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31.
Oxygen Tracer Diffusion in Vitreous Silica 总被引:2,自引:0,他引:2
Joseph D. Kalen Rethia S. Boyce James D. Cawley 《Journal of the American Ceramic Society》1991,74(1):203-209
Oxygen diffusion in vitreous silica glass is studied using the gas exchange technique. The tracer concentration profiles are consistent with a model based on two mechanisms, one network and the other interstitial. These processes are coupled through limited network–interstitial exchange. Nuclear reaction analysis and secondary ion mass spectrometry techniques are performed and compared. These results are compared to experiments on transport in thin silica films grown on single-crystal silicon. 相似文献
32.
本文研究了一种Zn-Ti合金新镀层,经盐水浸泡、中性盐雾和大气暴露试验结果试验,其耐蚀明显超过镀Zn层,并与镀Cd层相近,用缺口持久拉伸试验检验氢脆性,拉伸持续时间超过200h,达到原航空部部颁标准(HB5067-85),该镀层适用于高强度钢防护。 相似文献
33.
In the research presented here, we explore the use of a low‐energy plasma to deposit thin silicone polymer films using tetramethyldisiloxane (TMDSO) (H(CH3)2? Si? O? Si? (CH3)2H) on the surface of an ethylene propylene diene elastomeric terpolymer (EPDM) in order to enhance the surface hydrophobicity, lower the surface energy and improve the degradation/wear characteristics. The processing conditions were varied over a wide range of treatment times and discharge powers to control the physical characteristics, thickness, morphology and chemical structure of the plasma polymer films. Scanning electron microscopy (SEM) shows that pore‐free homogeneous plasma polymer thin films of granular microstructure composed of small grains are formed and that the morphology of the granular structure depends on the plasma processing conditions, such as plasma power and time of deposition. The thicknesses of the coatings were determined using SEM, which confirmed that the thicknesses of the deposited plasma‐polymer films could be precisely controlled by the plasma parameters. The kinetics of plasma‐polymer film deposition were also evaluated. Contact angle measurements of different solvent droplets on the coatings were used to calculate the surface energies of the coatings. These coatings appeared to be hydrophobic and had low surface energies. X‐ray photoelectron spectroscopy (XPS) and photoacoustic Fourier‐transform infrared (PA‐FT‐IR) spectroscopy were used to investigate the detailed chemical structures of the deposited films. The optimum plasma processing conditions to achieve the desired thin plasma polymer coatings are discussed in the light of the chemistry that takes place at the interfaces. Copyright © 2004 Society of Chemical Industry 相似文献
34.
Barium copper oxalate was grown in silica hydrogel at ambient temperature. The effect of various parameters like gel pH, gel
density, gel aging and concentrations of reactants on the growth of these crystals was studied. The crystals grown were characterized
by chemical analysis, X-ray powder diffractometry, infrared spectroscopy, thermogravimetric and differential thermal analysis.
The results of these observations are described and discussed. 相似文献
35.
Asbestos fibres, of the chrysotile variety, and chopped carbon fibres were pretreated by an in-situ polycondensation technique eventually resulting in a polyamide coating on the fibre surface. Ionomer based composites containing either carbon or asbestos fibres in random in plane fibre orientation were prepared, and the influence of this coating process on the tensile properties was investigated. It was found that for the asbestos-filled composites the presence of the nylon 6,6 interlayer improves the tensile performance, especially at moderate polyamide depositions. This is not the case with the pretreated carbon-filled composites for which carbon fibres with higher polyamide contents are preferred. Combinations of the treated asbestos fibres with carbon and/or aramid fibres may be used to reduce the asbestos content in asbestos-only based engineering plastics. 相似文献
36.
The fabrication of functional textiles able to provide thermal regulation and comfort for the body has attracted increasing interest in recent years. This research investigated fabric coatings containing energy absorbing, temperature stabilizing, phase‐change material microcapsules (PCMMcs), and their methods of application. Specifically, a coated fabric was directly prepared by a dual‐type coating method, in which the PCMMcs were dispersed in a polyurethane coating solution with no binder. The thermal performances of the dual‐coated samples were evaluated by differential scanning calorimetry, and their physical characteristics were examined by scanning electron microscopy, thermal vision camera, porosity, water vapor transmission rate (WVTR), and water entry pressure (WEP) analyses. Furthermore, the microclimate characteristics of the thermally enhanced fabrics were investigated under experimental conditions using a human‐clothing‐environment (HCE) simulator system. The study results confirmed the superior performance of the dual‐coated fabrics in terms of thermal regulation and body comfort, compared with those coated by the dry or wet coating method, because of the improved WEP, WVTR, and thermal performance. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
37.
山特维克可乐满公司切削刀具涂层技术的发展 总被引:3,自引:0,他引:3
佘建芳 《稀有金属与硬质合金》2003,31(3):51-55
介绍了山特维克可乐满公司切削刀具涂层技术的发展,并对该公司自1979年以来硬质合金涂层产品的发展情况进行了总结。 相似文献
38.
Giampiero Sacchetti Paola Pittia Manuela Biserni Gian G. Pinnavaia & Marco D. Rosa 《International Journal of Food Science & Technology》2003,38(2):135-143
Summary Ready‐to‐eat breakfast cereals immersed in milk undergo undesirable changes in texture because of sudden moisture uptake. The textural changes are ascribable to a plasticizing effect of water, which modifies the mechanical strength of products by softening the starch/protein matrix. In this work, some textural parameters of different cereal flakes were derived from the force–displacement curves monitored during 300 s of immersion in milk. Hardness loss, deformability increment and changes in the force–displacement curve profile were calculated and plotted against soaking time. The application of a sugar coating process to a model cereal flake increased the initial product hardness and improved the preservation of the textural parameters during immersion. The Peleg model closely fitted the experimental data, with regression coefficients from 0.967 to 0.999. 相似文献
39.
40.
研究了在700℃盐和水蒸气协同作用下TiAlNb合金的腐蚀行为以及溅射涂层对TiAlNb合金的防护作用。结果表明,在盐和水蒸气协同作用下,溅射TiAlCrAg涂层对TiAlNb合金具有一定的保护作用。盐和水蒸气协同作用加速了合金以及涂层的腐蚀。挥发性气体氯化物对α2相的循环作用是TiALNb合金腐蚀的主要原因。涂层中较少的α2相以及Laves相中较高的Cr含量是腐蚀有所减缓的主要原因。 相似文献