树枝状荧光探针设计制备及荧光特性初步研究

树枝状荧光探针是将荧光染料引入树枝状化合物（dendrimer）端基的一类化合物,具有良好的稳定性及光谱特性．笔者以2,2-二甲氧基乙胺为核,采用发散合成法合成了一端含活性氨基的扇形树枝状化合物,并将羧基噻唑橙染料（TO—COOH）引入树枝状化合物的端基,制备出树枝状荧光分子．初步研究了其荧光特性,讨论了反应温度、反应时间等条件对反应收率的影响．     

双向全桥DC-DC变换器单移相闭环控制研究

针对基于传统单移相控制的双向全桥DC-DC变换器存在效率低的问题,提出了一种基于单移相闭环控制的双向全桥DC-DC变换器设计方案;分析了双向全桥DC-DC变换器稳态特性,详细介绍了基于单移相闭环控制的双向全桥DC-DC变换器的建模实现。仿真与实验结果表明,基于单移相闭环控制的双向全桥DC-DC变换器效率高、损耗小。     

The influence of pH on reaction pathways for O2 reduction on the Au(100) face

Oxygen reduction on the Au(100) face was studied by the rotating disk-ring electrode technique in solutions of anions which adsorb strongly on gold (HSO₄⁻/SO₄²⁻ and/or OH⁻) over the entire pH range. The specific adsorption of OH⁻ anions, which is a pH dependent process, is found to play the key role in determining the reaction pathways. In the absence of OH⁻ adsorption, for pHs below 6, the reduction of O₂ begins as a 2e-process. Due to the increase in local pH during O₂ reduction, the reaction pathway turns into a 4e-reduction at a certain potential depending on the pH of the solution. For pHs higher than 6, O₂ reduction begins as a 4e-process in the potential region where specifically adsorbed OH⁻ anions are present.     

便携式多参数采集仪表的设计

介绍了以IAP15F2K61S2单片机为控制器的多参数采集仪表的硬件设计及软件流程,该仪表通过数字传感器实现外界温、湿度、光照度、大气压强等参数的采集,通过COG段码液晶模块显示输出,同时可根据需求将存储数据通过串口上传到PC机,具备实时时钟、低电压监测、待机模式等功能。该仪表设计集成化、数字化程度较高,成本低,便于携带;硬件稍作改动可方便移植到机房、温室、家居等环境监测领域,有较好的市场应用前景。     

一种基于SRT-8算法的SIMD浮点除法器的设计与实现

在科学计算、数字信号处理、通信和图像处理等应用中,除法运算是常用的基本操作之一。基于SRT 8除法算法,设计一个SIMD结构的IEEE 754标准浮点除法器,在同一硬件平台上能够实现双精度浮点除法和两个并行的单精度浮点除法。通过优化SRT 8迭代除法结构,提出商选择和余数加法的并行处理,并采用商数字存储技术降低迭代除法的计算延时,提高频率。同时,采用复用策略减少硬件资源开销,节省面积。实验表明,在40nm工艺下,本设计综合cell面积为18601.9681 μm2,运行频率可达2.5GHz,相对传统的SRT 8实现关键延迟减少了23.81%。     

一种单种群混合蛙跳算法

针对SFLA算法运行速度较慢、在优化部分函数问题时精度不高和易陷入局部最优的缺点,提出了一种单种群混合蛙跳算法SPSFLA。该算法采用单个种群,无需对整个种群进行排序,每个个体通过向群体最优个体和群体中心位置学习进行更新。如果当前个体学习没有进步,则对群体最优个体进行变异,并用变异的结果替代当前个体,加快了算法的运行速度和收敛速度,提高了优化精度。仿真实验结果表明,该算法具有更好的优化性能。     

Extrusion of ultrahigh molecular weight polyethylene under ultrasonic vibration field

The effects of polypropylene (PP) and ultrasonic irradiation on the processing and mechanical properties of ultrahigh molecular weight polyethylene (UHMWPE) are studied. The results show that PP can effectively improve the fluidity and mechanical properties of UHMWPE. The Izod notched impact strength increases from 92 kJ/m² for pure UHMWPE to 109.2 kJ/m² for the blend of UHMWPE with 10 wt % PP. The Young's modulus increases from 528 MPa for pure UHMWPE to 1128 MPa when 25 wt % PP is contained in the blend, and the yield strength also rises when PP is added. The application of ultrasonic vibrations during extrusion can prominently decrease the die pressure and apparent viscosity of the melt, thus increasing the output of extrudate. An appropriate ultrasonic intensity and irradiation time can further promote the mechanical properties, while an overdose of irradiation destroys them. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 2628–2632, 2003     

不同支护结构的实测土压力及其分析

通过对南京某大厦深基坑支护结构侧土压力的实测研究 ,分析和研究了软土地区悬臂支护结构、单层支点混合支护结构、连拱支护结构侧土压力分布的基本规律。     

A comparative investigation of interfacial adhesion behaviour of polyamide based self-reinforced polymer composites by single fibre and multiple fibre pull-out tests

Abstract

Interfacial adhesion of composite materials plays an important role in their mechanical properties and performance. In the present investigation, analysis of the interfacial properties of self-reinforced polyamide composites by using microbond multiple fibre pull-out test is emphasised. Microbond specimens prepared through thermal processing are tested for their interfacial properties by multiple fibre bundle pull-out tests and compared with that of traditional single fibre pull-out test specimens. Multiple fibre pull-out addresses the volume fraction as well as eliminates the possibility of fibre breakage before matrix shear. Higher scatter in the data in the samples is addressed in the present studies. FTIR and Fractographic studies are carried out for deep understanding of the post pull-out interfacial adhesion.     

车间空气中氨浓度测定方法改进

用纳氏试剂分光光度法代替纳氏试剂目测比色法测定车间空气中氨浓度，并采用了单管直接抽取空气样品的方法，使操作简单。并对分析过程中的干扰因素进行了消除，经过作标准曲线、空白试验和计算方法检测限，证明此方法准确度较高。