东乌煤及不同化学组分的傅里叶红外分析

通过对东乌煤及其腐殖酸、抽提腐殖酸残煤、抽提沥青质残煤进行傅里叶红外分析,揭示抽提腐殖酸和抽提沥青质实验对煤结构的影响。结果表明:由于酸碱溶液的影响,腐殖酸残煤中芳香烃振动的峰,脂肪烃的伸缩振动峰,3400cm-1附近的峰都变弱;由于吡啶溶剂的影响,沥青质残煤中反映芳香结构的峰变尖锐;煤样的fa随H/C增加有减小趋势,而随着O/C的增加呈增大趋势;煤样中腐殖酸的脂肪链最长,支链最少;腐殖酸残煤的脂肪链最短,支链最多。     

白光LED用Ce，Sm共掺杂YAG单晶荧光材料的光谱性能

对白光发光二极管（light-emitting diode,LED）用Y3Al5O12（YAG）单晶荧光材料的制备和光谱性能进行了研究。采用提拉法生长了白光LED用Ce：YAG及Sm,Ce：YAG晶体,并通过吸收光谱、激发光谱和发射光谱等对晶体的光谱特性进行表征。结果表明：Ce：YAG单晶作为荧光材料被发射波长460 ...     

Tm3+掺杂硅酸盐玻璃的1.8μm光谱性质

研究了Tm掺杂硅酸盐玻璃的热稳定性、1.8μm荧光性质.测试了玻璃样品的特征温度、吸收光谱和荧光光谱:根据吸收光谱,计算并讨论了玻璃样品的吸收和发射截面、Judd-Ofelt参数、辐射跃迁几率和辐射寿命等光谱参量.计算得出Tm3+:3F4→3H6能级跃迁的辐射寿命达到5.62ms,受激发射截面和辐射寿命的乘积σem×τ...     

Plutonium Third Phase Formation in the 30% TBP/Nitric Acid/Hydrogenated Polypropylene Tetramer System

Abstract

A study on plutonium third phase formation in 30% TBP/nitric acid/hydrogenated polypropylene tetramer (HPT) was performed. Characterization studies of HPT indicate its composition to be a mixture of many highly branched alkanes with a volatility close to n‐undecane. This composition results in about a factor of two better resistance to Pu(IV) third phase formation than dodecane. At 7 M nitric acid in the aqueous phase, the presence of Pu(VI) was observed to substantially reduce the organic phase metal concentration necessary to induce phase splitting in both diluents. Spectroscopic investigation of mixed valence systems also suggest a prominent role for Pu(VI) in the formation of the dense organic phase. Accumulation of Pu(VI) in the heavy phase, as well as certain spectral features, suggest that Pu(VI) is forming a different species, possibly a plutonyl trinitrato, with a strong tendency to form third phase.     

钛合金中锰铬锆元素的看谱分析方法

用光栅看谱镜和棱镜看谱镜分析钛合金及成分元素锰、铬、锫的特征谱线,研究钛合金中锰、铬、锆元素的定性分析、半定量分析方法.锰、铬、锫元素可分别使用Mn 475.40谱线组、cr520.45谱线组和Zr 473.95谱线组进行定性和半定量分析.     

交流TIG电弧过零时段的时间-能量分布特征

借助于高时间分辨率的增强型CCD光谱分析系统,对交流TIG电弧在方波、梯形波、正弦波3种波形条件下不同过零速度的发射光谱进行了观测与分析,应用谱线Stark展宽理论计算得到了电子密度及其时间的变化.结果表明,对应于不同电流波形的电子密度在过零时段表现出一种滞后现象,并且滞后时间与电流过零速率、能量输入以及电弧输入功率变化率有关,探讨了焊接弧一源系统能量转换过程中的非傅里叶效应的存在及其条件.     

In-situ monitoring of surface stoichiometry and growth kinetics study of GaN (0001) in MOVPE by spectroscopic ellipsometry

GaN surface stoichiometry and growth kinetics in MOVPE were studied by in-situ spectroscopic ellipsometry. The effect of MOVPE conditions on both the surface stoichiometry and growth kinetics was investigated. The surface stoichiometry, such as N-rich, Ga-rich and Ga-excess surfaces, was monitored, and was drastically changed by the variation of the NH₃ partial pressure. When the TMG supply was interrupted during the growth, the layer-by-layer decomposition/revaporation was observed in H₂/NH₃ ambient. The decomposition rate was measured as a function of the NH₃ flow rate at the conventional epilayer growth temperatures (1050–1140 C). The decomposition rate was decreased with the increase in the N coverage on the GaN surface. it was found that the surface stoichiometry is a very important parameter for the control of the MOVPE growth kinetics.     

熏蒸处理对大叶杨理化性能的影响

目的探讨质检熏蒸处理对大叶杨理化性能的影响。方法采用氧硫化碳(COS)、溴甲烷(MB)、硫酰氟(SF)3种不同的熏蒸剂,在不同浓度条件下对大叶杨进行熏蒸处理,并用色差分析、力学性能检测、扫描电镜、红外光谱分析等方法对熏蒸前后大叶杨的理化性能进行对比。结果使用3种熏蒸剂处理后,大叶杨材色均发生明显变化,其中COS熏蒸对大叶杨材色影响最小;经过COS熏蒸处理后,大叶杨木材的顺纹抗压强度、静曲强度、弹性模量均明显下降,在熏蒸剂质量浓度为124.2 g/m~3条件下,下降幅度达8%~12%;熏蒸处理后,大叶杨微观表面并没有发生明显变化;在大叶杨红外光谱图中,经MB和SF熏蒸处理后,1734 cm~(–1)处吸收峰明显加强,C=O键明显增多;COS处理后,1598,1510,1245 cm~(–1)处吸收峰强度均降低。结论熏蒸处理会使木质包装材料材色、力学性能发生变化,并在木材内部有明显残留,但是熏蒸剂与木材内化学物质的反应仍需进一步探讨。     

Growth and optical properties of Pr~(3+):La_2CaB_(10)O_(19) crystal

Pr3+ doped La2CaB10O19 crystal were grown by the top-seeded solution growth(TSSG) method.The absorption spectra,emission spectra and lifetime were measured at room temperature.The J-O parameters(Ωt,t=2,4,6),the radiative transition probabilities AJ,J',oscillator strengths PJ,J',radiative lifetime τ,fluorescence branch ratios βJ and the value of integrated emission cross section have also been calculated.Five main absorption bands,3H4 to 3P1+3P2,3P0,1D2,3F3 + 3F4 and 3F2,were observed in the absorption spect...     

微晶玻璃的制备与光谱特性

高温熔制摩尔组分为32CaO-12Y₂O₃-24Al₂O₃-31SiO₂-1Yb₂O₃的玻璃, 制得的玻璃于950、1050、1100℃三个不同温度进行热处理, 用XRD分析热处理后样品的相变, 用TEM观察1050℃热处理后的样品, 并研究了1050℃热处理前后样品的光谱特性. 研究结果表明: 玻璃在1050℃热处理后, 在玻璃中产生单一YAG相微晶颗粒; 热处理前后样品光谱特性的变化表明热处理后掺杂的Yb ³⁺离子择优进入到YAG晶格位, 制备得到了透明Yb:YAG微晶玻璃.