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N. B. B. Obasi A. C. Igboechi T. V. Benjamin 《Journal of the American Oil Chemists' Society》1990,67(10):624-625
The fixed oil ofThevetia peruviana (Pers.) K. Schum. (T. neriifolia Juss) was obtained by solvent extraction, and its yield and composition were studied to reflect the effect of seasonal variations.
Ripe and unripe seeds collected in December and February (the dry season) gave average yields of 72 and 52%, v/w, respectively,
and those of May and August (the rainy season) gave 56 and 41%, v/w, respectively.
Sitosterol was isolated and identified from the unsaponifiable fraction. Oleic, linoleic, stearic and palmitic acids were
shown to be present in all the oils, while myristic, lauric, capric and caprylic acids were identified only in the oil from
unripe seeds collected in the rainy season. The physical and chemical constants of the oils are given also. 相似文献
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Lars?JohnssonEmail author Rolf?E.?Andersson Paresh?C.?Dutta 《Journal of the American Oil Chemists' Society》2003,80(8):777-783
Although the structure of phytosterols is closely related to cholesterol, there is a gap in knowledge concerning the formation
and occurrence of oxidation products from phytosterols. The main objective of this study was to isolate and characterize some
side-chain oxidation products formed after autoxidation of stigmasterol. Another objective was to highlight the difficulties
in the analysis of phytosterol and a mixture of their oxidation products by GC. Pure stigmasterol was oxidized at 120°C for
72 h in an air-ventilated oven. Preparative TLC separated the oxidation products, and the products were characterized with
GC-MS and NMR. In addition to the common ring-structure oxidation compounds, three semipolar oxidation products—24-ethylcholest-5,22-dien-3β,25-diol,
24-ethylcholest-5,22-dien-3β,24-diol, and 24-ethyl-5,22-choladien-3β-ol-24-one—were characterized for the first time by TLC,
GC-MS, and NMR. Moreover, the results of the analysis of a large number of oxidation products from sitosterol, campesterol,
and stigmasterol by capillary column GC indicated that further efforts and optimization are required in this area. 相似文献
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Olga V Egorova Seraphima A Gulevskaya Irina F Puntus Andrey E Filonov Marina V Donova 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2002,77(2):141-147
Mycobacterium sp VKM Ac‐1815D strain was able to cleave sterol side chain giving androstenedione (AD) as a major product with a molar yield of 63–68%. Clones having altered resistance to antibacterial agents were selected. After treatment with ethyl methane sulfonate or mitomycin C, mutants were obtained that retained the ability to produce AD from sitosterol with molar yields of 70–75%. A mutant strain able to effectively reduce 3,17‐diketosteroids at C‐17 was selected. The 17β‐hydroxy steroid dehydrogenase activity of its crude extract was twice as high as that found for the parent organism. The approach offers the possibility of obtaining improved and labelled biocatalysts for AD or testosterone production from sterols. © 2002 Society of Chemical Industry 相似文献
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Lars?JohnssonEmail author Paresh?C.?Dutta 《Journal of the American Oil Chemists' Society》2003,80(8):767-776
Based on the cholesterol-lowering effects of phytosterols, known since the 1950s, extra phytosterol amounts have been added
to certain food products for almost 10 yr. Literature reports on oxidation of phytosterols in general are limited, and data
on side-chain oxidation of these compounds are scarce. The aim of this study was to investigate and characterize autoxidation
products from a mixture of the two phytosterols sitosterol and campesterol. A commercial mixture of the two sterols was oxidized
for 72 h at 120°C in an air-ventilated oven. The oxidation products were separated by preparative TLC and identified and characterized
with GC-MS. The following oxidation products were identified from the two phytosterols: 24-methylcholest-5-en-3β,24-diol,
24-methylcholest-5-en-3β,25-diol, 24-methylcholest-4-en-6α-ol-3-one, 24-methylcholest-4-en-6β-ol-3-one, 24-ethylcholest-5-en-3β,24-diol,
24-ethylcholest-5-en-3β, 25-diol, 24-ethylcholest-4-en-6α-ol-3-one, 24-ethylcholest-4-en-6β-ol-3-one. Full-scan mass spectra
of these compounds are reported for the first time as their trimethylsilyl-ether derivatives. 相似文献
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Csaba D Andrs Bla Simndi Ferenc
rsi Charalambos Lambrou Doukeni Missopolinou‐Tatala Costas Panayiotou Jnos Domokos Fruzsina Doleschall 《Journal of the science of food and agriculture》2005,85(8):1415-1419
Pilot‐scale supercritical fluid extraction of okra seeds was carried out, using carbon dioxide as solvent, at temperatures of 40, 50 and 60 °C and pressures of 150, 300 and 450 bar. Laboratory‐scale Soxhlet extraction of the ground seeds was carried out with ethanol and n‐hexane. The yields of supercritical fluid extraction and n‐hexane Soxhlet extractions were similar. The ethanol Soxhlet extraction gave the highest yield, but the concentrations of β‐sitosterol and tocopherols in this extract were lower than in the supercritical fluid extraction product. The fatty acid profiles of the extracts were determined, and a high unsaturated/saturated ratio was observed. The fatty acid compositions were only slightly different for oils obtained by the different extraction methods. Copyright © 2005 Society of Chemical Industry 相似文献
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Marina V Donova Dmitry V Dovbnya Galina V Sukhodolskaya Sergey M Khomutov Vera M Nikolayeva Inchan Kwon Kyuboem Han 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2005,80(1):55-60
Soybean extract residue (scum), a waste of soybean oil production, was examined as a raw material for C17‐ketosteroid production. As a model process, its bioconversion to 9α‐hydroxyandrost‐4‐ene‐3,17‐dione (9‐OH‐AD) by Mycobacterium sp VKM Ac‐1817D was studied. The content of transformable sterols (sitosterol, stigmasterol and campesterol) in scum was estimated at ~14%. The bioconversion of scum to 9‐OH‐AD was characterized by a long lag‐period (300–350 h) followed by 9‐OH‐AD accumulation. The microbial or chemical elimination of fatty non‐identified components resulted in sterol‐enriched scum preparations. Effective conversion of these preparations by Mycobacterium sp was demonstrated: 9‐OH‐AD molar yield ~65% was reached at 60 h from the scum preparation containing 10 g dm?3 transformable sterols. The process productivity was comparable with that for high quality‐sitosterol of wood origin (tall‐oil sitosterol). Copyright © 2004 Society of Chemical Industry 相似文献