Dielectric study of β-relaxation in some cellulosic substances

6-(2-Cyanoethylamino)-6-deoxycellulose (Cell-CEA) as a novel cellulose derivative was prepared from 6-bromo-6-deoxycellulose. The influence of the reaction conditions on the degree of substitution was studied in detail. The dielectric characteristics of a Cell-CEA sample having degree of substitution of 0.86, together with those of microcrystalline and regenerated celluloses, have been investigated in the temperature range from −60 to 120°C, and frequency range 30 Hz to 100kHz. One relaxation process, designated as β, was recognised, which was attributed to side-group motions, probably −CH₂X (X = OH or NHCH₂CH₂CN). The higher activation energy of this process and the shift to higher temperature in Cell-CEA, compared with microcrystalline and regenerated celluloses, reflects the enhanced steric constraints involved in the motion of the bulkier, −CH₂NHCH₂CH₂CN, side groups. The results obtained are discussed in terms of the dielectric parameters ϵ″_max′ β and Δϵ.     

大型催化裂化再生烟气实现超低排放——从构思到工业实践

国内外催化裂化装置再生烟气治理一般采用湿法脱硫工艺,其特点是适应性和脱硫效果较好,但投资和运行维护费用较高,设备腐蚀、高含盐废水排放、烟羽拖尾等一系列问题难以解决,急需寻找更好的处理方案.中国石油化工集团公司针对催化裂化再生烟气的特点,从再生过程的SOx和NOx产生源头控制,集成开发了负压式半干法烟气超低排放治理技术,...     

PET Recycling – Contributions of Crystallization to Sustainability

Polyethylene terephthalate (PET) is one of the most common thermoplastic polymers and its durability has become a major environmental concern. The current public debate on plastic debris also triggered the revision of PET recycling technologies. This Research Article focuses on the chemical recycling of PET by means of methanolysis. The process degrades PET into two main reaction products, dimethyl terephthalate (DMT) and ethylene glycol (EG). Subsequent separation by distillation combined with crystallization removes critical impurities and non-PET components from co-polymers, providing monomers of high purity needed for re-polymerization purposes.     

PET/PC共混物配比对其高压结晶行为的影响

利用SEM及W AXD等测试手段研究了配比对PET/PC共混物高压结晶行为的影响。SEM观察表明,随PC比例的增加,共混物高压下主要结晶形态以伸直链晶体,生长成熟的立体开放球晶,大尺寸球晶的方式变化。拟合分峰法和W arren-A verbach傅氏分析法的计算结果表明,随PC含量的增加,高压结晶共混物的结晶度降低,PET的平均晶粒尺寸总体呈减小趋势,晶粒尺寸分布则变窄,而晶格畸变平均值在一定PC比例范围内达到极大值。     

PET和PA纤维的原液染色与纺织品染色:对立还是互补

比较了PET和PA纤维的原液染色与纺织品染色.详细描述了原液染色和纺织品染色的优缺点.讨论了汽车用染色物品的着色和色彩协调.介绍了Clariant产品(瑞士)公司开发的"可染色的"颜料.     

共聚PET固相聚合粘度变化规律的研究

利用固相聚合生产装置,研究了共聚PET固相聚合反应温度、停留时间、氮气流量、催化剂含量、基础切片端羧基含量对增粘的影响。结果表明:在一定的工艺条件下,产品粘度随反应温度提高、停留时间的延长及催化剂含量的增大而增大;当气固比大于0.3时,增大氮气流量对增粘速率不再产生影响。     

再生丝素蛋白/羟基磷灰石多孔复合材料的制备

再生丝素蛋白具有良好的生物相容性,羟基磷灰石同时还具有成骨诱导性。通过将再生丝素蛋白制备形成丝素蛋白多孔材料,并在37℃下将其浸渍于模拟体液中可以制备再生丝素蛋白/羟基磷灰石多孔复合材料。扫描电镜研究发现在再生丝素蛋白多孔材料的孔隙中羟基磷灰石由针状晶体聚集而成,红外光谱和XRD等表征表明复合材料中羟基磷灰石以羰基取代的羟基磷灰石存在。制备的再生丝素蛋白/羟基磷灰石多孔材料有望作为骨组织修复材料使用。     

笼式反应器的功率特性

以聚酯笼式终缩聚反应器开发为背景 ,在采用库特流模型对反应器偏心环隙流功率特性进行理论分析的基础上 ,考查了介质黏度、装料液位、转速等因素对笼体和网面功率消耗的影响 .结果表明 :转速影响最大 ,而液位影响最小 ,最终得到了笼体和网面功率关联式 ,实验测定结果与理论分析基本吻合     

多浇口热流道注射成型PET瓶坯

研究了多浇口一模四腔热流道注射成型PET饮料瓶坯的模具结构、成型工艺,取得良好效果。     

18F-FDG PET/CT全身显像受检者辐射剂量研究

目的 研究受检者在全身18F-FDG PET/CT 显像中所受到的辐射有效剂量.方法 选取58例全身PET/CT显像的受检者,在自动曝光技术下通过公式估算出CT 和PET 的全身有效剂量,并将估算结果与传统放射检查（常规CT、X线、99mTC核素显像）相比较.结果 单次全身PET/CT 显像受检者所接受的CT 有效剂量为2.4～6.8 mSv,平均（4.3±2.2）mSv,PET 有效剂量为4.2～6.3 mSv,平均（5.5±1.5）mSv;PET/CT 总有效剂量为6.6～13.1 mSv,平均（9.8±3.3）mSv.其辐射总有效剂量与一次腹部或盆部常规CT扫描所产生的辐射剂量相当.结论 单次全身PET/CT检查受检者所接受的辐射剂量是安全的.