大理石抛光表面变质层的研究

本文利用扫描电镜发现大理石抛光表面存在有微米级的不同于大理石母材的变质层。进而利用透射电镜证明:该变质层是由非晶和微晶组成的。它的产生有助于提高大理石抛光表面的光泽度。     

超细WC粉末的强化球磨和表面钝化

研究了超细WC球磨破碎和分散机理,通过表面活性剂和聚合物的添加,降低了超细WC的球磨料浆粘度,提高了WC的球磨效率;经过150小时球磨后WC的BET小于100nm,X衍射晶粒度小于30nm。WC表面聚合物包覆的物理改性,其抗氧化能力提高了一倍。     

Technique of pulse electrochemical finishing in molds and dies

Surface finishing is one of the most important processes in mould and die making. This process is necessary not only for smoothing the surface of die or mould, but also for removing the surface layer, which has been damaged by the preceding machining process and finally improve the performances and lifetime of moulds to a large extent. It has been reported that between 30% and 40% of the total time required to manufacture a die or mold is spent on finishing operations, most of which are performed by skilled workers employing traditional techniques. At present, key problems in mould and die finishing technology can improve the finishing efficiency, consistency and quality at reduced costs. A new and high efficiency unconventional finishing technology, pulse electrochemical finishing was introduced. Experiments were done in neutral nitrate electrolytes. The influence of electrolyte composition, intereletrode gap, finishing time, flow quality, current density, compositions of steel materials and pulse parameters on the resulting surface finishing was investigated. Results indicate that pulse parameters have important influence on operations finishing and the proper selection of pulse parameters can lead to both good smoothing efficiency and surface quality at low costs.     

Au-Ni-Kovar合金系统基底元素表面偏聚的SAM和XPS研究SCIEI

本文采用SAM和XPS对实用Au-Ni-Kovar合金系统热处理样品(250—350℃,0.5—1.5h)进行了基底元素穿透Au层的表面偏聚研究,给出了这一复杂系统中Ni,Co表面偏聚机理的直观证据,即Ni,Co主要是通过晶界扩散穿透Au层而后以表面扩散覆盖镀Au表面的;表面偏聚元素化学态的研究则不仅表明,氧的吸附和氧化反应是Ni,Co表面偏聚的驱动力,而且发现,上述偏聚会引起样品表面吸水的现象。     

酸性表面调整工艺对彩涂产品性能的影响

为了获得高质量的涂层钢板，通过一系列的试验研究工作，从微观和宏观两方面证实了彩涂板涂敷前处理工艺中的酸性表面调整处理可提高彩涂板的抗剥离性能和耐蚀能力。     

表面氧化层对TiMn1.25Cr0.25储氢合金活化性能的影响

通过TiMn1.25Cr0.25合金粉活化前在空气中暴露不同的时间,探讨了表面氧化层的形成对其活化性能的影响。活化测试结果表明：合金的活化难度随着合金在空气中暴露时间的延长而加大。俄歇电子能谱(AES)结果表明,在空气中暴露后的合金表面形成了一层大约6nm-10nm厚的表面氧化层,正是这层氧化层的形成加大了合金的活化难度。扫描电镜(SEM)结果表明合金的活化过程与合金的碎化有着密切的联系。     

Study of Co-Ce coating and surface on pasted nickel electrodes substrate

The process of electroplating Co-Ce alloys on the nickel foam framework surface can improve electro-conductivity for active materials and nickelsubstrate interface. The results of inductive coupled plasma emission spectrometer (ICP), cyclic voltammetry (CV), scanning electron microscopy (SEM), X-ray diffraction (XRD) and electron probe microanalysis (EPMA) indicate that the Co-Ce coating chemical content of rare earth Ce 0.19wt.%-0.28wt.% can not only alter the microstructure of electroplating coating, but also accelerate the oxidation reaction of Co and improve its transfer rate of electric current conductivity to the active material particles. The grads-like distributing electro-conductive network of CoOOH is formed on the nickel substrate surface, which improves reversibility of pasted nickel electrode. The charging receptivity is improved by Co-Ce coating on the pasted nickel electrode substrate, and its specific discharging capacity is improved by 50%.     

扫描隧道显微镜在金属表面粗糙度检测上的应用

本文用扫描隧道显微镜(STM)观察了钢预磨和抛光后的表面形貌,测量了表面粗糙度Ra,并与表面轮廓仪的测量结果进行了对比,取得了一致的结果,从而提供了一种测量高光洁金属表面微区粗糙度的新方法.     

铝合金铸件充型过程及氧化膜卷入的数值模拟

对于直接有限差分法，提出了单元表面无量纲距离、表面充填比率和体积充填比率，以描述铸件充型过程中自由表面的形状，建立了相应的充型过程数学模型，考虑了自由表面形状对动量、质量和能量传输的影响；提出了充型过程自由表面碰撞中表面氧化膜破碎，及其后破碎氧化膜流动的计算模型。对实验铝合金铸件进行了模拟应用，通过实际铸件充型过程的特殊X射线实时观察和记录。及实际铸件的气孔、收缩缺陷分布的检测，对模拟结果进行了验证分析。结果表明：充型过程模拟结果与X射线实时观察结果吻合较好，尤其是自由表面的变化；氧化膜卷入模拟结果与实际铸件气孔、收缩缺陷的分布存在一定的对应关系。