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排序方式: 共有6128条查询结果,搜索用时 18 毫秒
51.
Karin Yaccato Alfred Hagemeyer Andreas Lesik Anthony Volpe Henry Weinberg 《Topics in Catalysis》2004,(1):127-132
High-throughput synthesis and screening methods have been developed for the discovery of highly active lead compounds for the selective catalytic reduction as well as direct decomposition of NO in the temperature range 200–300 °C. The discovery libraries for primary screening consisted of 16 × 16 catalyst arrays on 4in. square quartz wafers. Catalysts were prepared by robotic liquid dispensing techniques and screened for catalytic activity in Symyx' scanning mass spectrometer. The scanning mass spectrometer is a fast serial screening tool that uses flat wafer catalyst surfaces, local laser heating, a scanning/sniffing nozzle and a quadrupolar mass spectrometer to compare relative catalytic activities. The feed consisted of NO/NH3 mixtures with optional O2 cofeed and Kr as the internal standard in Ar carrier gas. QMS detection allowed for tracking of H2O, N2, NO, O2, N2O and Kr. Screening protocols for catalytic materials encompassed metal precursors and carriers for supported vanadia systems, extensive doping of V2O5/TiO2, and broad screening of mixed redox metal oxides and supported base and noble metal systems. More than 500 samples could be screened in a single day. Active hits (high NO consumption accompanied by corresponding N2 production) identified in discovery libraries were re-synthesized as focus libraries for lead confirmation and further optimization. These libraries used shallower compositional gradients, for example 56 points (compositions) per ternary, with four 56-point ternaries per 4in. wafer. Broad screening ternaries were generally 8 or 15 points. The focus libraries more clearly reveal the trends and provide guidelines for secondary screening and scale-up. High conversions were achieved in scanning mass spectrometer so the scalability risk is small for the short contact time reactions. 相似文献
52.
The selective oxidation of n-butane to maleic anhydride(MA) on a vanadium-phosphorus oxide (VPO) catalyst was studied using on-line gas-chromatography combined with mass spectrometry(GC-MS) and transient response technique.The reaction intermediates,butene and furan,were found in the reaction effuent under near industrial feed condition (3% butane 15% O2),while dihydrofuran was detected at high butane concentration (12% butane,5%O2).Some intermediates of MA decomposition were also identified.Detection of these intermediates shows that the vanadium phosphorus oxides are able to dehydrogenate butane to butene,and butene further to form MA.Based on these observations,a modified scheme of reaction network is proposed.The transient experiments show that butane in the gas phase may directly react with oxygen both on the surface and from the metal oxide lattice,without a proceeding adsorption step.Gas phase oxygen can be adsorbed and transformed to surface lattice oxygen but it can not participate in selective oxidation.Adsorbed oxygen leads to deep oxidation,while lattice oxygen leads to selective oxidation. 相似文献
53.
The adsorption properties of oxygen and methane on Ga-ZSM-5 and Cu-ZSM-5 catalysts were examined by a TPD method to clarify the extraordinary selectivity of HC-SCR using methane on Ga-ZSM-5. It was observed that Ga-ZSM-5 did not adsorb oxygen but adsorbed methane dissociatively, while on Cu-ZSM-5 oxygen was dissociatively adsorbed and reacted with adsorbed ethylene. 相似文献
54.
改性皂土催化下甲苯的浓硝酸硝化(Ⅶ) 总被引:1,自引:2,他引:1
在皂土硝酸盐催化下,甲苯能被浓硝酸对位选择性硝化,对邻硝化产物比率达1.0以上。 相似文献
55.
Tae Hwan Kim B. Ramachandra Jung Sik Choi M. B. Saidutta Ko Yeon Choo Sun-Dal Song Young-Woo Rhee 《Catalysis Letters》2004,98(2-3):161-165
Methanol selective oxidation to formaldehyde over a modified Fe-Mo catalyst with two different stoichiometric (Mo/Fe atomic ratio = 1.5 and 3.0) was studied experimentally in a fixed bed reactor over a wide range of reaction conditions. The physicochemical characterization of the prepared catalysts provides evidence that Fe2(MoO4)3 is in fact the active phase of the catalyst. The experimental results of conversion of methanol and selectivity towards formaldehyde for various residence times were studied. The results showed that as the residence time increases the yield of formaldehyde decreases. Selectivity of formaldehyde decreases with increase in residence time. This result is attributable to subsequent oxidation of formaldehyde to carbon monoxide due to longer residence time. 相似文献
56.
The surface coverage analysis derived from two formal steady-state kinetic models is compared to values directly obtained
from steady-state isotopic transient analysis (SSITKA) for the selective catalytic reduction (SCR) of NO by CH4 over Co-ZSM-5 catalysts. It is shown that the most abundant reacting intermediates are NO
x
adspecies, though no clear differentiation between the various adspecies identified by DRIFT spectroscopy was achieved. Less
numerous carbon containing adspecies were identified and quantified in the reacting system, essentially as methoxy species.
Nitromethane-like intermediates remained undetectable due to a very rapid transformation into N2 and CO2. On the basis of these converging kinetic analyses related to each elementary step of the SCR process, a microkinetic model
can be derived, which allows describing transient operation, in view of a non steady-state application. 相似文献
57.
不同分散剂对细粒高硫煤及煤系黄铁矿的选择性分散 总被引:1,自引:0,他引:1
主要研究六偏磷酸钠和腐植酸纳2种分散剂分别对细粒高硫煤、煤系黄铁矿悬浮液的分散作用,考察了分散剂用量、介质pH值对细粒煤与煤系黄铁矿选择性分散的影响。 相似文献
58.
Polycrystalline Ag treated with O2 at pressures up to 1 bar and at temperatures up to 920 K was examined by TDS. It was found that the peak commonly observed at 595±25 K and assigned to adsorbed atomic oxygen (Oa) is shifted to higher desorption temperatures with rising dosing temperatures. Since saturation of the uptake was not possible either, this peak was identified as dissolved atomic oxygen (Od). The existence of a maximum for the O2 uptake after exposure at 820 K was found. Hence, under conditions of formaldehyde synthesis ( 920 K) the ability of the catalyst to dissolve oxygen is near its maximum. 相似文献
59.
考察了Pd/Al2O3、In/Al2O3和Co/Al2O3对甲烷选择性还原NO的催化活性。结果表明,采用浸渍法制备的Pd/Al2O3、In/Al2O3和Co/Al2O3三种催化剂,在有氧气氛下,用CH4作还原剂催化还原NO时,Pd/Al2O3催化剂的活性最佳,热稳定性好,在550 ℃,用CH4选择还原NO,Pd/Al2O3催化剂表现出较强的催化能力,NO的转化率达到100%。在高空速实验中,该催化剂亦表现出较高的活性,其活性顺序为Pd/Al2O3>In/Al2O3>Co/Al2O3。实验研究了助催化剂、氧含量以及空速对Pd/Al2O3催化剂活性的影响。 相似文献
60.
以城市污水处理厂剩余污泥为原料制备了一种新型碳质催化剂。通过试验考察了催化剂在NH3选择催化还原NO中的应用效果。结果表明,催化性能较好,最佳的制备和催化反应条件为:锌铁物质的量比1∶0.5,热解温度750 ℃,反应温度400 ℃,O2浓度15%。在此条件下,NOx的最大转化率达98.3%。通过考察证明催化剂自身具有一定的还原性能。对催化剂进行了FTIR、TG、SEM和BET分析,结果表明,催化剂具有很丰富的孔结构、活性粒子和表面官能团,比表面积较大,最大可达307 m2·g-1,分析结果显示具有良好的催化条件。 相似文献