Enthalpies of Solution and Mixing for Graphite in Molten Silicon at 2000 K

Partial and integral enthalpies of mixing have been determined in an isoperibolic calorimeter for liquid alloys in the silicon – carbon binary system at 2000 K. These enthalpies of mixing are small exothermic quantities which agree with published data. The enthalpy of mixing _f Hº₂₉₈ has been calculated for silicon carbide.     

气相碱度与质子亲合势的基本概念及其测定方法

介绍了气相碱度和质子亲合势的基本概念 ,对气相碱度及质子亲合势的测定方法进行了详细评述 ,包括 :电离阈值法、理论计算法、气相平衡常数法、插入法、动力学法、热力学法等。列出相关文献近 4 0篇     

从舒适性角度谈卧式风机盘管的选择

卧式风机盘管作为舒适性空调系统中大量使用的一种末端设备，在设备选择时，不能忽视设备的舒适特性。通过对三种卧式风机盘管的舒适性的比较，发现同一规格的产品，其在房间内的冷气流的运动轨迹、温度、速度衰减有较大的不同，因而对房间的舒适性有较大的影响，从舒适性角度考虑应选择风量大，送风温差小的设备；指出开发低焓差的产品，从而对提高设备的舒适特性很有必要。     

Thermochemical Study on Ternary Solid Complex of La（Gly）2（Ala）3Cl3·2H2O（s）

The complex of lanthanum chloride with Glycine and Alanine,La(Gly)2(Ala)3Cl3·2H2O,was synthesized and characterized by IR,elementary analysis,thermogravimetric analysis,and chemical analysis.The dissolution enthalpies of LaCl3 ·7H2O(s),2Gly(s) 3Ala(s)and La(Gly)2(Ala)3Cl3 ·2H2O(s)were determined in 2 mol·L-1 HCl by a solution-reaction isoperibol calorimeter.By designing a thermochemical cycle in terms of Hess' Law and through calculation,the reaction enthalpy of lanthanum chloride seven-hydrate with Glycine and Alanine was obtained:ΔrHθm(298.15 K)=(29.652±0.504)kJ·mol-1,and the standard enthalpy of formation of La(Gly)2(Ala)3Cl3·2H2O(s)ΔfHθm [La(Gly)2(Ala)3Cl3·2H2O,s,298.15 K]=-4467.6±8.3 kJ·mol-1.     

一种考虑控制系统耦合关系的汽包锅炉简化模型与分析

考虑了控制系统间的耦合关系，根据基本物理定律，建立了一种汽包锅炉简化模型，并对模型进行了分析。在建模过程中，提出了系统压力变动焓的概念，对影响系统压力变动焓的因素进行了分析。利用该参数把锅炉给水和减温水的影响引入汽包锅炉简化模型，体现了控制系统间的耦合影响。同时，提出了一种新的水位控制系统和主汽温控制系统前馈信号，可更好地削弱耦合回路的影响，进一步改善控制效果。文中为研究复杂的电站机组系统提供了一种新思路和新方法。     

驻点法在桩群模拟中的运用

采用有限元方法建立了二维平面水流模型，并引入驻点的概念模拟水中桩柱对水流的影响，即在计算中将网格节点设置于桩柱处，并在该节点设置滞流边界条件，即流速为0m／s．以长寿朱家坝码头的高桩码头方案为算例进行了模拟计算，结果表明该方法可以较好地模拟桩群对水流流速、流态的影响．     

超临界机组的给水自动控制策略

根据超临界直流炉的控制特点及给水控制,分析了目前国内常用的两种控制结构,比较了基于中间点焓值校正和基于中间点温度校正的优缺点,提出了给水超驰控制策略以克服部分特殊工况下常规给水控制策略的不足,工程应用效果良好。     

Cu(TO)2Cl2的制备和热力学研究（英）

根据制备过程,提出了配合物Cu(TO)2Cl2在混合溶液中的晶体生长的动力学模型。通过这个动力学模型,测定了一系列的动力学参数Ea=45.37kJ·mol-1,ln(A/s-1)=14.65,Δ≠Gm=82.11kJ·mol-1,Δ≠Hm=42.85kJ·mol-1,Δ≠Sm=131.58J·mol-1·K-1。另外,用RD496-Ⅲ型微量热计测定了该化合物在298.15K时的比热容,并计算了[Cu(TO)2]2 (aq)和Cu(TO)2Cl2(s)的标准生成焓。     

NTO负一价离子的水合焓ΔhHθm(NTO-)

借助M(NTO)n·mH2O (M=La,Ce,Pr,Eu,Sm,Gd,n=3,m=7;M=Y,Yb,n=3,m=6;M=Dy,Tb,n=3,m=5;M=Nd,n=3,m=8)在水中的溶解焓ΔsolHθm、晶格焓ΔHθL、晶格能ΔUθL和标准生成焓ΔfHθm(M n ,aq,∞)、ΔfHθm(M n ,g)、ΔfHθm(H2O,g)、ΔfHθm(H2O,l)、ΔfHθm(NTO-,aq,∞)、ΔfHθm(NTO-,g)以及Mn 的水合焓ΔhHθm(M n )的文献数据,估算了NTO负一价离子的水合焓ΔhHθm(NTO-),结果显示,ΔhHθm(NTO-)=-(153.73±0.21) kJ·mol-1.     

Thermodynamic characterization of bio-fuels: Excess functions for binary mixtures containing ETBE and hydrocarbons

European energy policy is promoting the use of bio-fuels for transportation. Bioethers and bioalcohols are used as blending agents for enhancing the octane number. They make gasoline work harder, help the engine last longer and reduce air pollution. They also cause changes in the fuel properties. Development of renewable fuels needs both knowledge of new thermodynamic data and improvement of clean energy technologies. In this context, the use of ethanol of vegetable origin in its manufacture process, increases the interest of ETBE or bio-ETBE as an oxygenated additive. A complete study of the behaviour of ETBE + hydrocarbons mixtures is presented. Some experimental data concerning vapor-liquid equilibria and heats of mixing were determined in our laboratory. All the techniques have a high accuracy. The data were reduced by well-known models, such as NRTL and used to model the thermodynamic properties.