锌钾硼对甜菜产质量效应及最佳施肥措施的研究

本文利用最优回归设计“310”方案,研究了黑土地甜菜 Zn、K_2O、B的效果及合理施用问题。得出甜菜块根产量、含糖、产糖量、灰分 K 和有害 N 与 ZnK_2O、B 肥回归关系显著的回归模型,分析了 Zn、K_2O、B 对上述五个指标的效应,明确了 Zn 是影响各项指标的主要因子,并采用频率筛选法,提出了兼顾上述五项指标的优质高产施肥措施。     

Urea briquette applicator for transplanted rice

A plunger-type, completely hand-operated applicator prototype, made of polyvinyl chloride (PVC), for deep placement of urea briquettes (UB), i.e., pillow-shaped urea supergranules with edges, in line transplanted rice has been developed for use by small-scale rice farmers. The field evaluation of the applicator was conducted in the Philippines during the 1989 dry season. The applicator consistently placed UB at proper depth (7 to 8 cm), which resulted in low concentrations of urea N (<7 ppm) in about 4 cm of floodwater 1 day after placement. These findings indicated that the prototype worked properly. Average work output of the applicator was 0.20 ha workday^–1 and may increase with practice. The yields of irrigated transplanted rice in the field trials show that agronomic efficiencies of hand-placed UB and applicator-placed UB were equal and were superior to those of split-applied prilled urea.     

Ethynedithiol‐based polyeneoligosulfides as active cathode materials for lithium‐sulfur batteries

Ethynedithiol‐based polyeneoligosulfides have been synthesized in 96% yield by the reaction of sodium acetylides (HC?CNa, NaC?CSNa) and elemental sulfur through the Na? C_sp bond in liquid ammonia with the following spontaneous polymerization of ethynedithiols (HSC?CSH) formed by the hydrolysis. The polyeneoligosulfides synthesized are brown powders (up to 77% sulfur content, mp 128–184°C), partially soluble in organic solvents. They are high‐resistance semiconductors (10^?13 to 10^?14 S cm^?1), possess paramagnetic (10¹⁷ to 10¹⁸ spin g^?1) and redox properties. The oligosulfides obtained, being redox systems capable of reversible redox processes, provide high values of discharge capacity (345–720 mA h g^?1) of rechargeable lithium‐sulfur batteries. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

硫含量对钴钼型耐硫脱氧剂的脱氧活性影响

研究了工艺气中硫含量对钴钼型耐硫脱氧剂脱氧活性的影响。通过常压微反 -色谱装置测定脱氧剂的本征脱氧活性 ,加压原粒度反应器测定脱氧剂的表观脱氧活性 ,结合实际经验确定了耐硫脱氧剂所需的最低硫含量。还讨论了温度、压力、空速对耐硫脱氧剂脱氧活性的影响。结果表明 ,耐硫脱氧剂完全能满足耐硫变换工艺的要求 ,而且有耐硫变换的作用 ,并对耐硫变换催化剂起到保护作用     

塔河渣油高温催化临氢热转化技术研究

以塔河减压渣油（简称塔河减渣）为原料，在实验室小型试验装置和中型连续试验装置上，对在较高温度条件下催化临氢热转化加工塔河减渣的工艺操作条件及改质效果进行了系统研究。采用高分散的油溶性催化剂，在高压釜反应器中考察了反应温度、反应压力、催化剂添加量、溶剂油添加量、反应时间以及助剂添加量对塔河减渣催化临氢热转化反应的转化率和缩合率的影响，优化了操作参数。在优化的操作条件下，进行了塔河减渣催化临氢热转化中型试验，得到初馏点大于524 ℃组分的裂化率为85.2%，馏分油收率为80%，金属（Ni+V）和沥青质脱除率均大于90%。     

Study on Reduction of Sulfur Content in FCC Gasoline

Reduction of sulfur content in FCC gasoline was studied in a fixed fluid bed (FFB) unit by using metal-modified LV-23 FCC catalyst. The results showed that the sulfur content in FCC gasoline could be reduced with LV-23 catalyst modified with zinc, palladium, zinc-palladium, zinc-cobalt, and zinc-nickel. Among these metals or metal combinations, palladium-containing catalyst was the most effective. Desulfufization of the heavy fraction of FCC gasoline was more effective than full-range gasoline under the same conditions with palladium-containing catalysts. A high reaction temperature was favorable to desulfurization, but it would reduce the yield of liquid product. After desulfurization reaction, the olefm content of product gasoline decreased while the aromatic and iso-alkane contents increased. Removal of thiophene and benzothiophene is higher.     

利用贫软锰矿制备锰盐的研究

用二氧化硫法处理贫软锰矿，得到含硫酸锰和连二硫酸锰的溶液，继而将该溶液进行净化，除杂，浓缩，结晶处理即得工业级硫酸锰，结晶母液用碳铵沉淀即得碳酸锰产品     

消化吸收引进技术 完善化肥工业国产化

本文回顾了我国化肥工业国产化发展过程，论述了实现国产化的条件，并对国产化项目提出了几点建议。     

我国车用无铅汽油的质量状况及分析

对1998－2001年间生产领域和流通领域的近500批次汽油产品检验数据进行了总结和分析，表明我国汽油的实物质量正在不断提高，但从环保要求出发还需不断向国际水平靠扰，尤其应进一步降低烯烃含量，硫含量。     

制备低硫可膨胀石墨的研究

研究了以过二硫酸铵作氧化剂低硫可膨胀石墨的制备，找到了在较低温度下，制备低硫可膨胀石墨的最佳条件。即过二硫酸铵和石墨的重量比为１５％；反应温度为５５℃；反应时间为４０ｍｉｎ；硫酸浓度为９８％；硫酸与石墨的重量比为４∶１，草酸和硝酸（浓度为６５％）的重量比为７．５％时，所制得的可膨胀石墨含硫量为０．６５％，膨胀容积为２００ｍＬ／ｇ可膨胀石墨。并且，其终端产品柔性石墨具有优良的力学性能和抗氧化性能。