Simulation of Fe-Al compounds developed during single superphosphate manufacture

In order to analyse iron phosphate complexes and gel-like phases encountered in the single superphosphate process, experiments were performed with a free-Al, Fe apatite crystal of Durango from Mexico phosphate rock and sulfuric acid. Reaction products were studied by X-ray diffraction and surface analysis methods namely X-ray photoelectron spectroscopy and scanning electron microscopy. Results show that in a free Al, Fe-system, part of the Ca(H₂PO₄ )₂.H₂O (MCPM) forms before precipitation of any CaSO₄(CS) and gel-like phase such H₂SO₄.yH₃PO₄.xH₂O is formed. When iron is added, the precipitation rate of (CS) and (MCPM) increases and Fe₃(H₃O)H₈(PO₄)₆.6H₂O is formed. When Fe and Al are added, a gel-like phase is quickly formed with a molar ratio that changes with time and develops into crystalline compounds. The composition of this gel may be represented as a mixture of two phases: H₂SO₄.yH₃PO₄.xH₂O and a gel containing Al-Fe-Si.     

过磷酸钙折流混合器的改进

由于绿原化工有限公司过磷酸钙装置生产能力由 6 70 t/ d(实物量 )提高到 84 0 t/ d,折流混合器负荷增大 ,出现折流环磨损加快等问题。采用若干技改措施 :扩大折流环内径、改变折流混合器喷射方向、采用新材料制作折流环 ,使折流混合器能满足 84 0 t/ d过磷酸钙生产的需要     

溶剂对维生素C单晶生长动力学的影响

引　言当过饱和溶液中产生晶核或加入晶种时 ,溶质分子在过饱和度的推动下使晶核或晶种长大的过程就是晶体生长 .晶体生长动力学决定了晶体产品的形态及其物理性质 ,是结晶过程设计、优化和操作的基础 ,在结晶过程研究中占有重要地位[1,2 ] .晶体生长的外部条件例如过饱和度、温度、溶剂等都直接影响到晶面吸附情况的变化、晶体比表面自由焓 ,从而影响晶面的生长速度[3,4 ] .单晶研究是借助于显微镜、照相机、衍射仪等观察手段测定单晶各方向的尺寸随时间的变化 ,确定晶体生长动力学的方法[5] .作者曾采用间歇动态法实验测试维生素C在水 乙…     

高水头船闸一字闸门水动力特性数值模拟

针对某山区高水头船闸30 m淹没水深下一字闸门的水动力特性进行研究,借助FLUENT软件提供的Realizable k-ε紊流模型对门体启闭过程非恒定流场进行动态模拟,通过建立由二维平面混合网格纵向拉伸成的三维棱柱体网格,结合2.5D重构和弹性光顺动网格法,在降低网格数量、提高计算效率的同时,实现一字闸门启闭全过程三维流场模拟。引入VOF法对自由水面迭代求解,得到一字闸门启闭过程门前后水位差及动水阻力矩变化规律,将计算结果与模型试验进行比较,两者吻合较好。模拟计算发现:门底间隙对闸门运行整个阶段动水阻力矩均有影响,动水阻力矩峰值随门底间隙增大而变小。     

Synthesis of polyethylene oxide end‐capped with perfluoroalkyl groups/polystyrene prototype brushes

Polystyrene (PS)/poly(ethylene oxide) (PEO) prototype brushes were prepared by alternating free‐radical copolymerization of methacryloyl‐terminated PS and α‐vinylbenzyl‐ω‐hydroxy or α‐vinylbenzyl‐ω‐perfluoroalkyl (R_f) PEO macromonomers with the addition of Lewis acid (SnCl₄). It was found from their dilute‐solution properties that PS/PEO end‐capped with R_f (PBR_f), and PS/PEO having OH groups at terminal ends (PBOH) prototype brushes formed a single molecule in benzene and aggregates in chloroform, respectively. However, the brush PBOH formed a single molecule in N,N‐dimethylformamide. Such aggregation behaviors seemed to be caused by the interaction between hydroxy groups of PEO chain ends. The brush PBOH was also converted into PBR_f‐type brush by chemical modification, using corresponding acid chloride. The substitution of R_f groups was ～70% due to slipping of terminal hydroxy groups into PEO internal domains. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 772–778, 2006     

域自适应学习研究进展

传统的机器学习假设测试样本和训练样本来自同一概率分布. 但当前很多学习场景下训练样本和测试样本可能来自不同的概率分布. 域自 适应学习能够有效地解决训练样本和测试样本概率分布不一致的学习问题,作为 机器学习新出现的研究领域在近几年受到了广泛的关注. 鉴于域自适应学习技术 的重要性,综述了域自适应学习的研究进展. 首先概述了域自适应学习的基本问 题,并总结了近几年出现的重要的域自适应学习方法. 接着介绍了近几年提出的 较为经典的域自适应学习理论和当下域自适应学习的热门研究方向,包括样例加 权域自适应学习、特征表示域自适应学习、参数和特征分解域自适应学习和多 源域自适应学习. 然后对域自适应学习进行了相关的理论分析,讨论了高效的度 量判据,并给出了相应的误差界. 接着对当前域自适应学习在算法、模型结构和 实际应用这三个方面的研究新进展进行了综述. 最后分别探讨了域自适应学习在 特征变换和假设、训练优化、模型和数据表示、NLP 研究中存在的问题这四个方面 的有待进一步解决的问题.     

Electrochemical reduction of nitrate on Pt(S)[n(1 1 1) × (1 1 1)] electrodes in perchloric acid solution

The electrochemical reduction of nitrate ion was studied by cyclic voltammetry on Pt(1 1 1) and [n(1 1 1) × (1 1 1)] stepped Pt surfaces, where n (=14, 10, 7, 6, 5, 4, 3, 2) is the number of terrace atoms, in 0.1 M HClO₄ + 10 mM KNO₃. The electrocatalytic nitrate reduction was found to hardly proceed on Pt(1 1 1) in the hydrogen adsorption region, while the electrocatalytic activity was improved with the increase in the step density. Inactivation was observed in the presence of adsorbed hydrogen or nitrate-derived reduced adsorbate, i.e. adsorbed NO, on (1 1 1) step sites. It was, therefore, concluded that the electrocatalytically active NO₃⁻ species does not adsorb on the (1 1 1) terraces but on the (1 1 1) monoatomic steps. The nitrate reduction current increased with the step density in a non-linear relationship. The overall current density at 0.21 V (RHE) corresponding to the peak potential of the main electrocatalytic nitrate reduction wave which was maximum at n = 2, abruptly increased with short terraces, i.e. n < 5, where the current wave of adsorbed hydrogen on the Pt stepped surface with comparatively narrow (1 1 1) terraces, denoted as H_nt, also appeared unmodified for n < 5 on voltammograms recorded in 0.1 M HClO₄ in the absence of nitrate.     

基于GPS/GIS的公共安全监测系统的研究

GPS技术在公共安全监测领域中的应用正向高精度、实时化和自动化的方向发展。GPS公共安全监测不仅注重结果,还要分析产生变形的原因。要实现这一目标,就需要借助于G IS的空间分析功能,即需要建立一种基于GPS/G IS的公共安全监测系统。研究了GPS监测的似单差数学模型和算法流程,由于该模型只用到L1载波相位观测值及伪距,因此可适用于单频接收机,从而降低监测成本。同时,结合GPS公共安全监测的特点,提出了GPS/G IS公共安全监测系统的技术路线。     

包结拆分在手性药物分离中的机理与应用

对外消旋体药物进行分离拆分是获取手性药物的重要方法。探讨了环糊精体系包结拆分法的机理，并对运用其机理于手性药物分离中的应用作了探讨。     

Torque Transmission Capabilities of Bonded Polygonal Lap Joints for Carbon Fiber Epoxy Composites

Although carbon fiber epoxy composite materials have excellent properties for structures, the joint in composite materials often reduces the efficiency of the composite structure because the joint is often the weakest area in the composite structure.

In this paper, the effects of the adhesive thickness and the adherend surface roughness on the static and fatigue strengths of adhesively-bonded tubular polygonal lap joints have been investigated by experimental methods. The dependencies of the static and fatigue strengths on the stacking sequences of the composite adherends were observed.

From the experimental investigations, it was found that the fatigue strength of the circular adhesively-bounded joints was quite dependent on the surface roughness of the adherends and that polygonal adhesively-bonded joints had better fatigue strength characteristics than circular adhesively-bonded joints.