Influence of the presence of titanium oxide on the formation of pyrochlore phase in ferroelectric strontium bismuth tantalate ceramics

The effects of addition of TiO₂ on the formation of pyrochlore phase and dielectric properties of ferroelectric SrBi₂Ta₂O₉ have been investigated. When the content of Ti02 is less than 10 mol%, no secondary phases are produced, and SrBi₂Ta₂O₉-TiO₂ solid solutions are formed. However, with TiO₂ content ≥20 mol%, a pyrochlore phase is produced. Raising the content of TiO₂ in starting materials significantly increases the amounts of pyrochlore phase, and reduces the initial temperature for the formation of pyrochlore phase. The existence of TiO₂ also decreases the thermal stability of SrBi₂Ta₂O₉, causing the decomposition of SrBi₂Ta₂O₉to take place at lower temperatures. Furthermore, the presence of TiO₂ reduces the dielectric constants as well as remnant polarization of formed ceramics.     

Sr Microalloying for Refining Grain Size of AZ91D Magnesium Alloy

The grain refining process of an AZ91D Mg alloy by Sr addition was studied and the heterogeneous nucleating particles of α-Mg were investigated by electron probe microanalysis （EPMA）. With 0.6 wt% Sr addition, the mean grain size of AZ91D alloy was refined from 235.4μm to 52.5 μm at the one-half radius of the ingot. The morphology of primary crystal changed from a sixford symmetrical shape to a petallike shape, Mg-Sr-Al-Fe-Mn heterogeneous nucleating particles were observed at the grain centers and Sr solute atoms presented segregation along the grain boundaries. Grain refinement was facilitated by both the Mg-Sr-Al- Fe-Mn nucleating particles and the Sr solute atoms, and the former played a dominate role in the process.     

MgO掺杂Ba0.6Sr0.4TiO3铁电材料的结构研究

采用固相反应法制备了掺杂不同量氧化镁（MgO）的钛酸锶钡（BST）微波铁电材料。采用SEM、EPMA、XRD等测试手段，分析研究了烧结产物的微观形貌特征、相组成、微区成分等特点，结果表明：MgO总是以单独相存在，Mg^2＋没有取代Ba^2＋（Sr^2＋）或Ti^4＋离子而进入BST晶格。     

碳酸锶生产过程中的除钡新方法

以天青石为原料 ,硫酸铵作为抑制剂抑制硫酸钡转化 ,免除传统除钡工序 ,得到纯度为 97%的碳酸锶产品。在此基础上与硫酸除杂相结合 ,通过调整工艺参数 ,增添絮凝剂 ,可得到纯度大于 99% ,钡离子去除率达 95 %的高纯度碳酸锶 ,而且不会向溶液中引入其它杂质。     

氯化锶水溶液的净化和SrCl2的制取

生产锶盐的过程中都存在ＳｒＣｌ２溶液的净化，本文讨论了锶的氯盐溶液净化的方法和影响因素，得到了ＳｒＣｌ溶液沉淀法降钙钡及其它杂质净化方法。     

反铁畸变中钛酸锶(SrTiO3)晶体学原胞的选取

通过对钛酸锶（SrTiO3)在相变前后结构对称性的分析，提出了与之相应的两种晶体学原胞的选取方法。无论选取D4和D2d哪一种原胞，其对称元素个数均为8，即对称元素个数保持不变，只是所选原胞体积相差一倍。因此，在选取原胞时必须遵从以下两个原则：1）所选晶体学原胞的体积在相变前后要保持不变；2）所选取的晶体学原胞，应最能反映相变前后晶体结构对称性的变化，且其对称元素个数不因所选原胞体积的不同而变化。     

钛酸锶钡铁电薄膜的制备与性能优化研究

综述了目前钛酸锶钡(BST)铁电薄膜最为常用的4种制备工艺:磁控溅射法(Magnetron Sputtering)、脉冲激光沉积法(PLD)、溶胶-凝胶法(Sol-gel)、金属有机物化学气相沉积法(MOCVD)。并介绍了在优化BST铁电薄膜性能方面所作的工作和取得的成果。     

锶在改性介质中迁移的柱实验研究

通过室内土柱实验研究了锶在不同润湿性介质中的迁移规律和特征,并采用CXTFIT 2.1软件对实验结果进行了拟合,通过实验数据计算了延迟因子。结果表明：在疏水介质中,锶的穿透速度较快,利用平衡CDE方程或两区模型来模拟锶在三种润湿性不同的石英砂柱中的迁移均是可行的,但两区模型的模拟效果更好。     

Thermal Instability and Microstructure of Strontium M-type Hexaferrite Nanoparticles Synthesized by Citrate Approach

The dried gel of SrFe12O19, prepared by citrate approach, was investigated by means of infrared spectroscopy （ IR ）, thermogravimetric analysis （ TG ）, differential scanning calorimetry （ DSC ）, X- ray diffraction（ XRD ） techniques, energy dispersive spectroscopy（ EDS ）, and transmission electron microscopy（ TEM ）. The thermal instability and the thermal decomposition of low-temperature strontium M-type hexaferrite crystallized at about 600℃ were confirmed for the first time by XRD method. The decomposition of the low-temperature strontium M-type hexaferrite took place at about 688.6℃ determined by DSC investigation. The low-temperature strontium M-type hexaferrite nanopartieles were decomposed into SrFeO2.5 with an orthorthombic cell and Fe2O3 with a tetragonal cell as well as possibl α-Fe2O3 . The agglomerated particles with sizes less than 200 nm obtained at 800℃ were plesiomorphous to strontium M-type hexaferrite. The thermally stable strontium M-type hexaferrite nanopartieles with sizes less than 100um cotdd take place at 900 ℃ . Up to 1000 ℃ , the phose transformotion to form strontium M-type hexaferrite was ended, the calcinations with the sizes more than 1μm were composed of α-Fe2O3 and strontium M-type hexaferrite. The method of distinguishing γ-Fe2O3 with a spinel structure from Fe2O3 with tetragonal cells by using powder XRD method was proposed. Fe2O3 with tetragonal cells to be crystallized before the crystallization of thermally stable strontium M-type hexaferrite was confirmed for the first time. The reason why α- Fe2O3 as an additional phase appears in the calcinations is the cationic vacancy of stroutium M-type hexaferrite , SrFe12-x□O19 （0≤x ≤0.5）.     

Sr/Zr掺杂以及抛光对BaTiO_3陶瓷结构和介电性能的影响

采用冷压陶瓷技术制备了(Ba0.75Sr0.25)TiO3、Ba(Ti0.8Zr0.2)O3、(Ba0.75Sr0.25)(Ti0.8Zr0.2)O3陶瓷.XRD结果表明,Sr和Zr在BaTiO3的Ba位、Ti位、及Ba/Ti双位并入均具有高固溶性,且为没有超结构特征的单相钙钛矿结构.Sr/Zr的双位并入加快介电峰向低温的移动.Sr掺杂对Ba(Ti0.8Zr0.2)O3介电峰移动率的贡献为-1.5℃/mol%Sr.抛光技术对介电温谱的影响研究表明,尽管水抛光导致(Ba0.75Sr0.25)(Ti0.8Zr0.2)O3陶瓷颜色变暗,但晶体结构不变、介电峰值降低.