太原地区深基开挖问题之探讨

深基坑的开挖和支护工程，是整个建筑工程重要组成部分，其造价、工期在整个建筑工程中占很大比例。本文通过山西省电力局中心调度大楼的基坑开挖中存在的问题所采取的补救措施及问题分析初探，提出太原地区在受到周围场地限制、地下水位高情况下，深基开挖中应注意和考虑的问题。     

高层建筑地下室的后浇带和墙体施工缝构造措施研究

以吉林省延吉市某小区高层建筑框架结构工程为实例,对地下室后浇带和墙体水平施工缝的施工提出了新的构造措施:后浇带两侧采用由钢板网和钢筋骨架组成的模板,并且在其之间设置钢筋作为水平支撑,同时用钢板止水带止水的方法;水平施工缝采用钢板止水带止水、开口箍筋定位的方法.工程实践表明,施工质量符合现行规范验收标准,可为类似工程提供借鉴.     

An electrochemical approach to total organic carbon control in printed circuit board copper sulfate plating baths Part II: Overall system

An electrochemical system for oxidative removal of high levels of total organic carbon (TOC) in printed circuit board (PCB) copper sulfate plating baths has been developed. These organic contaminants build-up over the course of pattern plating of PCBs, and at high concentrations they interfere with the quality of the plated copper. The chemistry of the electrochemical oxidation of the plating bath contaminants was qualitatively followed using high performance liquid chromatography (HPLC) and chemical oxygen demand (COD) measurements. A complete treatment system is described and rough calculations are given showing, for a given set of conditions, how the proper choice of electrode material and current density can minimize the system cost.     

Orthogonal Translation Meets Electron Transfer: In Vivo Labeling of Cytochrome c for Probing Local Electric Fields

Cytochrome c (cyt c), a redox protein involved in diverse fundamental biological processes, is among the most traditional model proteins for analyzing biological electron transfer and protein dynamics both in solution and at membranes. Studying the role of electric fields in energy transduction mediated by cyt c relies upon appropriate reporter groups. Up to now these had to be introduced into cyt c by in vitro chemical modification. Here, we have overcome this restriction by incorporating the noncanonical amino acid p‐cyanophenylalanine (pCNF) into cyt c in vivo. UV and CD spectroscopy indicate preservation of the overall protein fold, stability, and heme coordination, whereas a small shift of the redox potential was observed by cyclic voltammetry. The C≡N stretching mode of the incorporated pCNF detected in the IR spectra reveals a surprising difference, which is related to the oxidation state of the heme iron, thus indicating high sensitivity to changes in the electrostatics of cyt c.     

Effect of annealing process on the growth and surface properties of Au–ZnO nanowire films grown by chemical routes

Au–ZnO nanowire films have been synthesized by chemical routes, electrochemical deposition (ECD) and chemical bath deposition (CBD) techniques, on zinc foil followed by annealing in air at 400 °C. X-ray diffraction patterns reveal formation of the ZnO wurtzite structure along with binary phases Au₃Zn and AuZn₃. Scanning electron microscopy shows the presence of ZnO nanowires having several micrometers in length and less than 120 nm in diameter synthesized by ECD and in the range of 70–400 nm using the CBD technique. During the annealing process, different surface morphologies originating from different catalytic effects of Au atoms/layers were observed. In addition, the effect of synthesis routes on crystalline quality and optical properties were studied by Raman and photoluminescence spectrometers indicating varying concentration of defects on the films. The Raman results indicate that Au–ZnO nanowire film prepared by chemical bath deposition route had better crystalline quality.     

化学镀镍复合添加剂BH的工艺特性

开发了一种由含钼化合物、碘化钾以及邻苯二甲酸酐衍生物组成的复合添加剂BH,讨论了它对化学镀镍液稳定性、镀速以及镀层磷含量、硬度、孔隙率和微观形貌的影响。对测试化学镀镍液稳定性的PdCl2试验标准进行了改进:温度由80°C提高到90°C,PdCl2的浓度由0.1g/L增加到1.0g/L。研究结果显示,新标准检验的镀液稳定性差异能较好地反映实际生产中的镀液稳定性差异;当复合添加剂BH的添加量为2.0mL/L时,化学镀镍层微观形貌得到较大的改善。经过新的PdCl2试验标准检验,该镀液可达到900s不发生浑浊,镀速为24μm/h,镀层孔隙率0.57个/cm2,磷含量7.3%,硬度520HV。     

N形限位挡块的设计

为解决滚轮式行程开关易出现的复位弹簧弹力下降导致不能复位问题,设计了一种N形限位挡块,通过调整挡块的安装位置改变传统的行程开关与挡块撞击后行程开关上转臂所处的状态,使其恢复到撞击前的原始自由状态,进而改变复位弹簧的压缩状态,并对典型的控制电路进行了相应改进,从而在一定条件下延长行程开关的使用寿命。     

整体提升锡槽顶盖更换锡槽槽底

结合锡槽冷修工程实际情况,改进传统的冷修方案,用整体提升锡槽顶盖的方案,进行槽底砖的更换工作,取得了令人满意的效果.     

大型电解槽温度管理

以贵阳铝镁设计研究院92台280kA电解槽和沈阳铝镁设计研究院182台280kA电解槽为基础，研究了大型槽温度变化规律以及与诸多因素的关系，公布了最佳电解质温度研究结果，并且在生产实践中得到了验证。同时对其它槽型提出了建议．具有一定的参考价值。