa及23．20MPa，喷涂环氧漆膜为7．93MPa 及13．40MPa，并介绍了测定试验中的实际操作经验和技术细节。     

硝铵装置降膜蒸发存在问题与改进措施

对我公司硝铵装置降膜蒸发工序存在的问题进行分析 ,并通过技术改进 ,使干燥洗涤液全部返回系统 ,造粒塔粘塔问题得到缓解 ,取得可观的经济效益和环保效益     

Effect of polycarboxylate-type superplasticizer on the paste fluidity based on the water film thickness of flocs

The excess water film theory and the properties of flocs are integrated to examine the effect of the polycarboxylate-type superplasticizer on the paste fluidity.The theory states that excess water can surround the flocs rather than the particles and that the cell consists of a floc and a superficial water film.Experiments on limestone powder pastes were conducted to verify the theory.The superplasticizer dosage(sp%)and the water–powder ratio by volume(Vw/Vp)were systematically varied.A sedimentation balance method was used to measure the size distribution of the flocs in the limestone powder pastes.The water film thickness(WFT)of flocs was then calculated and shown to determine the paste fluidity.Based on this WFT of flocs,the effect of the sp on the paste fluidity was determined and then compared with the effect of water.     

环保高性能防腐涂料驱动未来市场

介绍了防腐涂料的新品种和防腐体系的选择,指出了我国防腐涂料的发展趋势。     

汽车防护条塑料件的涂装工艺及设计

介绍了汽车防护条的预处理工艺、涂装工艺及设计原则,列举了防护条涂装工艺的应用实例。