低密度泡沫玻璃的研究与应用

低密度泡沫玻璃是利用碎玻璃制造的一种气孔率大于90%的隔热保温材料,它具有强度高、导热系数小、吸水率低、不吸湿、耐腐蚀等特性,在潮湿环境下抗冻性能好,是一种优良的低温、超低温隔热保温材料。该产品用途广泛,所用的原材料简单易得,但生产工艺过程比较复杂,生产过程控制精度要求较高,容易产生各种缺陷而影响产品的质量。本文对低密度泡沫玻璃的生产工艺过程进行详细的分析研究,提出相应的措施,确保产品的低密度和高成品率,提高产品的性能,扩大产品的使用范围。     

On the nature of the active state of silver during catalytic oxidation of methanol

Under the applied high reaction temperatures (900 K) the Ag surface is restructured and a tightly held oxygen species is formed on the surface (O) apart from O atoms dissolved in the bulk (O). Methanol oxidation to formaldehyde proceeds through this O species as demonstrated by application of a variety of spectroscopic techniques.     

陶瓷原料中SiO_2的钼酸银沉淀法测定

通过实验,发现络合滴定用的指示剂——偶氮胂—Ⅲ,可用作本测定中的沉淀滴定指示剂。根据标准 AgNO_3溶液同 MoO_4~(2-)的定量反应,计算出以硅钼黄 Hg[Si(Mo_2O_7)_6]形式存在的MoO_4~(2-)量,再据以算出硅酸盐中 SiO_2的含量。     

P_2O_5影响Na_2O-B_2O_3-SiO_2系玻璃结构与性质的特殊性

本文通过不混溶温度的确定,分相玻璃沥滤速率的测定以及NMR定量分析,研究了P_2O_6对Na_2O-B_2O_3-SiO_2系统玻璃结构和沥滤性质的影响。结果表明,P_2O_5在很大程度上促进钠硼硅分相玻璃的沥滤并非压抑“硼反常”所致,而是由以下三种因素综合作用的结果:(1)P_2O_5促进了钠硼硅玻璃的分相,使连通富硅相骨架尺寸增大;(2)P_2O_5的加入使富硅相骨架间隙中沉积的SiO_2量减少,减小了可溶相扩散阻力;(3)P_2O_5也使可溶相的溶解速率加快。     

Propagation of the Chain Explosive‐Decomposition Reaction in Silver Azide Crystals

The velocity of the chain explosivedecomposition reaction in silver azide whiskes has been measured (1500 m/sec). The measured velocity is identified as the propagation velocity of the diffusion front of holes generated in the course of explosive decomposition.     

An easy pot incubation method for measuring nitrogen mineralization from easily decomposable organic material under well defined conditions

A pot incubation method for measuring mineralization dynamics from fresh plant material was tested. The aim was to develop a method which under well-defined conditions could produce mineralization data suited for estimating model input parameters for nitrogen prediction models. The results showed that the water tension of the soil could be controlled easily and precisely by diffusion through porous ceramic cups, and that nitrogen mineralization or immobilization could be measured already after 15 days at 15°C. The results showed that for the incubated catch crop residues carbon, nitrogen and nitrate-N contents were the most important factors determining mineralization. No significant effects ould be ascribed to other parameters measured.     

Preparation,characterization, and some physical properties of polypropylene/poly(methyl acrylate)‐grafted glass wool composites

Polypropylene/poly(methyl acrylate)‐grafted glass wool (PMA‐g‐GW) mixes were prepared. The polymerization process was carried out using potassium persulfate (PPS) and PPS/acetone sodium bisulfite (ASBS) as a redox‐pair initiation system at 60 and 70°C. The effect of using PPS or PPS/ASBS on the grafting percent and conversion percent reveals that the conversion percent values on using PPS as an initiator are higher than those of PPS/ASBS, while in the case of grafting, the inverse is true, that is, using PPS as an initiator gives grafting percent values lower than those that can be obtained using PPS/ASBS. The dielectric properties, thermal diffusivity, specific heat capacity, and thermal conductivity of PP loaded with modified glass wool as a function of different types and concentrations of initiators—used in the grafting polymerization process, namely, PPS and the redox initiating system—were also studied. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 723–732, 2003     

货架喷塑前处理工艺的选择与应用

介绍了CZ99-03(7)常温锌系磷化剂在货架上的应用,根据货架构件的特点,优化货架喷塑前处理工艺,讨论了影响磷化质量的工艺因素,提出了提高磷化效果的措施以及进一步改进磷化工艺的工艺设计。     

Partial acidulation of an ‘unground’ phosphate rock: II. Plant availability of phosphate

Four greenhouse experiments were conducted using three soils to determine the availability to plants of P from unground North Carolina phosphate rock (PR) treated with 20% to 50% of the H₃PO₄ required for complete acidulation. The influences of soil P retention, P status, the method of preparation of partially acidulated phosphate rocks (PAPRs) and the granule size of the products were investigated. Perennial ryegrass was grown as the test plant for up to 8 months. Triple superphosphate (TSP) was used as the standard fertilizer and unground North Carolina rock was included for comparison.The dry matter yield and P uptake response curves showed that in all experiments PAPRs were markedly superior to the PR. P status of soils appeared to influence the effectiveness of PAPRs to a greater extent than P retention. In soils of low P status the degree of acidulation required for PAPR to be nearly or as effective as TSP was 50% whereas in a soil of high P status even 30% PAPR applied as a maintenance fertilizer was effective. There was a significant positive correlation between water soluble P of fertilizers and P uptake by ryegrass. However, in general PAPRs were more effective per unit of water soluble P than TSP. Granule size (< 1 mm and 1–2 mm) and method of preparation of PAPRs did not alter the effectiveness of PAPRs.