压延铜箔电镀Zn-Ni合金工艺研究

研究了硫酸盐-柠檬酸体系电镀锌-镍合金工艺。该锌-镍合金作为印制板用压延铜箔的阻挡层。考察了镀液主要成分及工艺条件对压延铜箔性能的影响,并对各因素进行分析,由此确定了压延铜箔电镀锌-镍合金工艺条件。经测试,使用该工艺处理的压延铜箔与印制板基板具有良好的结合力,并具有较强的耐腐蚀性。     

UV photo‐stabilization of tetrabutyl titanate for aramid fibers via sol–gel surface modification

Tetrabutyl titanate was used as sol–gel precursor of a nanosized TiO₂ coating to improve the photo‐stability of aramid fibers. The nanosized TiO₂ coating was characterized by XRD and XPS. The influence of the TiO₂ coating on photo‐stability of aramid fibers was investigated by an accelerated photo‐ageing method. The photo‐stability of aramid fiber showed obvious improvement after coating. After 156 h of UV exposure, the coated fibers showed less deterioration in mechanical properties with the retained tensile strength and elongation at break greater than 36 and 50% of the original values, respectively, whereas the uncoated fibers degraded completely and became powdery. SEM analysis showed no significant surface morphological change on the coated fiber after the exposure, while some latitudinal crack fractures appeared on the uncoated aramid fiber. The effect of the nanosized TiO₂ coating was also well demonstrated by examining the difference of distributions of C1s in XPS deconvolution analysis on the surface of uncoated/coated fibers with increasing UV exposure time. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 3113–3119, 2007     

Hydrotreating processes for catalytic abatement of water pollutants

Opportunities and problems in application of catalytic hydrotreating processes, which are presented a viable approach in the abatement of water pollutants, are discussed. Analysis of the hydrodechlorination (HDC) and hydrodenitrification (HDN) using Pd-based catalysts supported on various materials like granulated activated carbon (GAC), fibrous activated carbon cloths (ACCs) or glass fiber cloths (GFCs) studied recently in our laboratory suggests the following perspectives:

Exhaustive regeneration of Pd/GAC saturated with p-chlorophenol can be achieved in a two-step approach, incorporating gas-phase HDC by hydrogen followed by oxidation by air.

Pd/ACC catalysts are good candidates for the liquid-phase HDC showing activity higher than that of Pd/GAC or Pd/GFC; the high adsorption capacity of Pd/ACC lead suggesting its use in a technology with periodic adsorption and HDC, in similarity to adsorption with regeneration of GAC.

Pd/GFC and Pd–Cu/GFC are promising catalyst for removal of nitrites and nitrates, showing activity and selectivity that compares favorably with those of powdered catalysts.

高强箍筋混凝土简支梁抗剪承载力试验研究

通过对14根500 MPa细晶粒钢筋、1根400 MPa及1根600 MPa钢筋做箍筋的混凝土简支梁在集中荷载作用下的试验,观测了不同混凝土强度、不同剪跨比、不同箍筋强度、不同配箍率、不同截面尺寸条件下试件的裂缝、挠度、承载力及破坏形态;并将实测值与有关公式的计算值进行了比较.试验结果表明,构件的斜截面承载力仍可按现行《混凝土结构设计规范》的相关公式进行计算,并有足够的安全储备.     

废棉布制备高粘度羧甲基纤维素

为纺织废料的再利用,本文以废棉布为原料制备高粘度羧甲基纤维,采用碱醚同釜法及正交实验,通过测试粘度得到最佳反应条件为:浴比为1∶3,氢氧化钠质量分数为30%,氯乙酸乙醇质量分数为30%,醚化时间为2 h,碱化时间为2 h,碱化温度为35~40℃,醚化初期温度为40~45℃,后期温度为70℃,羧甲基纤维素的的粘度值为932.6mPa.s。     

酸性KMnO_4条件下芳纶纤维的表面改性研究

利用KMnO4在酸性的环境中具有氧化性的特性对芳纶纤维进行表面改性研究,分析其表面形貌、强力以及拉伸性能的变化;采用扫描电子显微镜观察处理前后芳纶纤维的表面形态特征;以夹角余弦幅度法确定权重;利用模糊正交法的理论与方法处理试验数据,得出模糊综合评价值.从而得出最佳实验指标为:硫酸质量分数10%,KMnO4质量浓度5 g/L,处理温度为30℃,处理时间35 min.     

热定型工艺对斜纹涤纶机织滤布透气性能的影响

通过改变热定型温度、时间等工艺条件测试了织物热定型前后的透气性的变化,探讨了热定型工艺参数对涤纶机织滤布透气性的影响规律;采用二次回归正交设计得出斜纹涤纶机织滤布透气性与定型工艺的非线性关系,建立了热定型工艺与织物透气性影响规律的二次回归非线性经验方程.在定型温度为212℃、定型时间为143 s时涤纶机织滤布的透气量达...     

芳纶帘线——轻型载重子午线轮胎理想的胎体骨架材料

采用芳纶帘线替代普通聚酯帘线进行轻型载重子午线轮胎的生产，并将两种化胎性能进行了对比。结果表明，采用芳纶帘线生产的轮胎静负荷性能、耐外性能、强度性能及高速性能等均可达到普通聚酯帘线轮胎的水,轮胎的刚性、转向能动性和驾驶性能提高，而且还可提高生产效率，同时减小了轮胎质量，节约了成本。     

基于机器学习合成高分辨率布料褶皱

为了精化布料网格得到逼真的布料模拟效果,提出了一种基于机器学习的方法合成高分辨率布料褶皱。首先模拟真实的布料运动,获取布料运动的帧数据信息,将布料运动的帧数据信息转换为图像信息的形式进行存储。然后将图像信息作为输入,输入到卷积神经网络(CNN)中进行训练,通过将卷积神经网络与缩小网络相结合,最终得到高分辨率布料图像。最后将高分辨率布料图像转换为高分辨率布料网格,对布料进行模拟。实验结果表明,与初始的低分辨率布料网格对比,合成的高分辨率布料网格模拟出的布料有着大量且细微的褶皱,并且能够模拟出真实的布料效果,与真实场景中的布料模拟效果相似。该方法在不同的场景中都可以模拟出高质量的布料动画效果,而且减少了仿真速度,验证了该方法的有效性。     

预应力纤维布加固混凝土梁冻融特性试验

为了研究预应力碳纤维布对受冻融作用影响的混凝土梁的加固效果,从而进一步认识混凝土与碳纤维布共同工作的行为,研究了加固梁中碳纤维布和混凝土的各自力学性能以及碳纤维布加固混凝土梁的整体力学性能.结果表明,冻融后的试验梁开裂荷载和极限承载力有所下降;初始预应力水平越高,试验梁的开裂荷载和极限荷载下降速度越快;在冻融循环和预应力耦合作用下混凝土内部损伤严重,碳纤维布-混凝土界面的粘结力退化明显.