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51.
The transitions and reactions involved in the thermal treatment of several commercial azodicarbonamides (ADC) in an inert atmosphere have been studied by dynamic thermogravimetry analysis (TGA), mass spectrometry and Fourier transform infrared (FTIR) spectroscopy. A pseudo‐mechanistic model, involving several competitive and non‐competitive reactions, has been suggested and applied to the correlation of the weight loss data. The model applied is capable of accurately representing the different processes involved, and can be of great interest in the understanding and quantification of such phenomena, including the simulation of the instantaneous amount of gases evolved in a foaming process. In addition, a brief discussion on the methodology related to the mathematical modeling of TGA data is presented, taking into account the complex thermal behaviour of the ADC. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
52.
马钢三烧低SiO2烧结的生产实践 总被引:3,自引:1,他引:2
马钢三烧通过采取有效措施,在保证烧结矿产质量稳步提高的前提下。使SiO2含量逐步降低,取得了较好的效果。 相似文献
53.
本文将介绍三种不同成分的低合金钢粉。在混入2 0%铜和不同石墨含量的条件下,对该三种粉进行了试验评定。试件的密度为6 9g/cm3,在氮氢混合气氛中于1120℃下烧结25min,在炉内冷却带650~400℃温区的冷却速度为0 4或1 5℃/s条件下,对烧结态和回火后试件的力学性能进行了测试。回火条件为200℃下保温60min。在一定的冷却速率和碳含量条件下,各种钢粉烧结后的硬度可高达40HRC。回火后,硬度仍可以保持在30HRC以上。 相似文献
54.
55.
56.
The objective of this study is to determine the chemical kinetics of desulphurization of Thai limestone in an atmospheric fluidized bed combustor (AFBC). The experiments, which employed the batch technique using the limestone samples from six major sources in Thailand, were performed in a laboratory‐scale AFBC. The results obtained were analysed and correlated in the form of apparent reaction rate and deactivation rate constants as a function of operating conditions of the furnace and their properties, respectively. The formulae derived from these correlations were kept as general as possible in order that they could be used as input parameters for the selected mathematical model of desulphurization in an AFBC that is suitable for practical use. The predicted results were in good agreement with the experimental data reported in the literature. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
57.
58.
三(明)钢烧结厂电除尘灰的气力输送 总被引:1,自引:1,他引:0
三钢烧结厂130m^2烧结机电除尘输灰首次采用了气力输送系统。该系统由气源、输送、管路、灰库及控制五部分组成,本文介绍了系统的工作原理及运行调试情况。系统投产后,运行平稳,达到了设计要求。 相似文献
59.
60.
A numerical study of the transport phenomena arising in a single-screw extruder channel is carried out. A non-Newtonian fluid
is considered, using a power law model for the variable viscosity. Chemical reaction kinetics are also included. Finite difference
computations are carried out to solve the governing set of partial differential equations for the velocity, temperature and
species concentration fields, over a wide range of governing parameters for the case of a tapered screw channel.
The numerical treatment for this combined heat and mass transfer problem is outlined. A marching procedure in the down-channel
direction is adopted and the validity of the scheme for practical problems discussed. For large viscous dissipation, the material
heats up considerably due to the prevailing shear field, affecting the viscosity significantly, and results in large changes
in the pressure development at the end of the channel. The rate of reaction controls the mass diffusion rate which in turn
affects viscosity and the flow significantly. The dimensionless throughput,q
v
, is one of the most important parameters in the numerical solution. The dimensionless pressure variation is very sensitive
toq
v
, and orders of magnitude changes are possible for small variations inq
v
. Schemes for dealing with other important effects such as back flow, heat transfer by conduction in the barrel, and the effect
of the die are also outlined.
A list of symbols is given at the end of the paper
This is publication No. F-10544-4-91 of the New Jersey Agricultural Experiment Station supported by State Funds and the Center
for Advanced Food Technology (CAFT). The Center for Advanced Food Technology is a New Jersey Commission on Science and Technology Center. This work was also
supported in part by the US Army Research Office. 相似文献