Modeling and simulation of an oxy-fuel combustion boiler system with flue gas recirculation

In this paper, a mathematical model of an oxy-fuel combustion boiler system with flue gas recirculation is investigated. The reduction of CO₂ emission from coal-fired power plants is an important research issue in alleviating the global warming. The entire dynamics are decomposed in two main parts; fire-side dynamics and water-side dynamics. The fire-side dynamics consist of the mass and energy balance equations in the furnace (combustion process) and the flue gas dynamics represented by the mass balance equations of five gases (O₂, CO₂, SO₂, H₂O and NO₂). The water-side dynamics include a drum pressure equation and a steam temperature equation. To validate the developed models, the real experimental data in Karakas, Koumanakos, et al. (2007) are used. To investigate the local behavior near an operating point, a linearization method at its steady-state condition is pursued. The time responses of the entire dynamics using step inputs (the oxygen mass flow rate, the coal mass flow rate, the primary air mass flow rate, etc.) are also discussed.     

涤纶织物化学镀银纳米Al2O3复合镀层

用不同分散剂进行涤纶织物纳米Al2O3颗粒化学复合镀银.镀银液配方为:硝酸银5.1g/L,葡萄糖8g/L,氢氧化钾3.5 g/L,氨水适童.结果发现:使用纯水分散时镀速最快;用聚乙烯吡啶烷酮和海藻酸钠混合物分散时镀层表面粗糙,但耐磨性能和结合力有所提高.加入纳米Al2O3颗粒对镀层结构没有影响,但会使晶粒尺寸增大.与普...     

弯曲裂缝对再生混凝土构件碳化性能影响的试验研究

混凝土是脆性材料,抗拉强度远低于其抗压强度,钢筋混凝土构件在使用时往往处于带裂缝工作状态.当钢筋混凝土构件表面混凝土的裂缝达到一定宽度之后,经过时间的推移,有可能直接影响结构的正常使用以及耐久性,甚至影响结构的功能和安全性.试验着眼于再生混凝土表面弯曲裂缝对钢筋混凝土构件碳化性能的影响,以不同强度等级(C20、C40)和裂缝宽度(0.1 mm、0.2 mm)为变动因素进行了对比性碳化试验,试验结果表明,与没有倒入微裂缝的对比用普通混凝土试件以及再生混凝土试件相比,再生混凝土试件表面的弯曲裂缝对混凝土碳化性能的影响要比裂缝宽度对混凝土碳化性能的影响更大.     

PET共聚酯的热性能及其纤维的力学性能

直接酯化法合成了一系列聚对苯二甲酸乙二酯(PET)-间苯二甲酸双羟乙酯磺酸钠(SIPE)-聚乙二醇(PEG)共聚酯,以差示扫描量热分析法(DSC)研究了这些共聚酯及纯PET的熔融和结晶过程,并利用万能材料测试仪研究了纤维的力学性能。试验结果表明:加入SIPE和PEG后,共聚酯熔点(Tm)、玻璃化转变温度(T)g降低;随着PEG相对分子质量的增大,PET共聚酯的Tg、冷结晶温度(Tc)c、Tm、结晶温度降低(T)c,纤维的断裂强度和初始模量下降,断裂伸长率增加。     

从织物弹性考查PTT/PET双组分长丝的制造技术

首先采用自纺丝和企业中试丝两大系列18种聚对苯二甲酸丙二酯(PTT)/聚对苯二甲酸乙二酯(PET)双组分长丝,试制了18种机织物试样,并进行织物弹性测试,分析复合方式、PTT组分特性黏度和含量、热盘温度4个主要纺丝工艺参数对织物弹性的影响。试验发现,在采用板内复合纺丝方法,PTT和PET两组分特性黏度差较大,热盘温度高的纺丝条件下,织物的定力伸长率比较大;文献资料报道的PTT质量分数为50%时双组分纤维卷曲曲率及卷曲伸长率最大仅仅是某些条件下的试验结果,当PET与PTT弹性模量比(e)较大时,存在例外情况。     

Coating films prepared by photoreactions of the surface‐modified diamond powder and PET film with a binder agent

The surface‐modified diamond and PET film underwent photopolymerization rapidly with a binder agent to afford coating films of interpenetrating network (IPN) structure. The coating films thus formed exhibit higher tensile strength, thermal stability, and adhesion strength to the PET film. The inert surfaces of pristine diamond (PD) and PET film were modified by different chemicals and procedures to introduce epoxide and methacryloyl groups, respectively, on their surfaces. A coating agent consisting of an epoxide group containing modified diamond (called ED), a binder agent, and photoinitiators was prepared. After applying the coating agent to the substrate (a glass plate or a methacryloyl group containing PET film, MMA‐PET) and degassing under reduced pressure, the thin film of the coating agent was exposed to UV light (λ_max; 365 nm) at room temperature to yield a coating film of IPN‐structure. The tensile strength and thermal properties of the ED‐containing free coating film (called free film) increased with the amount of ED embedded, whereas the strength of the PD‐containing free film decreased with the amount of PD embedded. The adhesion strength of the coating film on the MMA‐PET improved significantly by the free radical polymerization of the methacryloyl groups on the MMA‐PET and the acrylate resin in the binder agent. The surface photoreactions of ED and MMA‐PET with the binder agent were confirmed by modeling. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011     

废玻璃混凝土最优复掺方式及耐高温性能研究

目前将废玻璃进行填埋处理不仅污染了环境,也是对资源的浪费.将固废物进行资源化利用,实现循环经济是可持续发展战略的重要内容.为提高废玻璃利用率,选取废玻璃粉作为辅助胶凝材料取代混凝土中的部分水泥,同时废玻璃作为粗、细集料取代混凝土中的部分石子、河砂,研究其复掺方式对再生混凝土抗压强度的影响,并确定最优掺加方式.在此基础上...     

双钢板-再生混凝土组合剪力墙抗震性能有限元分析

为研究双钢板-再生混凝土组合剪力墙的抗震性能,在已有试验的基础上,使用有限元软件ABAQUS进行模型验证和分析,研究内容包括再生粗骨料取代率、距厚比、轴压比以及连接件形式.结果表明:(1)随再生粗骨料取代率的增加,试件抗弯承载力、抗剪承载力、初始抗侧刚度均出现不同程度的劣化;(2)当轴压比为0～0.5时,试件承载力随轴...     

LLDPE-g-GMA对PET/LLDPE性能的影响

自制了线性低密度聚乙烯与甲基丙烯酸缩水甘油酯接枝物(LLDPE-g-GMA)，研究了LLDPE-g-GMA对聚对苯二甲酸乙二酯／线性低密度聚乙烯(PET／LLDPE)合金体系力学性能、结晶行为及玻璃化转变活化能的影响。结果表明，LLDPE-g-GMA有效地改善了PET／LLDPE的拉伸性能、弯曲性能及冲击性能；同时LLDPE-g-GMA的加入提高了PET的结晶速率，两者有较好的相容性；动态力学试验结果也证明了LLDPE-g-GMA与PET有较好的相容性。LLDPE-g-GMA可以作为PET／LLDPE体系的反应性增容剂。     

聚酯啤酒瓶现状及展望

综述了近年国外对PET，PEN啤酒瓶的开发和应用，讨论了两者的利弊，指出由于PEN啤酒瓶性能优越，可回收并且生产成本有望大幅度降低，是今后塑料啤酒瓶的主流。