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61.
X. Q. Ma H. Zhang J. Dai J. Roth R. Hui T. D. Xiao D. E. Reisner 《Journal of Thermal Spray Technology》2005,14(1):61-66
This work addresses the fabrication of membrane-type solid oxide fuel cells (SOFCs) operating at medium temperatures, where
all components are fabricated by plasma spray technology, and the evaluation of the performance of the SOFC single unit in
a temperature range of 500 to 800 °C. Single cells composed of LaSrMgO3 cathodes, LaSrGaMgO3 (LSGM) electrolytes, and Ni/yttria-stabilized zirconia anodes were fabricated in successive atmospheric plasma-spraying processes.
Plasma-spraying processes have been optimized and tailored to each layer to achieve highly porous cathode and anode layers
as well as high-density electrolyte layers. A major effort has been devoted to the production of the LSGM electrolyte that
has a high density and is free of cracks. Electrochemical impedance spectroscopy was used to investigate the conductivity
of the electrode layers, and particularly the resistance of the electrolyte layer. It revealed that the heat treatment had
a great influence on the specific conductivity of the sprayed electrolyte layers and that the specific conductivity of the
heat-treated layers was dramatically increased to the same magnitude as is typical for sintered LSGM pellets. The experimental
results have demonstrated that the plasma-spraying process has a great potential for the integrated fabrication of medium-temperature
SOFC units.
The original version of this article was published as part of the ASM Proceedings, Thermal Spray 2003: Advancing the Science and Applying the Technology, International Thermal Spray Conference (Orlando, FL), May 5–8, 2003, Basil R. Marple and Christian Moreau, Ed., ASM International,
2003. 相似文献
62.
N. Z. Mehdizadeh M. Lamontagne C. Moreau S. Chandra J. Mostaghimi 《Journal of Thermal Spray Technology》2005,14(3):354-361
Plasma-sprayed molten molybdenum particles (∼40 μm in diameter) were photographed impinging at high velocity (∼140 m/s) on
a glass substrate at room temperature. An optical sensor detected thermal radiation emitted by a droplet as it approached
the substrate and activated a time delay unit. After a selected time interval, an Nd:YAG laser was triggered, emitting a 5
ns pulse that provided illumination for a charge-coupled device (CCD) camera to photograph the impacting droplet through a
long-range microscope. By varying the delay before pulsing the laser, different stages of droplet deformation were recorded.
Impacting droplets spread into a thin circular film that ruptured and broke into small fragments. An optical detector recording
thermal radiation from the impacting droplet gave a signal that increased as the droplet spread out, reached a maximum when
the liquid film began to rupture, and decreased as portions of the droplet recoiled because of surface tension and then flew
out of view of the photodetector. 相似文献
63.
本文通过研究目前汽车烤漆房的实际运行情况,提出了一种汽车烤漆房喷漆自动控制系统,阐述了系统喷漆装置的构成、配合与运行原理,并构成了实际试验系统。 相似文献
64.
Thermal sprayed aluminum and zinc provide long-term (> 20 years to first maintenance) corrosion control coatings. However,
this application is usually more expensive than painting or galvanizing if thermal spraying (metallizing) is not integrated
into the design and fabrication phases of new construction and repair projects. Aluminum and zinc metallized coatings are
tough enough to withstand fabrication, transportation, and assembly operations. The improved capabilities and productivity
of metallizing equipment for aluminum and zinc spraying are a major factor in their current cost competitiveness. The net
result is that the cost difference between metallizing, paint, and galvanizing is getting closer every day. Even though the
initial application cost of metallizing may be higher, the life cycle cost (LCC) and average equivalent annual costs (AEAC)
are lower than paint coating systems. Metallizing LCCs, when properly engineered into the construction schedule, are equal
to or less than paint coating LCCs. This article summarizes some metallizing considerations for installing improved corrosion
control coating systems in new construction and in maintenance and repair of infrastructure.
Editor’s Note: The following constants have been used to convert between English and Metric dimensions: 1ft2-0.0929 m2; 1lb/ft2-4.89 kg/m2; 1 mil=0.025mm.
Presented at the 5th National Thermal Spray Conference (NTSC-93), Infrastructure Maintenance and Repair Session, 10 June 1993,
Anaheim, CA. 相似文献
65.
为解决高海拔地区输电线路运行维护检修存在的传感器供电可靠性差、无移动信号区域数据传输难度大的问题,文中提出了一种基于异构物联网络的输电线路智慧巡检方法。首先,研究了风光协同的传感器供电技术,实现了高海拔地区恶劣环境下输电线路监测传感器的可靠供电;其次,建立了异构的输电线路物联网络,实现了输电线路无移动信号传感器的数据采集。在此基础上,通过深度学习对所采集数据样本进行分析,实现对输电线路的智慧巡检;最后,将所提方法在某无信号地区110 kV线路的现场运行,其结果验证了所提方法的有效性和可行性。 相似文献
66.
Marine antifouling coating using functional polymers has emerged as an important tool to combat marine fouling. Owing to their natural abundance, polysaccharides represent a more sustainable option than synthetic polymers and carrageenan, a sulfated polysaccharide, is identified as a promising candidate for further research based on its excellent marine antifouling properties. However, existing research has only explored the application of carrageenan-based coatings for 2D objects, using techniques such as spin-coating. Here, a spray-coating method is proposed to apply carrageenan-based coatings to the surfaces of 2- and 3-D objects. The coated surfaces exhibit high stability under various chemical/physical stresses and high resistance to protein adsorption and marine diatom adhesion. 相似文献
67.
The deposition of copper by cold gas dynamic spraying has attracted much interest in recent years due to the capability to
deposit low-porosity oxide-free coatings. However, it is generally found that as-deposited copper has a signicantly greater
hardness, and potentially lower ductility, than bulk material. In this article, copper was deposited by cold spraying using
helium as the driving gas at both 298 and 523 K. Evidence is presented indicating that the material sprayed at the lower temperature
exhibits a lower dislocation density throughout the grain structure than the material sprayed at the higher temperature. The
low stacking fault energy of copper restricts recovery during annealing, and thus microstructural changes during annealing
only proceed once recrystallization begins. The material sprayed at low temperature (with the low dislocation density) exhibited
recrystallization at annealing temperatures as low as 373 K with a corresponding reduction in hardness. However, the copper
sprayed with helium at 523 K was resistant to annealing at temperatures up to 473 K where the dislocations in the structure
prevented recrystallization. However, at higher temperatures, recrystallization did proceed (with corresponding reductions
in hardness). The fracture behavior of the copper that was cold sprayed with helium at 523 K, both in the as-sprayed condition
and following annealing, was measured and explained in terms of the annealing mechanisms proposed.
The original version of this paper was published in the CD ROM Thermal Spray Connects: Explore Its Surfacing Potential, International
Thermal Spray Conference, sponsored by DVS, ASM International, and HW International Institute of Welding, Basel, Switzerland,
May 2–4, 2005, DVS-Verlag GmbH, Düsseldorf, Germany. 相似文献
68.
The characterization of La
x
Sr1−x
MnO3 powders produced by spray pyrolysis using scanning electron microscopy (SEM) and transmission electron microscopy (TEM) observation,
specific surface area (Brunauer-Emett-Teller), and particle size distribution measurements shows that the resultant large
particles are loose agglomerates consisting of many small particles. However, the sintered tiny particles can form hard agglomerates,
and the particle size increases remarkably. The structures of the powders before and after sintering were identified by x-ray
diffraction (XRD). The study of the electrical property of the powder shows that the powder is a metallic conductor. In a
reducing atmosphere, the powder can be decomposed. When the powder is cofired with yttria-stabilized zirconia 5% (YSZ) powder
at 1200 °C for 5 h, no new phase is produced, and the powder remains a single provskite hexagonal-rhombohedral structure. 相似文献
69.
借助Thermo-Calc热力学相图计算软件,开发了用于电梯的含氮节镍奥氏体不锈钢QN1701(12Cr17Mn7Ni2Cu2N),以代替443(019Cr21CuTi)超纯铁素体不锈钢。通过OM、SEM和电化学工作站等方法研究了QN1701和443不锈钢的组织及性能。N原子起着间隙固溶和细晶强化的作用,使QN1701不锈钢的屈服强度提高至400 MPa以上,达到443不锈钢的1.32倍。QN1701不锈钢的点蚀电位为241 mV,低于443不锈钢的289 mV,但其点蚀速率为9.10 g/(m2·h),低于443不锈钢的14.58 g/(m2·h)。在电梯用研磨拉丝表面状态下,QN1701不锈钢在质量分数为10%NaCl中性盐雾和干湿循环盐雾等加速腐蚀试验中的耐蚀性能均优于443不锈钢。分析发现,443不锈钢添加一定量的Nb、Ti稳定化元素所生成的(Nb,Ti)(C,N)析出相经研磨拉丝处理后,暴露于表面或被拖拽后留下微坑,导致其耐蚀能力急剧下降。综上所述,相较443不锈钢,QN1701不锈钢具有强度更高、伸长率更大和在研磨拉丝表面状态下耐蚀性更好等特点,这对于电梯轻量化设计和长寿命具有重要价值。 相似文献
70.
铜基体超音速火焰喷涂碳化物涂层界面研究 总被引:1,自引:0,他引:1
使用扫描电子显微镜及透射电子显微镜,对铜基体超音速火焰喷涂(HVOF)碳化物涂层的形成过程,组织结构和界面形态进行了研究。结果表明,HVOF涂层界面显微组织非常复杂,存在纳米晶,非晶和大量位错孢,非晶是粘结相在喷涂中受热,骤冷形成的,而涂层中的纳米晶来自半熔碳化物的破碎。 相似文献