凝胶色谱法表征我国几种有代表性超滤膜的截留率——分子量曲线

本文考察了凝胶色谱法的操作压力和进料流速的影响。对国内具有代表性的几种平板超滤膜(聚砜、聚砜酰胺、醋酸纤维素、聚丙烯腈、聚氯乙烯)以及聚砜中空纤维超滤膜的截留率——分子量曲线进行了测定。并给出它们的切割分子量数据。     

乳胶涂料中填料粒径测定与分散剂的选择

介绍了重力沉降法和容量沉降法两种测定乳胶涂料中填料粒径的方法。通过比较粉体粒径结果显示：沉降法比激光法更形象直观，更能代表体系粒径真实情况。以滑石粉、重钙、轻钙粉体为基准，采用不同用量、不同类型的分散剂的容量沉降法进行比较得出：用容量沉降法能定量地对分散剂性能做出评价。     

Estimation of the critical properties of compounds using volume-based thermodynamics

The importance, yet scarcity of the critical constants of thermally unstable fluids warrants the development of reliable methods for the estimation of these essential thermodynamic properties. A thorough investigation undertaken in this study on 1,589 compounds belonging to 83 chemical classes, indicated that the ratio of critical temperature to critical pressure of both low and high molecular weight compounds could be well expressed in terms of their volumetric properties. In addition, two new methodologies are presented for estimating V_c, as well as an indirect approach for prediction of T_c from surface tension data, altogether allowing the calculation of Z_c. Moreover, comparative studies are made with five group contribution methods. It is also demonstrated that by employing the Peng-Robinson EOS, and without prior knowledge of the critical properties, it is possible to calculate various thermophysical properties including P^sat., T_b, , ∆H^vap. , C_p, and even the T_c and P_c themselves.     

聚氨酯的阻尼性能与频率关系的研究

从时温等效原理出发,依据WLF方程和自由体积理论推导了一个较为简单的将高分子材料的温度谱转变为频率谱的方法。用该方法计算得到的损耗因子与实验数据吻合得很好。研究了所合成的聚氨酯材料在1～10000Hz范围内的特征阻尼频率.结果表明25℃下.含填料的H052的特征阻尼频率为5430Hz。     

CORRELATION OF DIFFUSION COEFFICIENTS FOR LIQUIDS AND DENSE FLUIDS WITH TEMPERATURE AND PRESSURE

On the basis of the free volume theory and activation energy concept,a fundamental equation whichtakes into account the effects of temperature and pressure has been developed.By introducing differentexpressions for the free volume and activation energy,several equations for fluid diffusion coefficients were derivedaccordingly.With the van der Waals free volume and intermal energy formula,a three-parameter model for fluiddiffusion coeffficients at moderate pressure was obtained.The grand average absolute deviation percent of 345data points (44 systems)for self-and infinite dilute inter-diffusivities is 2.32,against the results of the model ofCohen and Turnbull,4.13.In particular,by means of the modified Carnahan-Starling free volume equation,afour-parameter model with average abosolute deviation percent 2.64(30 systems,644 data points)for theestimation of dense fluid inter-and self-diffusivities at high pressures and in supercritical conditions was derived.The derived model is superior to the method of L     

分子电距矢量对竹叶挥发油成分的色谱保留时间的估计和预测

用分子电距矢量描述子(MEDV)对24个从慈竹叶中分离出的挥发油成分的分子结构进行了表征,应用多元线性回归技术建立了结构描述子MEDV与这些化合物的色谱保留时间的定量相关模型。对9参数模型进行线性回归,复相关系数达到了0 995,但交互检验的相关系数为-3 019。对此模型进行改进,采用逐步回归5参数模型,复相关系数为0.993,交互检验的相关系数RCV值提高到0 984,表明5参数模型对样本具有良好的估计和预测能力。     

Increased hydropower production and hydropeaking mitigation along the Upper Inn River (Tyrol,Austria) with a combination of buffer reservoirs,diversion hydropower plants and retention basins

Research on hydropeaking in Austria started in the 1990s and the implementation of the WFD stipulated large research projects since the year 2009. The first research projects supported the process understanding and in a second investigation step, measures were evaluated. The mountains in the region of Tyrol create large heads and thus support the production of flexible energy. In this region, TIWAG is operating 9 large (>10 MW) and 27 small (<10 MW) hydropower plants, with an installed capacity of about 1,550 MW and a mean annual production of 3,000 GWh. As the governmental energy strategy foresees an extension of the hydropower production in Austria, suitable options were selected in 2004 by TIWAG and the water management framework plan for Western Tyrol was developed. This strategic planning instrument proposes five large power plants, with a generation of 1,800 GWh/year of renewable energy, which enables to reach the WFD targets, because the concept includes hydropeaking mitigation by combining buffer reservoirs (impoundments), diversion hydropower plants, and retention basins. We present our promising concept of hydropeaking mitigation and exemplify this based on the GKI, a hydropeaking diversion hydropower plants (HPP) at the Swiss/Austrian border as well as the Silz hydropeaking retention basin, with a volume of about 300,000 m³. As the presented case studies are the largest measures for hydropeaking mitigation being currently implemented in Central Europe, they have pilot-character. Thus, ongoing research and monitoring programs are expected to improve the knowledge about hydropeaking mitigation.     

基于LVM 的系统扩容技术研究

近年来,随着大数据业务的使用,系统在运行时会产生大量的数据信息与日志文件并保存在磁盘中。由于在系统规划初期,对系统分区大小规划预期不足,很难合理规划磁盘空间,造成后期系统运行中经常出现系统分区磁盘不足的问题。当发生此类告警时,通常的分区很难动态调整大小,通常采用暂停业务,更换磁盘,数据备份与恢复的方式,该方式操作困难,程序复杂,有数据丢失的风险。在Linux系统里使用LVM(逻辑卷)技术,支持在线空间扩容,可以在用户无感知的情况下扩展系统分区容量,达到合理利用磁盘空间的目的。本文介绍了LVM技术,并在Linux系统里将分区做成逻辑卷,达到合理利用磁盘空间的目的。     

基于反应扩散方程的水平集结构拓扑优化方法与实现

为实现更加先进的拓扑优化算法,研究采用反应扩散方程的水平集结构拓扑优化方法,通过理论推导给出算法中的参数选择建议.该方法允许在拓扑优化过程中生成新的孔洞,初始结构无须包含孔洞,不需要重新初始化步骤,从而可提高算法的收敛性.针对传统拓扑优化中主要采用体积约束、以柔度最小为目标和体积保留率设定存在一定主观性的问题,探究不同体积保留率下的结构应力水平的变化规律,结果显示可以依据结构最大应力水平与体积保留率的变化规律确定最优体积保留率.     

有创呼吸机停机后自动护理启动方法研究

为提高有创呼吸机停机后自动护理的启动速度,设计一个有创呼吸机停机后自动护理启动方法。通过吸潮气流量与呼吸频率计算,对患者呼吸状态进行判断,并增加了呼吸触发误判识别功能,确定有创呼吸机停机后自动护理启动状态,采用PI算法进行启动控制,以此完成有创呼吸机停机后自动护理启动。实验结果表明,此次研究的有创呼吸机停机后自动护理启动方法,在1分钟之内就能够及时启动自动护理功能,并且能够准确判断患者呼吸频率,满足了有创呼吸机停机后自动护理启动方法的设计需求,具备一定的实际应用意义。